Collisional excitation of vinylidene (H2CC)

Though H₂CO, H₂CS, H₂CCC, H₂CCCC, H₂CCO have been identified in cool interstellar molecular clouds, identification of H₂CC is still awaited. To analyze its spectrum, collisional rate coefficients are required. We have calculated collisional rate coefficients for rotational transitions between 23 levels of ortho and para H₂CC for kinetic temperatures 10, 20, 30, 40, and 50 K. The scattering problem is analyzed using the computer code MOLSCAT where the colliding partner is He atom. The interaction between H₂CC and He has been calculated with GAUSSIAN 2003. For the interaction potential obtained with GAUSSIAN 2003, MOLSCAT is used to derive the parameters q(L,M,M^′|E)$q(L\text{,}M\text{,}{M}^{\prime }|E)$ as a function of energy E   of the colliding partner. After averaging the parameters q(L,M,M^′|E)$q(L\text{,}M\text{,}{M}^{\prime }|E)$ over a Maxwellian distribution, the parameters Q(L,M,M^′|T)$Q(L\text{,}M\text{,}{M}^{\prime }|T)$ as a function of the kinetic temperature T in the cloud are obtained. Finally, the collisional rate coefficients have been calculated.