Molecular Hydrogen

Observations of H₂ line emission in galactic and extragalactic environments obtained with the Infrared Space Observatory (ISO) are reviewed. The diagnostic capability of H₂ observations is illustrated. We discuss what one has learned about such diverse astrophysical sources as photon-dominated regions, shocks, young stellar objects, planetary nebulae and starburst galaxies from ISO observations of H₂ emission. In this context, we emphasise use of measured H₂ line intensities to infer important physical quantities such as the gas temperature, gas density and radiation field and we discuss the different possible excitation mechanisms of H₂. We also briefly consider future prospects for observation of H₂ from space and from the ground. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Infrared Spectroscopy of Solar-System Planets

Most of our knowledge regarding planetary atmospheric composition and structure has been achieved by remote sensing spectroscopy. Planetary spectra strongly differ from one planet to another. CO₂ signatures dominate on Mars, and even more on Venus (where the thermal component is detectable down to 1 μm on the dark side). Spectroscopic monitoring of Venus, Earth and Mars allows us to map temperature fields, wind fields, clouds, aerosols, surface mineralogy (in the case of the Earth and Mars), and to study the planets’ seasonal cycles. Spectra of giant planets are dominated by H₂, CH₄ and other hydrocarbons, NH₃, PH₃ and traces of other minor compounds like CO, H₂O and CO₂. Measurements of the atmospheric composition of giant planets have been used to constrain their formation scenario.     

The Ice Survey Opportunity of ISO

The instruments on board the Infrared Space Observatory have for the first time allowed a complete low (PHOT, CVF) to medium resolution (SWS) spectroscopic harvest, from 2.5 to 45 μm, of interstellar dust. Amongst the detected solids present in starless molecular clouds surrounding recently born stellar and still embedded objects or products of the chemistry in some mass loss envelopes, the so-called “ice mantles” are of specific interest. They represent an interface between the very refractory carbonaceous and silicates materials that built the first grains with the rich chemistry taking place in the gas phase. Molecules condense, react on ices, are subjected to UV and cosmic ray irradiation at low temperatures, participating efficiently to the evolution toward more complex molecules, being in constant interaction in an ice layer. They also play an important role in the radiative transfer of molecular clouds and strongly affect the gas phase chemistry. ISO results shed light on many other species than H₂O ice. The detection of these van der Waal's solids is mainly performed in absorption. Each ice feature observed by ISO spectrometer is an important species, with abundance in the 10⁻⁴–10⁻⁷ range with respect to H₂. Such high abundances represent a substantial reservoir of matter that, once released later on, replenishes the gas phase and feeds the ladder of molecular complexity. Medium resolution spectroscopy also offers the opportunity to look at individual line profiles of the ice features, and therefore to progressively reveal the interactions taking place in the mantles. This article will give a view on selected results to avoid to overlap with the numerous reviews the reader is invited to consult (e.g. van Dishoeck, in press; Gibb et al., 2004.). Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

The Cool Interstellar Medium

Infrared spectroscopy and photometry with ISO covering most of the emission range of the interstellar medium has led to important progress in the understanding of the physics and chemistry of the gas, the nature and evolution of the dust grains and also the coupling between the gas and the grains. We review here the ISO results on the cool and low-excitation regions of the interstellar medium, where T _gas≲ 500 K, n _H∼ 100–10⁵ cm⁻³ and the electron density is a few 10⁻⁴. JEL codes: D24, L60, 047 Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Composition and Measurement of Charged Atmospheric Clusters

Atmospheric charged clusters are formed in a series of rapid chemical reactions after ionisation, leaving a central ion X⁺ or X^? clustered with n ligands (Y) _n . In solar system tropospheres and stratospheres there are two distinct cluster regimes: the terrestrial planets contain largely hydrated clusters (i.e. Y=H₂O), whereas the gas planets and their moons have organic or nitrogenated cluster species. These classifications are largely based on model predictions, since hardly any measurements are available. The few existing composition measurements are reviewed, including the recent detection of massive charged particles in Titan’s upper atmosphere. Technologies for both remote sensing and in situ measurements of atmospheric charged clusters are discussed. Preliminary measurements in the terrestrial atmosphere are presented indicating that ambient charged cluster species interact with downwelling infra-red radiation at 9.15 μm, even in the presence of cloud. This supports the possibility of future infrared detection of charged clusters.     

Evolution of Interstellar Ices

Infrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Ices in molecular clouds are dominated by the very simple molecules H₂O, CH₃OH, NH₃, CO, CO₂, and probably H₂CO and H₂. More complex species including nitriles, ketones, and esters are also present, but at lower concentrations. The evidence for these, as well as the abundant, carbon-rich, interstellar, polycyclic aromatic hydrocarbons (PAHs) is reviewed. Other possible contributors to the interstellar/pre-cometary ice composition include accretion of gas-phase molecules and in situ photochemical processing. By virtue of their low abundance, accretion of simple gas-phase species is shown to be the least important of the processes considered in determining ice composition. On the other hand, photochemical processing does play an important role in driving dust evolution and the composition of minor species. Ultraviolet photolysis of realistic laboratory analogs readily produces H₂, H₂CO, CO₂, CO, CH₄, HCO, and the moderately complex organic molecules: CH₃CH₂OH (ethanol), HC(=O)NH₂ (formamide), CH₃C(=O)NH₂ (acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C₆H₁₂N₄), as well as more complex species including amides, ketones, and polyoxymethylenes (POMs). Inclusion of PAHs in the ices produces many species similar to those found in meteorites including aromatic alcohols, quinones and ethers. Photon assisted PAH-ice deuterium exchange also occurs. All of these species are readily formed and are therefore likely cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Photochemistry in Outer Solar System Atmospheres

The photochemistries of the H₂-He atmospheres of the gas giants Jupiter, Saturn and ice giants Uranus and Neptune and Titan’s mildly reducing N₂ atmosphere are reviewed in terms of general chemical and physical principles. The thermochemical furnace regions in the deep atmospheres and the photochemical regions of the giant planets are coupled by vertical mixing to ensure efficient recyling of photochemical products. On Titan,mass loss of hydrogen ensures photochemical evolution of methane into less saturated hydrocarbons. A summary discussion of major dissociation paths and essential chemical reactions is given. The chapter ends with a overview of vertical transport processes in planetary atmospheres.     

Late Stages of Stellar Evolution

A large fraction of ISO observing time was used to study the late stages of stellar evolution. Many molecular and solid state features, including crystalline silicates and the rotational lines of water vapour, were detected for the first time in the spectra of (post-)Asymptotic Giant Branch (AGB) stars. Their analysis has greatly improved our knowledge of stellar atmospheres and circumstellar environments. A surprising number of objects, particularly young planetary nebulae with Wolf-Rayet (WR) central stars, were found to exhibit emission features in their ISO spectra that are characteristic of both oxygen-rich and carbon-rich dust species, while far-IR observations of the PDR around NGC 7027 led to the first detections of the rotational line spectra of CH and CH⁺. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

The ionospheres of the major planets

Physical and chemical processes which affect the equilibrium distribution of ionization in the atmospheres of Jupiter, Saturn, Uranus and Neptune are reviewed. Current models imply readily detectable ionospheres for all four planets and suggest that protons should represent the dominant positive ion. Attention is directed to the probable importance of dissociative ionization of H₂ as a source of H⁺. A number of potentially important loss mechanisms for H⁺ are discussed including a possible reaction of H⁺ with vibrationally excited H₂. Protons may be removed efficiently at lower altitudes by reaction with CH₄ and this process may offer a simple remote means for location of the turbopause.This is one of the publications by the Science Advisory Group.     

Aeronomy of Extra-Solar Giant Planets

The intense stellar UV radiation field incident upon extra-solar giant planets causes profound changes to their upper atmospheres. Upper atmospheric temperatures can be tens of thousands of kelvins, causing thermal dissociation of H₂ to H. The stellar ionizing flux converts H to H⁺. The high temperatures also drive large escape rates of H, but for all but the planets with the smallest orbits, this flux is not large enough to affect planet evolution. The escape rate is large enough to drag off heavier atoms such as C and O. For very small orbits, when the hill sphere is inside the atmosphere, escape is unfettered and can affect planet evolution.     

Rare Atoms,Molecules and Radicals in the Coma of P/Halley

We have searched for rare molecules and radicals in the coma of P/Halley using the ion data obtained by IMS-Giotto. Whereas our established methods were used in the ionosphere, a new model was developed for the interpretation of the ion data in the outer coma. Ne/H₂O < 1.5 × 10^-3 was determined in the coma of the comet. Upper limits for the production of Na were derived from the very low abundance of Na⁺. Methyl cyanide and (probably) ethyl cyanide were identified with abundances of CH₃CN/H₂O = (1.4 ± .6) × 10^-3 and C₂H₅CN/H₂O = (2.8 ± 1.6) × 10^-4. These results and upper limits for other N-bearing species confirm that nitrogen is depleted in the Halley material. C₄H was identified and a point source strength of C₄H/H₂O = (2.3 ± .8) × 10^-3 was derived. Our upper limit for C₃H is lower than the abundance of C₄H. This is in agreement with the enhanced abundances of C_nH species with even numbers of C-atoms found in interstellar molecular clouds, suggesting that the C₄H in Halley was synthesized under molecular cloud conditions. Thus, C₄H and other organics with unpaired electrons may turn out to be indicators for a molecular cloud origin of cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

New Horizons: Anticipated Scientific Investigations at the Pluto System

The New Horizons spacecraft will achieve a wide range of measurement objectives at the Pluto system, including color and panchromatic maps, 1.25–2.50 micron spectral images for studying surface compositions, and measurements of Pluto’s atmosphere (temperatures, composition, hazes, and the escape rate). Additional measurement objectives include topography, surface temperatures, and the solar wind interaction. The fulfillment of these measurement objectives will broaden our understanding of the Pluto system, such as the origin of the Pluto system, the processes operating on the surface, the volatile transport cycle, and the energetics and chemistry of the atmosphere. The mission, payload, and strawman observing sequences have been designed to achieve the NASA-specified measurement objectives and maximize the science return. The planned observations at the Pluto system will extend our knowledge of other objects formed by giant impact (such as the Earth–moon), other objects formed in the outer solar system (such as comets and other icy dwarf planets), other bodies with surfaces in vapor-pressure equilibrium (such as Triton and Mars), and other bodies with N₂:CH₄ atmospheres (such as Titan, Triton, and the early Earth).     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Debris Discs Around Stars: The 2004 ISO Legacy

Debris discs around stars were first discovered by the Infrared Astronomical Satellite (IRAS) in 1983. For the first time material orbiting another star than the Sun, but distinct from a circumstellar envelope, was observed through its far infrared emission. This major discovery motivated astronomers to investigate those discs by further analyzing the IRAS data, using ground-based telescopes for the hunting of exoplanets, developing several projects using the Infrared Space Observatory (ISO), and now exploiting the ISO Data Archive (IDA). This review presents the main ISO results, statistical as well as individual, on debris discs in orbit around pre-main-sequence and main-sequence stars. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Thermospheric X-Ray and Euv Heating by the Young Sun on Early Venus and Mars

In view of the low H₂O abundance in the present Venusian and Martian atmospheres several observations by spacecraft and studies suggest that both planets should have lost most of their water over the early active period of the young Sun. During the first Gyr after the Sun arrived at the Zero- Age-Main-Sequence high X-ray and EUV fluxes between 10 and 100 times that of the present Sun were responsible for much higher temperatures in the thermosphere-exosphere environments on both planets. By applying a diffusive-gravitational equilibrium and thermal balance model for investigating radiation impact on the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by CO₂ IR emission in the 15μm band we found expanded thermospheres with exobase levels between about 200 km (present) and 2000 km (4.5 Gyr ago). The higher temperatures in the upper atmospheres of both planets could reach “blow-off” conditions for H atoms even at high CO₂ mixing ratios of 96%. Lower CO₂/N₂ mixing ratio or higher contents of H2O vapor in the early atmospheres could have had a dramatic impact from the loss of atmosphere and water on both planets. The duration of this phase of high thermal loss rates essentially depended on the mixing ratios of CO₂, N₂, and H₂O in the early atmospheres and could have lasted between about 150 and several hundred Myr.     

The Cassini Ion and Neutral Mass Spectrometer (INMS) Investigation

The Cassini Ion and Neutral Mass Spectrometer (INMS) investigation will determine the mass composition and number densities of neutral species and low-energy ions in key regions of the Saturn system. The primary focus of the INMS investigation is on the composition and structure of Titan’s upper atmosphere and its interaction with Saturn’s magnetospheric plasma. Of particular interest is the high-altitude region, between 900 and 1000 km, where the methane and nitrogen photochemistry is initiated that leads to the creation of complex hydrocarbons and nitriles that may eventually precipitate onto the moon’s surface to form hydrocarbon–nitrile lakes or oceans. The investigation is also focused on the neutral and plasma environments of Saturn’s ring system and icy moons and on the identification of positive ions and neutral species in Saturn’s inner magnetosphere. Measurement of material sputtered from the satellites and the rings by magnetospheric charged particle and micrometeorite bombardment is expected to provide information about the formation of the giant neutral cloud of water molecules and water products that surrounds Saturn out to a distance of ∼12 planetary radii and about the genesis and evolution of the rings.The INMS instrument consists of a closed ion source and an open ion source, various focusing lenses, an electrostatic quadrupole switching lens, a radio frequency quadrupole mass analyzer, two secondary electron multiplier detectors, and the associated supporting electronics and power supply systems. The INMS will be operated in three different modes: a closed source neutral mode, for the measurement of non-reactive neutrals such as N₂ and CH₄; an open source neutral mode, for reactive neutrals such as atomic nitrogen; and an open source ion mode, for positive ions with energies less than 100 eV. Instrument sensitivity is greatest in the first mode, because the ram pressure of the inflowing gas can be used to enhance the density of the sampled non-reactive neutrals in the closed source antechamber. In this mode, neutral species with concentrations on the order of ≥10⁴ cm⁻³ will be detected (compared with ≥10⁵ cm⁻³ in the open source neutral mode). For ions the detection threshold is on the order of 10⁻² cm⁻³ at Titan relative velocity (6 km sec⁻¹). The INMS instrument has a mass range of 1–99 Daltons and a mass resolutionM/ΔM of 100 at 10% of the mass peak height, which will allow detection of heavier hydrocarbon species and of possible cyclic hydrocarbons such as C₆H₆.The INMS instrument was built by a team of engineers and scientists working at NASA’s Goddard Space Flight Center (Planetary Atmospheres Laboratory) and the University of Michigan (Space Physics Research Laboratory). INMS development and fabrication were directed by Dr. Hasso B. Niemann (Goddard Space Flight Center). The instrument is operated by a Science Team, which is also responsible for data analysis and distribution. The INMS Science Team is led by Dr. J. Hunter Waite, Jr. (University of Michigan).This revised version was published online in July 2005 with a corrected cover date.     

Vertical distribution of disequilibrium species in Jupiter's troposphere

Sources of organic matter and inorganic tracers on Jupiter, including solar UV photolysis, lightning discharges, and convective quenching of hot gases from the lower atmosphere, are reviewed in light of Earth-based and Voyager data with the purpose of predicting the tropospheric steady-state abundances and vertical distributions of HCN, CH₂O, and other species.It is concluded that a steady-state mole fraction of HCN in the Jovian troposphere of only 10^-12 could be maintained by vertical transport of hot gases from the deep atmosphere. The observed HCN abundance (roughly X_HCN = 10^-9) appears to be due to photochemical reactions.After HCN, the most abundant organic disequilibrium species in the troposphere is probably C₂H₆, derived from direct photolysis of CH₄ at high altitudes, with a mole fracton of 10^-10 at the H₂O cloud level. Inorganic tracers of disequilibrium processes are also briefly summarized.     

Radiolysis and Photolysis of Icy Satellite Surfaces: Experiments and Theory

The transport and exchange of material between bodies in the outer solar system is often facilitated by their exposure to ionizing radiation. With this in mind we review the effects of energetic ions, electrons and UV photons on materials present in the outer solar system. We consider radiolysis, photolysis, and sputtering of low temperature solids. Radiolysis and photolysis are the chemistry that follows the bond breaking and ionization produced by incident radiation, producing, e.g., O₂ and H₂ from irradiated H₂O ice. Sputtering is the ejection of molecules by incident radiation. Both processes are particularly effective on ices in the outer solar system. Materials reviewed include H₂O ice, sulfur-containing compounds (such as SO₂ and S₈), carbon-containing compounds (such as CH₄), nitrogen-containing compounds (such as NH₃ and N₂), and mixtures of those compounds. We also review the effects of ionizing radiation on a mixture of N₂ and CH₄ gases, as appropriate to Titan’s upper atmosphere, where radiolysis and photolysis produce complex organic compounds (tholins).     

On the Flux of Water and Minor Volatiles from the Surface of Comet Nuclei

Surface temperature and the available effective energy strongly influence the mass flux of H₂O and minor volatiles from the nucleus. We perform computer simulations to model the gas flux from volatile, icy components in porous ice-dust surfaces, in order to better understand results from observations of comets. Our model assumes a porous body containing dust, one major ice component (H₂O) and up to eight minor components of higher volatility (e.g. CO, CH₄, CH₃OH, HCN, C₂H₂, H₂S), The body's porous structure is modeled as a bundle of tubes with a given tortuosity and an initially constant pore diameter. Heat is conducted by the matrix and carried by the vapors. The model includes radially inward and outward flowing vapor within the body, escape of outward flowing gas from the body, complete depletion of less volatile ices in outer layers, and recondensation of vapor in deeper, cooler layers. From the calculations we obtain temperature profiles and changes in relative chemical abundances, porosity and pore size distribution as a function of depth, and the gas flux into the interior and into the atmosphere for each of the volatiles at various positions of the body in its orbit. In this paper we relate the observed relative molecular abundances in the coma of Comet C/1995 O1 (Hale-Bopp) and of Comet 46P/Wirtanen to molecular fluxes at the surface calculated from our model. This revised version was published online in June 2006 with corrections to the Cover Date.