Thermospheric X-Ray and Euv Heating by the Young Sun on Early Venus and Mars

In view of the low H₂O abundance in the present Venusian and Martian atmospheres several observations by spacecraft and studies suggest that both planets should have lost most of their water over the early active period of the young Sun. During the first Gyr after the Sun arrived at the Zero- Age-Main-Sequence high X-ray and EUV fluxes between 10 and 100 times that of the present Sun were responsible for much higher temperatures in the thermosphere-exosphere environments on both planets. By applying a diffusive-gravitational equilibrium and thermal balance model for investigating radiation impact on the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by CO₂ IR emission in the 15μm band we found expanded thermospheres with exobase levels between about 200 km (present) and 2000 km (4.5 Gyr ago). The higher temperatures in the upper atmospheres of both planets could reach “blow-off” conditions for H atoms even at high CO₂ mixing ratios of 96%. Lower CO₂/N₂ mixing ratio or higher contents of H2O vapor in the early atmospheres could have had a dramatic impact from the loss of atmosphere and water on both planets. The duration of this phase of high thermal loss rates essentially depended on the mixing ratios of CO₂, N₂, and H₂O in the early atmospheres and could have lasted between about 150 and several hundred Myr.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Atmospheric/Exospheric Characteristics of Icy Satellites

The atmospheres/exospheres of icy satellites greatly vary from one to the next in terms of density, composition, structure or steadiness. Titan is the only icy satellite with a dense atmosphere comparable in many ways to that of the Earth’s atmosphere. Titan’s atmosphere prevents the surface from direct interaction with the plasma environment, but gives rise to Earth-like exchanges of energy, matter and momentum. The atmospheres of other satellites are tenuous. Enceladus’ atmosphere manifests itself in a large water vapor plume emanating from surface cracks near the south pole. Io’s SO₂ atmosphere originates from volcanoes. Europa’s tenuous O₂ atmosphere is produced by intense radiation bombardment. This chapter reviews the characteristics of the atmospheres of Titan, Enceladus, Io and Europa based on observations.     

Photochemistry in Outer Solar System Atmospheres

The photochemistries of the H₂-He atmospheres of the gas giants Jupiter, Saturn and ice giants Uranus and Neptune and Titan’s mildly reducing N₂ atmosphere are reviewed in terms of general chemical and physical principles. The thermochemical furnace regions in the deep atmospheres and the photochemical regions of the giant planets are coupled by vertical mixing to ensure efficient recyling of photochemical products. On Titan,mass loss of hydrogen ensures photochemical evolution of methane into less saturated hydrocarbons. A summary discussion of major dissociation paths and essential chemical reactions is given. The chapter ends with a overview of vertical transport processes in planetary atmospheres.     

Aeronomy of Extra-Solar Giant Planets

The intense stellar UV radiation field incident upon extra-solar giant planets causes profound changes to their upper atmospheres. Upper atmospheric temperatures can be tens of thousands of kelvins, causing thermal dissociation of H₂ to H. The stellar ionizing flux converts H to H⁺. The high temperatures also drive large escape rates of H, but for all but the planets with the smallest orbits, this flux is not large enough to affect planet evolution. The escape rate is large enough to drag off heavier atoms such as C and O. For very small orbits, when the hill sphere is inside the atmosphere, escape is unfettered and can affect planet evolution.     

Neutral Atmospheres

This paper summarizes the understanding of aeronomy of neutral atmospheres in the solar system, discussing most planets as well as Saturn’s moon Titan and comets. The thermal structure and energy balance is compared, highlighting the principal reasons for discrepancies amongst the atmospheres, a combination of atmospheric composition, heliocentric distance and other external energy sources not common to all. The composition of atmospheres is discussed in terms of vertical structure, chemistry and evolution. The final section compares dynamics in the upper atmospheres of most planets and highlights the importance of vertical dynamical coupling as well as magnetospheric forcing in auroral regions, where present. It is shown that a first order understanding of neutral atmospheres has emerged over the past decades, thanks to the combined effects of spacecraft and Earth-based observations as well as advances in theoretical modeling capabilities. Key gaps in our understanding are highlighted which ultimately call for a more comprehensive programme of observation and laboratory measurements.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Atmospheric Escape and Evolution of Terrestrial Planets and Satellites

The origin and evolution of Venus’, Earth’s, Mars’ and Titan’s atmospheres are discussed from the time when the active young Sun arrived at the Zero-Age-Main-Sequence. We show that the high EUV flux of the young Sun, depending on the thermospheric composition, the amount of IR-coolers and the mass and size of the planet, could have been responsible that hydrostatic equilibrium was not always maintained and hydrodynamic flow and expansion of the upper atmosphere resulting in adiabatic cooling of the exobase temperature could develop. Furthermore, thermal and various nonthermal atmospheric escape processes influenced the evolution and isotope fractionation of the atmospheres and water inventories of the terrestrial planets and Saturn’s large satellite Titan efficiently.     

The Voyager infrared spectroscopy and radiometry investigation

The infrared investigation on Voyager uses two interferometers covering the spectral ranges 60–600 cm^–1 (17–170 m) and 1000–7000 cm^–1 (1.4–10 m), and a radiometer covering the range 8000–25 000 cm^–1 (0.4–1.2 m). Two spectral resolutions (approximately 6.5 and 2.0 cm^–1) are available for each of the interferometers. In the middle of the thermal channel (far infrared interferometer) the noise level is equivalent to the signal from a target at 50 K; in the middle of the reflected sunlight channel (near infrared interferometer) the noise level is equivalent to the signal from an object of albedo 0.2 at the distance of Uranus.For planets and satellites with substantial atmospheres, the data will be used to investigate cloud and gas composition (including isotopic ratios), haze scale height, atmospheric vertical thermal structure, local and planetary circulation and dynamics, and planetary energy balance. For satellites with tenuous atmospheres, data will be gathered on surface and atmospheric composition, surface temperature and thermal properties, local and global phase functions, and surface structure. For Saturn's rings, the composition and radial structure, particle size and thermal characteristics will be investigated. Comparative studies of the planets and their satellite systems will be carried out.Paris Observatory.Cornell University.Jet Propulsion Laboratory.University of Maryland.     

Molecular spectroscopy of planetary atmospheres

Summary Clearly spectroscopy has already provided considerable insight into the nature of the planetary atmospheres. Several molecular constituents have been positively identified and upper limits have been placed on the abundances of others which are of particular significance in devising planetary models. But, equally clearly, the inadequacy of the spectral data, due to low spectral and/or spatial resolution, renders deductions of abundances, temperatures and pressures very uncertain. With the sole exception of the Martian CO₂ abundance, knowledge of the concentrations of planetary atmospheric constituents is unsatisfactory, and all numbers given must be regarded as only crude estimates. This latter comment applies equally well to the derived temperatures and pressures.What is urgently needed is the development of a reasonably complete theory of line formation in planetary atmospheres. This, coupled with more detailed spectroscopic work, should produce numerical values of atmospheric parameters which can be used with assurance.This work was performed with the aid of NASA Grant NsG-101-61 with funds administered by the University of California.     

Exploring The Saturn System In The Thermal Infrared: The Composite Infrared Spectrometer

The Composite Infrared Spectrometer (CIRS) is a remote-sensing Fourier Transform Spectrometer (FTS) on the Cassini orbiter that measures thermal radiation over two decades in wavenumber, from 10 to 1400 cm^{− 1} (1 mm to 7μ m), with a spectral resolution that can be set from 0.5 to 15.5 cm^{− 1}. The far infrared portion of the spectrum (10–600 cm^{− 1}) is measured with a polarizing interferometer having thermopile detectors with a common 4-mrad field of view (FOV). The middle infrared portion is measured with a traditional Michelson interferometer having two focal planes (600–1100 cm^{− 1}, 1100–1400 cm^{− 1}). Each focal plane is composed of a 1× 10 array of HgCdTe detectors, each detector having a 0.3-mrad FOV. CIRS observations will provide three-dimensional maps of temperature, gas composition, and aerosols/condensates of the atmospheres of Titan and Saturn with good vertical and horizontal resolution, from deep in their tropospheres to high in their mesospheres. CIRS’s ability to observe atmospheres in the limb-viewing mode (in addition to nadir) offers the opportunity to provide accurate and highly resolved vertical profiles of these atmospheric variables. The ability to observe with high-spectral resolution should facilitate the identification of new constituents. CIRS will also map the thermal and compositional properties of the surfaces of Saturn’s icy satellites. It will similarly map Saturn’s rings, characterizing their dynamical and spatial structure and constraining theories of their formation and evolution. The combination of broad spectral range, programmable spectral resolution, the small detector fields of view, and an orbiting spacecraft platform will allow CIRS to observe the Saturnian system in the thermal infrared at a level of detail not previously achieved.This revised version was published online in July 2005 with a corrected cover date.     

可重复使用热防护材料应用与研究进展

可重复使用热防护系统是为高速重复使用飞行器而发展的关键性技术,涵盖了地球大气环境及非地球大气环境下的弹道式再入、高马赫数巡航等应用场景。根据现有高马赫数飞行器热防护现状,对高马赫数飞行器的主要热防护系统类型、特点和使用场景进行了简要介绍。在此基础上,结合国外里程碑式可重复使用飞行器（X-15、SR-71、航天飞机、X-33、X-37B、Spaceliner等）,梳理了可重复使用热防护材料的应用与研究进展,论述了代表性可重复使用热防护材料的发展、性能、研制进度、特点及应用前景。对国外在可重复使用热防护材料研制中的设计及发展思路,以及所存在的主要问题进行了总结归纳,为可重复使用热防护材料未来的发展提供了思路。     

Spectral analyses of Wolf-Rayet stars: Theory,results, conclusions

Stratified Non-LTE models for expanding atmospheres became available in the recent years. They are based on the idealizing assumptions of spherical symmetry, stationarity and radiative equilibrium. From a critical discussion we conclude that this standard model is basically adequate for describing real Wolf-Rayet atmospheres and hence can be applied for quantitative spectral analyses of their spectra.By means of these models, the fundamental parameters have been determined meanwhile for the majority of the known Galactic WR stars. Most of them populate a vertical strip in the Herzsprung-Russell diagram at effective temperatures of 35 kK, the luminosities ranging from 10^4.5 to 10^5.9 L . Only early-type WN stars with strong lines and WC stars are hotter. The chemical composition of WR atmospheres corresponds to nuclear-processed material (WN: hydrogen burning in the CNO cycle; WC: helium burning). Hydrogen is depleted but still detectable in the cooler part of the WN subclass.Different scenarios for the evolutionary formation of the Wolf-Rayet stars are discussed in the light of the empirical data provided from the spectral analyses. Post-red-supergiant evolution can principally explain the basic observational properties, except the rather low luminosities of a considerable fraction of WN stars. Among the alternative scenarios, close-binary evolution can theoretically produce the least-luminous WN stars. However, final conclusions about the evolutionary formation of the WR stars are not yet possible.     

The absolute magnitudes of RR Lyrae stars

A theoretical counterpart to the Barnes-Evans relation between stellar surface brightness and V-R color has been calculated from model atmospheres for parameters appropriate to RR Lyrae stars. Such a relation can be used to derive stellar angular diameters from V,R photometry and, when applied to variable stars and combined with a radial velocity curve, to derive radii, distances, and absolute magnitudes by the method of Barnes et al. (1977, MNRAS,178, 661). This was done for RR Lyr and X Ari using the photometry of Moffett and Barnes (1980, private communication) and radial velocities from the literature. The resulting absolute magnitudes are M_v = ± 0.59 + 0.25 for X Ari and M_v = 0.61 ± 0.35 for RR Lyr. The method is shown to be a very accurate way of determining radii, distances, and absolute magnitudes for RR Lyrae stars which compares very favorably to the variations of the Baade-Wesselink technique currently in use.     

The gravity-darkening of the main-sequence components of spectral types A,F and G in detached close binary systems

From analysis of the photometric ellipticity effect in seven well-understood detached close binary systems, empirical values of the exponent α of gravity-darkening have been practically deduced for eleven main-sequence components of spectral types A, F and G which should cover the range of structural change (from radiative to convective) in stellar atmospheres. The result indicate that values of the exponent diminish gradually with decreasing effective temperatures from α ～ 1.0 for radiative atmospheres with T > 8500 K to α = 0.2 ～ 0.3 for convective atmospheres with T < 6500 K, in spite of some uncertainty in the reflection correction process.     

The ionospheres of the major planets

Physical and chemical processes which affect the equilibrium distribution of ionization in the atmospheres of Jupiter, Saturn, Uranus and Neptune are reviewed. Current models imply readily detectable ionospheres for all four planets and suggest that protons should represent the dominant positive ion. Attention is directed to the probable importance of dissociative ionization of H₂ as a source of H⁺. A number of potentially important loss mechanisms for H⁺ are discussed including a possible reaction of H⁺ with vibrationally excited H₂. Protons may be removed efficiently at lower altitudes by reaction with CH₄ and this process may offer a simple remote means for location of the turbopause.This is one of the publications by the Science Advisory Group.     

The stellar content of the Orion OB1 association

We present a photometric investigation, using the VBLUW system, of the stellar content of Orion OB1. Physical parameters (logg, logT _eff) for the stars are derived with the aid of model atmospheres. From these, visual extinctions, absolute magnitudes and distance moduli are derived. The distance moduli are used to determine membership for the stars in each of the subgroups and distances to the subgroups are calculated. The ages of the subgroups are derived through isochrone fitting and the IMF is derived for each subgroup. The energy deposited into the ISM through stellar winds and supernovae is calculated and compared to observed large scale features in the ISM around Orion OB1.     

新型轻质隔热、透波Al-B-O 陶瓷的研究进展

Al5BO9、Al4B2O9等Al-B-O体系硼莫来石陶瓷具有低密度、低热导率、宽带隙等优异性能,在飞行器的隔热、透波、热密封等领域具有广泛的应用前景。本文系统介绍了这类新材料的结构、性能和制备方法。在理论计算方面,介绍了基于密度泛函理论的第一性原理计算对Al-B-O体系材料晶体结构、力学和热学性能的预测;实验方面,总结了固相反应、熔盐法、溶胶-凝胶法、热分解法和水热法等制备方法和力学、热学等实验结果,并讨论了该体系化合物的应用现状及未来发展方向。     

等离子喷涂LaTi2Al9O19热障涂层的微观组织结构及热物理性能

 第一代热障涂层(TBCs)由氧化钇部分稳定的氧化锆(YSZ)陶瓷隔热层和金属粘结层组成,该涂层长期使用温度低于1 200℃。随着先进航空发动机向着高推重比发展,迫切要求发展新一代超高温、高隔热热障涂层材料。LaTi₂Al₉O₁₉(LTA)在1 500℃长期保持相稳定,是一种非常有前景的超高温热障涂层候选材料。本文采用大气等离子喷涂(APS)制备了LTA涂层,研究了喷涂工艺对涂层微观组织结构和热物理性能的影响。结果表明沉积态涂层中含少量的非晶态,在860℃和1 130℃出现晶化峰。等离子喷涂过程中La₂O₃挥发量较多,导致沉积态涂层中La元素与原始粉末相比含量偏低,而其他组分的化学成分随喷涂功率变化不大。LTA涂层的热扩散系数在1 400℃下为0.3~0.4 mm²·s^-1,热导率为1.1~1.6 W·m^-1·K^-1。1 050℃经过20小时热处理后,得到晶化的涂层在晶化温度范围内的热扩散系数和热导率值均增大。随着喷涂功率减小,涂层孔隙率增加,热导率减小。     

低密度气凝胶复合材料的火星环境适应性研究

针对航天器的使用要求,研制了密度≤30 kg/m~3轻质高效的二氧化硅气凝胶复合材料。针对深空探测的应用环境,对低密度气凝胶复合材料在不同条件下的热导率、热循环、热真空和电离总剂量等环境试验进行测试。结果表明,低密度气凝胶复合材料服役温度可达到-145～85℃,在1 kPa CO_2气氛下热导率可达到6.6 mW/(m·K)。获得了不同气氛和不同温度条件下以及同种气氛、不同压力条件下低密度气凝胶复合材料的热导率变化规律,并测试批次性材料热导率,结果表明批次热导率稳定性良好。热循环、热真空和电离辐照试验前后热导率和尺寸收缩率均未变化,表明低密度气凝胶复合材料在深空环境下保持良好的结构和稳定的隔热性能。