Thermospheric X-Ray and Euv Heating by the Young Sun on Early Venus and Mars

In view of the low H₂O abundance in the present Venusian and Martian atmospheres several observations by spacecraft and studies suggest that both planets should have lost most of their water over the early active period of the young Sun. During the first Gyr after the Sun arrived at the Zero- Age-Main-Sequence high X-ray and EUV fluxes between 10 and 100 times that of the present Sun were responsible for much higher temperatures in the thermosphere-exosphere environments on both planets. By applying a diffusive-gravitational equilibrium and thermal balance model for investigating radiation impact on the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by CO₂ IR emission in the 15μm band we found expanded thermospheres with exobase levels between about 200 km (present) and 2000 km (4.5 Gyr ago). The higher temperatures in the upper atmospheres of both planets could reach “blow-off” conditions for H atoms even at high CO₂ mixing ratios of 96%. Lower CO₂/N₂ mixing ratio or higher contents of H2O vapor in the early atmospheres could have had a dramatic impact from the loss of atmosphere and water on both planets. The duration of this phase of high thermal loss rates essentially depended on the mixing ratios of CO₂, N₂, and H₂O in the early atmospheres and could have lasted between about 150 and several hundred Myr.     

Vertical distribution of disequilibrium species in Jupiter's troposphere

Sources of organic matter and inorganic tracers on Jupiter, including solar UV photolysis, lightning discharges, and convective quenching of hot gases from the lower atmosphere, are reviewed in light of Earth-based and Voyager data with the purpose of predicting the tropospheric steady-state abundances and vertical distributions of HCN, CH₂O, and other species.It is concluded that a steady-state mole fraction of HCN in the Jovian troposphere of only 10^-12 could be maintained by vertical transport of hot gases from the deep atmosphere. The observed HCN abundance (roughly X_HCN = 10^-9) appears to be due to photochemical reactions.After HCN, the most abundant organic disequilibrium species in the troposphere is probably C₂H₆, derived from direct photolysis of CH₄ at high altitudes, with a mole fracton of 10^-10 at the H₂O cloud level. Inorganic tracers of disequilibrium processes are also briefly summarized.     

Pollution of the upper atmosphere by rockets

This report estimates the amounts of various constituents that would have to be continually injected by rockets into the upper atmosphere in order to double the worldwide natural concentrations there. Involved in the calculations are: (a) the natural atmospheric abundances of constituents such as H₂O, CO₂, NO, Na, K, Li, H, etc.; (b) the residence times in various regions of the atmosphere, since these determine how rapidly a constituent will be removed; and (c) the chemical or photochemical stability of a substance exposed to the upper atmosphere environment. It is concluded that a doubling of the CO₂, H₂O, or NO content would require per year on the order of 10³ to 10⁵ Saturn-type rockets, each injecting 100 tons of exhaust above 100 km. On the other hand, a few hundred small rockets per year, each containing 10 kg of the chemical, would probably double the Na content; similarly, less than two such rockets per year would be expected to double the Li content. These last conclusions have implications for future tracer experiments using these substances.The author is now an Associate Director of the National Center for Atmospheric Research (NCAR) in Boulder, Colorado. The work reported here was supported by the United States Air Force under Contract AF 49(638)-700 with the RAND Corporation. The views or conclusions contained in this paper should not, however, be interpreted as representing the official opinion of the United States Air Force.     

The ionospheres of the major planets

Physical and chemical processes which affect the equilibrium distribution of ionization in the atmospheres of Jupiter, Saturn, Uranus and Neptune are reviewed. Current models imply readily detectable ionospheres for all four planets and suggest that protons should represent the dominant positive ion. Attention is directed to the probable importance of dissociative ionization of H₂ as a source of H⁺. A number of potentially important loss mechanisms for H⁺ are discussed including a possible reaction of H⁺ with vibrationally excited H₂. Protons may be removed efficiently at lower altitudes by reaction with CH₄ and this process may offer a simple remote means for location of the turbopause.This is one of the publications by the Science Advisory Group.     

Spectral analyses of Wolf-Rayet stars: Theory,results, conclusions

Stratified Non-LTE models for expanding atmospheres became available in the recent years. They are based on the idealizing assumptions of spherical symmetry, stationarity and radiative equilibrium. From a critical discussion we conclude that this standard model is basically adequate for describing real Wolf-Rayet atmospheres and hence can be applied for quantitative spectral analyses of their spectra.By means of these models, the fundamental parameters have been determined meanwhile for the majority of the known Galactic WR stars. Most of them populate a vertical strip in the Herzsprung-Russell diagram at effective temperatures of 35 kK, the luminosities ranging from 10^4.5 to 10^5.9 L . Only early-type WN stars with strong lines and WC stars are hotter. The chemical composition of WR atmospheres corresponds to nuclear-processed material (WN: hydrogen burning in the CNO cycle; WC: helium burning). Hydrogen is depleted but still detectable in the cooler part of the WN subclass.Different scenarios for the evolutionary formation of the Wolf-Rayet stars are discussed in the light of the empirical data provided from the spectral analyses. Post-red-supergiant evolution can principally explain the basic observational properties, except the rather low luminosities of a considerable fraction of WN stars. Among the alternative scenarios, close-binary evolution can theoretically produce the least-luminous WN stars. However, final conclusions about the evolutionary formation of the WR stars are not yet possible.     

Atmospheric/Exospheric Characteristics of Icy Satellites

The atmospheres/exospheres of icy satellites greatly vary from one to the next in terms of density, composition, structure or steadiness. Titan is the only icy satellite with a dense atmosphere comparable in many ways to that of the Earth’s atmosphere. Titan’s atmosphere prevents the surface from direct interaction with the plasma environment, but gives rise to Earth-like exchanges of energy, matter and momentum. The atmospheres of other satellites are tenuous. Enceladus’ atmosphere manifests itself in a large water vapor plume emanating from surface cracks near the south pole. Io’s SO₂ atmosphere originates from volcanoes. Europa’s tenuous O₂ atmosphere is produced by intense radiation bombardment. This chapter reviews the characteristics of the atmospheres of Titan, Enceladus, Io and Europa based on observations.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Neutral Atmospheres

This paper summarizes the understanding of aeronomy of neutral atmospheres in the solar system, discussing most planets as well as Saturn’s moon Titan and comets. The thermal structure and energy balance is compared, highlighting the principal reasons for discrepancies amongst the atmospheres, a combination of atmospheric composition, heliocentric distance and other external energy sources not common to all. The composition of atmospheres is discussed in terms of vertical structure, chemistry and evolution. The final section compares dynamics in the upper atmospheres of most planets and highlights the importance of vertical dynamical coupling as well as magnetospheric forcing in auroral regions, where present. It is shown that a first order understanding of neutral atmospheres has emerged over the past decades, thanks to the combined effects of spacecraft and Earth-based observations as well as advances in theoretical modeling capabilities. Key gaps in our understanding are highlighted which ultimately call for a more comprehensive programme of observation and laboratory measurements.     

Oxygen Isotopes and Sampling of the Solar System

The atmospheres of the four giant planets of our Solar System share a common and well-observed characteristic: they each display patterns of planetary banding, with regions of different temperatures, composition, aerosol properties and dynamics separated by strong meridional and vertical gradients in the zonal (i.e., east-west) winds. Remote sensing observations, from both visiting spacecraft and Earth-based astronomical facilities, have revealed the significant variation in environmental conditions from one band to the next. On Jupiter, the reflective white bands of low temperatures, elevated aerosol opacities, and enhancements of quasi-conserved chemical tracers are referred to as ‘zones.’ Conversely, the darker bands of warmer temperatures, depleted aerosols, and reductions of chemical tracers are known as ‘belts.’ On Saturn, we define cyclonic belts and anticyclonic zones via their temperature and wind characteristics, although their relation to Saturn’s albedo is not as clear as on Jupiter. On distant Uranus and Neptune, the exact relationships between the banded albedo contrasts and the environmental properties is a topic of active study. This review is an attempt to reconcile the observed properties of belts and zones with (i) the meridional overturning inferred from the convergence of eddy angular momentum into the eastward zonal jets at the cloud level on Jupiter and Saturn and the prevalence of moist convective activity in belts; and (ii) the opposing meridional motions inferred from the upper tropospheric temperature structure, which implies decay and dissipation of the zonal jets with altitude above the clouds. These two scenarios suggest meridional circulations in opposing directions, the former suggesting upwelling in belts, the latter suggesting upwelling in zones. Numerical simulations successfully reproduce the former, whereas there is a wealth of observational evidence in support of the latter. This presents an unresolved paradox for our current understanding of the banded structure of giant planet atmospheres, that could be addressed via a multi-tiered vertical structure of “stacked circulation cells,” with a natural transition from zonal jet pumping to dissipation as we move from the convectively-unstable mid-troposphere into the stably-stratified upper troposphere.

     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Thermal radio emission from the major planets

The use of long-wavelength radio measurements of brightness temperature to remotely measure the thermal structure of the atmospheres of the major planets at great depths (>10 atm.) is discussed. Data are presented which show that the gross features of Jupiter's and Saturn's microwave spectra, as determined from ground based observations, can be explained in terms of thermal emission from ammonia in deep convective atmospheres of He and H₂.This is one of the publications by the Science Advisory Group.     

Neutral Atmospheres of the Giant Planets: An Overview of Composition Measurements

Measurements of the chemical composition of the giant planets provide clues of their formation and evolution processes. According to the currently accepted nucleation model, giant planets formed from the initial accretion of an icy core and the capture of the protosolar gas, mosly composed of hydrogen and helium. In the case of Jupiter and Saturn (the gaseous giants), this gaseous component dominates the composition of the planet, while for Uranus and Neptune (the icy giants) it is only a small fraction of the total mass. The measurement of elemental and isotopic ratios in the giant planets provides key diagnostics of this model, as it implies an enrichment in heavy elements (as well as deuterium) with respect to the cosmic composition. Neutral atmospheric constituents in the giant planets have three possible sources: (1) internal (fromthe bulk composition of the planet), (2) photochemical (fromthe photolysis ofmethane) and(3) external (from meteoritic impacts, of local or interplanetary origin). This paper reviews our present knowledge about the atmospheric composition in the giant planets, and their elemental and istopic composition. Measurements concerning key parameters, like C/H, D/H or rare gases in Jupiter, are analysed in detail. The conclusion addresses open questions and observations to be performed in the future.     

Evolution of Interstellar Ices

Infrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Ices in molecular clouds are dominated by the very simple molecules H₂O, CH₃OH, NH₃, CO, CO₂, and probably H₂CO and H₂. More complex species including nitriles, ketones, and esters are also present, but at lower concentrations. The evidence for these, as well as the abundant, carbon-rich, interstellar, polycyclic aromatic hydrocarbons (PAHs) is reviewed. Other possible contributors to the interstellar/pre-cometary ice composition include accretion of gas-phase molecules and in situ photochemical processing. By virtue of their low abundance, accretion of simple gas-phase species is shown to be the least important of the processes considered in determining ice composition. On the other hand, photochemical processing does play an important role in driving dust evolution and the composition of minor species. Ultraviolet photolysis of realistic laboratory analogs readily produces H₂, H₂CO, CO₂, CO, CH₄, HCO, and the moderately complex organic molecules: CH₃CH₂OH (ethanol), HC(=O)NH₂ (formamide), CH₃C(=O)NH₂ (acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C₆H₁₂N₄), as well as more complex species including amides, ketones, and polyoxymethylenes (POMs). Inclusion of PAHs in the ices produces many species similar to those found in meteorites including aromatic alcohols, quinones and ethers. Photon assisted PAH-ice deuterium exchange also occurs. All of these species are readily formed and are therefore likely cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Milky Way 3-Helium Abundance

We are making precise determinations of the abundance of the light isotope of helium, ³He. The ³He abundance in Milky Way sources impacts stellar evolution, chemical evolution, and cosmology. The abundance of ³He is derived from measurements of the hyperfine transition of ³He⁺ which has a rest wavelength of 3.46 cm (8.665 GHz). As with all the light elements, the present interstellar ³He abundance results from a combination of Big Bang Nucleosynthesis (BBNS) and stellar nucleosynthesis. We are measuring the ³He abundance in Milky Way H ii regions and planetary nebulae (PNe). The source sample is currently comprised of 60 H ii regions and 12 PNe. H ii regions are examples of zero-age objects that are young relative to the age of the Galaxy. Therefore their abundances chronicle the results of billions of years of Galactic chemical evolution. PNe probe material that has been ejected from low-mass (M≤ 2M _⊙) to intermediate-mass (M∼2–5M _⊙) stars to be further processed by future stellar generations. Because the Milky Way ISM is optically thin at centimeter wavelengths, our source sample probes a larger volume of the Galactic disk than does any other light element tracer of Galactic chemical evolution. The sources in our sample possess a wide range of physical properties (including object type, size, temperature, excitation, etc.). The ³He abundances we derive have led to what has been called “The ³He Problem”.     

The Interior Structure, Composition, and Evolution of Giant Planets

We discuss our current understanding of the interior structure and thermal evolution of giant planets. This includes the gas giants, such as Jupiter and Saturn, that are primarily composed of hydrogen and helium, as well as the “ice giants,” such as Uranus and Neptune, which are primarily composed of elements heavier than H/He. The effect of different hydrogen equations of state (including new first-principles computations) on Jupiter’s core mass and heavy element distribution is detailed. This variety of the hydrogen equations of state translate into an uncertainty in Jupiter’s core mass of 18M _⊕ . For Uranus and Neptune we find deep envelope metallicities up to 0.95, perhaps indicating the existence of an eroded core, as also supported by their low luminosity. We discuss the results of simple cooling models of our solar system’s planets, and show that more complex thermal evolution models may be necessary to understand their cooling history. We review how measurements of the masses and radii of the nearly 50 transiting extrasolar giant planets are changing our understanding of giant planets. In particular a fraction of these planets appear to be larger than can be accommodated by standard models of planetary contraction. We review the proposed explanations for the radii of these planets. We also discuss very young giant planets, which are being directly imaged with ground- and space-based telescopes.     

Vibrational relaxation of CO2(m,nl, p) in a CO2N2 mixture. Part 2: Application to a one-dimensional problem

In order to quantify the relaxation mechanism of CO₂(m, n^l, p), the vibrational level populations are calculated for a particular test-case: the vibrational relaxation of a CO₂N₂ mixture along the stagnation streamline in a reentry problem. The N₂ species is chosen as a collision partner because it is a component existing in numerous gaseous mixtures (cf. Part. 1). Excitation and deexcitation processes are taken following Nickerson and Herzfeld. The Navier-Stokes code CELHYO for the simulation of hypersonic laminar viscous flows in chemical and thermal nonequilibrium is used with a new one-dimensional approach, reduction of the Navier-Stokes equations along the stagnation streamline. Mass fraction and ‘vibrational temperature’ distributions of every vibrational level, considered as an independent chemical species, are presented for the two different CO₂N₂ mixture compositions. The validity of the usual assumptions for the vibrational mechanism is examined on the basis of the obtained results.     

A spectroscopic analysis of B stars in the SMC cluster NGC 330

Medium resolution (2A/px) but high s/n spectra of approximately twenty of the brightest blue stars in the young open cluster NGC 330 in the SMC have been analyzed in order to determine their atmospheric parameters and the evolutionary status. Stellar parameters are determined by comparison with LTE and NLTE model atmosphere calculations and an HR diagram constructed. Luminosities of the sample stars lie in the range 4.0L _*/L )<5.0 and spectral types between O9 and late-B. The stars in our sample appear to define 4 groups: main-sequence B-stars (B2-B4), B-supergiants (B4) in a blue-loop phase of evolution, a small number of blue stragglers (O9-B0 near main-sequence stars) and a group of luminous giants (B1-B2) which reside in the so-called post main-sequence gap of the HR diagram. Furthermore, we have confirmed spectroscopically the very high incidence of Be stars in this cluster. Finally the almost complete absence of metal lines (at this resolution) is in keeping with the expected very low metallicity of the SMC.     

Primordial matter in the outer solar system: A study of its chemical composition from remote spectroscopic analysis

Our knowledge of the primordial matter from the objects of the outer solar system has made a considerable progress over the past years, in spite of the lack of any in situ measurements of these objects at the present time. The recent progress of ground-based instrumentation and the launch of the two Voyager fly-by missions have provided a huge amount of new informations about the origin and the evolution of the primitive Solar System objects.The most significant discoveries concerning the atmospheres of the Giant Planets can be summarized as follows: (1) there does not seem to be any differentiation in the internal structure of Jupiter during the planet's history; thus, the H₂/He ratio measured on Jupiter seems to be representative of the H/He ratio of the Primordial Nebula; (2) there is some evidence for a helium differentiation, relative to hydrogen, in Saturn's interior; (3) there seems to be a carbon enrichment on both Jupiter and Saturn by a factor about 2; this result is consistent with a model in which the planetary core is formed first, and the atmosphere accreted by this core in a second stage; (4) the D/H ratio measured on Jupiter should be representative of the D/H value in the Primordial Nebula, 4.5 billion years ago; this value is 2 to 5 times larger than the mean value measured in the local interstellar medium now; (5) Titan's atmosphere is dominated by nitrogen and contains traces of organic and prebiotic molecules (HCN, C₂N₂, HC₃N); the chemical composition of Titan's atmosphere could be favorable for the early stages of life development.The small bodies of the Solar System — asteroïds and comets — are still very poorly known. However they contain a key information about the physical and chemical properties of dust in the Primordial Nebula and the interstellar medium. With the launch of expected fly-by missions towards Comet Halley and, possibly, towards asteroïds, we may hope to know a new development of our understanding of these objects, comparable to the progress we have known on the Giant Planets over the past ten years.     

Molecular spectroscopy of planetary atmospheres

Summary Clearly spectroscopy has already provided considerable insight into the nature of the planetary atmospheres. Several molecular constituents have been positively identified and upper limits have been placed on the abundances of others which are of particular significance in devising planetary models. But, equally clearly, the inadequacy of the spectral data, due to low spectral and/or spatial resolution, renders deductions of abundances, temperatures and pressures very uncertain. With the sole exception of the Martian CO₂ abundance, knowledge of the concentrations of planetary atmospheric constituents is unsatisfactory, and all numbers given must be regarded as only crude estimates. This latter comment applies equally well to the derived temperatures and pressures.What is urgently needed is the development of a reasonably complete theory of line formation in planetary atmospheres. This, coupled with more detailed spectroscopic work, should produce numerical values of atmospheric parameters which can be used with assurance.This work was performed with the aid of NASA Grant NsG-101-61 with funds administered by the University of California.