Experimental study on NOx emission correlation of fuel staged combustion in a LPP combustor at high pressure based on NO-chemiluminescence

Experimental investigations on NO_x emissions of a single-cup, Lean Premixed Prevaporized (LPP), module combustor were carried out at elevated inlet temperature and pressure up to 810 K and 2.0 MPa, close to the real operating conditions of aero-engine combustors. This LPP combustor adopts centrally staged fuel injections which could produce separated stratified swirling spray flame. In the NO_x emissions measurements, the ranges of dome equivalence ratio and fuel stage ratio were from 0.55 to 0.58 and 8% to 24%, respectively. The optical diagnosis on separated stratified swirling spray flame were carried out with fuel stage ratio changing from 15% to 30%. Therefore, NO* and OH* chemiluminescence images were obtained. The results show that NO_x emissions increase with the increase of the fuel stage ratio. And from the chemiluminescence images, the main flame and pilot flame are found weakly coupled. The pilot flame plays a significant role in NO_x emission production because of its higher adiabatic flame temperature. Based on the results of chemiluminescence optical tests, a new NO_x emission prediction model is proposed based on the Lefebvre’s single flame model. The estimate of local equivalence ratio of the pilot stage’s non-premixed flame is modified considering the characteristics of spray combustion, and a “PLUS” emission prediction model suitable for separated stratified swirling spray flame is obtained. Compared to the experimental data, the “PLUS” model exhibits a good prediction in a range of ±13% of deviation.     

Evolution of Interstellar Ices

Infrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Ices in molecular clouds are dominated by the very simple molecules H₂O, CH₃OH, NH₃, CO, CO₂, and probably H₂CO and H₂. More complex species including nitriles, ketones, and esters are also present, but at lower concentrations. The evidence for these, as well as the abundant, carbon-rich, interstellar, polycyclic aromatic hydrocarbons (PAHs) is reviewed. Other possible contributors to the interstellar/pre-cometary ice composition include accretion of gas-phase molecules and in situ photochemical processing. By virtue of their low abundance, accretion of simple gas-phase species is shown to be the least important of the processes considered in determining ice composition. On the other hand, photochemical processing does play an important role in driving dust evolution and the composition of minor species. Ultraviolet photolysis of realistic laboratory analogs readily produces H₂, H₂CO, CO₂, CO, CH₄, HCO, and the moderately complex organic molecules: CH₃CH₂OH (ethanol), HC(=O)NH₂ (formamide), CH₃C(=O)NH₂ (acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C₆H₁₂N₄), as well as more complex species including amides, ketones, and polyoxymethylenes (POMs). Inclusion of PAHs in the ices produces many species similar to those found in meteorites including aromatic alcohols, quinones and ethers. Photon assisted PAH-ice deuterium exchange also occurs. All of these species are readily formed and are therefore likely cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

民用飞机全航线排放预测

针对民用飞机全航线的排放预测问题,运用飞机升阻特性模型、发动机性能模型和飞机航线性能模型计算了民用飞机在全航线上的飞机升阻特性与发动机性能,并将以上模型与基于T₃-p₃法与波音流量法所建立的排放计算模型相耦合,详细计算了飞机在实际飞行过程中未燃碳氢化合物(UHC)、一氧化碳(CO)、氮氧化合物(NOx)的排放指数,并得到了全航线的各种污染排放物排放总量,完善了民用航空发动机排放预测分析体系,为低污染民用航空发动机的设计与评估提供理论依据.计算结果表明,飞机处在起飞以及爬升阶段时,NOx的排放指数较高,而UHC与CO的排放指数较低;当飞机处在下降以及进场时,NOx的排放指数较低,而UHC与CO的排放指数较高.NOx的总排放量在3种污染排放产物中最高.      

Thermal radio emission from the major planets

The use of long-wavelength radio measurements of brightness temperature to remotely measure the thermal structure of the atmospheres of the major planets at great depths (>10 atm.) is discussed. Data are presented which show that the gross features of Jupiter's and Saturn's microwave spectra, as determined from ground based observations, can be explained in terms of thermal emission from ammonia in deep convective atmospheres of He and H₂.This is one of the publications by the Science Advisory Group.     

Combustion mechanism of fluorinated organic compound-modified nano-aluminum composite particles: Towards experimental and theoretical investigations

Fluorinated Organic Compounds (FOCs) are commonly used as modifiers for Aluminum (Al) powder to improve its ignition, combustion, and agglomeration characteristics. However, the effects of FOCs on combustion and inhibition mechanisms of agglomeration of Al powder are not well understood. In this paper, based on the experimental study of Fluorinated Graphite (FG)-modified Al matrix composite particles, the combustion and aggregation inhibition mechanisms of FOCs on Al particles were studied by the quantum chemical calculation at B3LYP/6-311+G(d,P) and G3//B3LYP/6-311+G(d,p) levels. The flame behavior and single particle burning behavior of FG-modified samples were compared through ignition experiments, and the characteristic spectra of Al related oxides of different samples in the initial ignition stage were captured. It is found that FG increases the burning intensity of Al composite samples significantly, while it decreases the emission intensity of Al secondary oxides. Quantum chemical calculation results show that the thermal decomposition intermediates of FOCs, namely C₂F₄, can react with AlO and Al₂O, which weakens the characteristic emission intensity of AlO and Al₂O in the sample, and thus inhibits the formation of Al₂O₃ in the combustion process. These results contribute to enriching the combustion dynamics model of Al-FOCs reaction system.     

Composition and Measurement of Charged Atmospheric Clusters

Atmospheric charged clusters are formed in a series of rapid chemical reactions after ionisation, leaving a central ion X⁺ or X^? clustered with n ligands (Y) _n . In solar system tropospheres and stratospheres there are two distinct cluster regimes: the terrestrial planets contain largely hydrated clusters (i.e. Y=H₂O), whereas the gas planets and their moons have organic or nitrogenated cluster species. These classifications are largely based on model predictions, since hardly any measurements are available. The few existing composition measurements are reviewed, including the recent detection of massive charged particles in Titan’s upper atmosphere. Technologies for both remote sensing and in situ measurements of atmospheric charged clusters are discussed. Preliminary measurements in the terrestrial atmosphere are presented indicating that ambient charged cluster species interact with downwelling infra-red radiation at 9.15 μm, even in the presence of cloud. This supports the possibility of future infrared detection of charged clusters.     

Ignition enhancement of ethylene/air by NOx addition

Recently, non-equilibrium plasma assisted combustion (PAC) has been found to be promising in reducing the ignition delay time in hypersonic propulsion system. NO x produced by non-equilibrium plasma can react with intermediates during the fuel oxidation process and thereby has influence on the combustion process. In this study, the effects of NO x addition on the ignition process of both the homogeneous ethylene/air mixtures and the non-premixed diffusion layer are examined numerically. The detailed chemistry for ethylene oxidization together with the NO x sub-mechanism is included in the simulation. Reaction path analysis and sensitivity analysis are conducted to give a mechanistic interpretation for the ignition enhancement by NO x addition. It is found that for both the homogenous and non-premixed ignition processes at normal and elevated pressures, NO 2 addition has little influence on the ignition delay time while NO addition can significantly promote the ignition process. The ignition enhancement is found to be caused by the promotion in hydroxyl radical production which quickly oxidizes ethylene. The promotion in hydroxyl radical production by NO addition is achieved in two ways:one is the direct production of OH through the reaction HO2+NO = NO2+OH, and the other is the indirect production of OH through the reactions NO+O2=NO2+O and C2H4+O = C2H3+OH. Moreover, it is found that similar to the homogeneous ignition process, the acceleration of the diffusion layer ignition is also controlled by the reaction HO2+NO = NO2+OH.     

CCD spectroscopy of the W Serpentis binaries KX And and RX Cas

Initial results are presented from a study of H _γ profiles in the two interacting binaries KX And and RX Cas of W Serpentis type. The used CCD spectra with a resolution of 0.13Å/px were obtained with the 2.2m telescope and the Coudé spectrograph at the German-Spanish Astronomical Center at Calar Alto/Spain. KX And. This star is probably a non-eclipsing member of the W Serpentis type interactive binaries and has a period of P = 38.908 days. Our seven spectra of KX And were obtained at phase 0.54 – 0.75. The P Cyg profiles of the H _γ line during our observations indicate an expanding shell. The asymetry becomes blue-sided at phase 0.67 and increases thereafter. This points toward a strong outflow of matter in the vicinity of the L3 point. RX Cas. According to the model of Andersen et al. (1988) the primary is a mid-B type star with M = 5.8M _⊙ and R = 2.5R _⊙. The star is completely obscured by a geometrically and optically thick disk, which is supplied by mass transfer from the other component. The secondary is a K1 giant with M = 1.8M _⊙ and R = 23.5R _⊙ and fills out his critical Roche lobe. Radiative and geometrical properties of the disk are variable and its structure is probably not homogenous. Five spectra of RX Cas were obtained during the primary eclipse (phase 0.95 – 0.19). The observed double-peak emission is seen only after the eclipse with a separation of ≈ 250 km/s peak-to-peak, while during the eclipse an asymetric line profile can be observed with a red-shifted emission always presented. Also, a central emission at φ = 0.94 should be noticed, probably originating in the vicinity of L1. The observations of both systems indicate that we are dealing with strongly interacting binaries. Further observations are planned for better covering of phase.     

MIRO: Microwave Instrument for Rosetta Orbiter

The European Space Agency Rosetta Spacecraft, launched on March 2, 2004 toward Comet 67P/Churyumov-Gerasimenko, carries a relatively small and lightweight millimeter-submillimeter spectrometer instrument, the first of its kind launched into deep space. The instrument will be used to study the evolution of outgassing water and other molecules from the target comet as a function of heliocentric distance. During flybys of the asteroids (2867) Steins and (21) Lutetia in 2008 and 2010 respectively, the instrument will measure thermal emission and search for water vapor in the vicinity of these asteroids. The instrument, named MIRO (Microwave Instrument for the Rosetta Orbiter), consists of a 30-cm diameter, offset parabolic reflector telescope followed by two heterodyne receivers. Center-band operating frequencies of the receivers are near 190 GHz (1.6 mm) and 562 GHz (0.5 mm). Broadband continuum channels are implemented in both frequency bands for the measurement of near surface temperatures and temperature gradients in Comet 67P/Churyumov-Gerasimenko and the asteroids (2867) Steins and (21) Lutetia. A 4096 channel CTS (Chirp Transform Spectrometer) spectrometer having 180 MHz total bandwidth and 44 kHz resolution is, in addition to the continuum channel, connected to the submillimeter receiver. The submillimeter radiometer/spectrometer is fixed tuned to measure four volatile species – CO, CH₃OH, NH₃ and three, oxygen-related isotopologues of water, H₂ ¹⁶O, H₂ ¹⁷O and H₂ ¹⁸O. The basic quantities measured with the MIRO instrument are surface temperature, gas production rates and relative abundances, and velocity and excitation temperature of each species, along with their spatial and temporal variability. This paper provides a short discussion of the scientific objectives of the investigation, and a detailed discussion of the MIRO instrument system.     

Infrared Spectroscopy of Solar-System Planets

Most of our knowledge regarding planetary atmospheric composition and structure has been achieved by remote sensing spectroscopy. Planetary spectra strongly differ from one planet to another. CO₂ signatures dominate on Mars, and even more on Venus (where the thermal component is detectable down to 1 μm on the dark side). Spectroscopic monitoring of Venus, Earth and Mars allows us to map temperature fields, wind fields, clouds, aerosols, surface mineralogy (in the case of the Earth and Mars), and to study the planets’ seasonal cycles. Spectra of giant planets are dominated by H₂, CH₄ and other hydrocarbons, NH₃, PH₃ and traces of other minor compounds like CO, H₂O and CO₂. Measurements of the atmospheric composition of giant planets have been used to constrain their formation scenario.     

Molecular Hydrogen

Observations of H₂ line emission in galactic and extragalactic environments obtained with the Infrared Space Observatory (ISO) are reviewed. The diagnostic capability of H₂ observations is illustrated. We discuss what one has learned about such diverse astrophysical sources as photon-dominated regions, shocks, young stellar objects, planetary nebulae and starburst galaxies from ISO observations of H₂ emission. In this context, we emphasise use of measured H₂ line intensities to infer important physical quantities such as the gas temperature, gas density and radiation field and we discuss the different possible excitation mechanisms of H₂. We also briefly consider future prospects for observation of H₂ from space and from the ground. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Model simulations of fuel sulfur conversion efficiencies in an aircraft engine: Dependence on reaction rate constants and initial species mixing ratios

The fuel sulfur conversion efficiency ε behind the combustor of a JT9D-7A aircraft engine in flight has been simulated using an extended exhaust plume chemistry model. The model simulations start in the high-temperature intra-engine regime behind the combustor. The simulations show that the sulfur conversion efficiency is sensitively dependent on model assumptions like reaction rate constants and initial mixing ratios. Sensitivity studies to demonstrate the effect of the uncertainties and variabilities of these parameters on ε are presented. Among the rate constants k, the uncertainty of the reaction rate constant for SO₂ + OH + M → HSO₃ + M has the greatest effect on ε: The uncertainty of k(SO₂ + OH) results in an uncertainty range of 1.1% <ε<6.2% for our simulation scenario, with a most probable value around 3.8%. The effect of the reaction SO₂ + O + M → SO₃ + M on ε is very small if the initial mixing ratio of O is smaller than that of OH. Among the initial mixing ratios, the variation of the initial OH mixing ratio OH₀ has the greatest effect on ε. For our simulation scenario, the uncertainty range of 5.7 ppmv < OH₀ < 14.7 ppmv (inferred from measurements) leads to an uncertainty range of 2.7% <ε<5.0%.     

Radiolysis and Photolysis of Icy Satellite Surfaces: Experiments and Theory

The transport and exchange of material between bodies in the outer solar system is often facilitated by their exposure to ionizing radiation. With this in mind we review the effects of energetic ions, electrons and UV photons on materials present in the outer solar system. We consider radiolysis, photolysis, and sputtering of low temperature solids. Radiolysis and photolysis are the chemistry that follows the bond breaking and ionization produced by incident radiation, producing, e.g., O₂ and H₂ from irradiated H₂O ice. Sputtering is the ejection of molecules by incident radiation. Both processes are particularly effective on ices in the outer solar system. Materials reviewed include H₂O ice, sulfur-containing compounds (such as SO₂ and S₈), carbon-containing compounds (such as CH₄), nitrogen-containing compounds (such as NH₃ and N₂), and mixtures of those compounds. We also review the effects of ionizing radiation on a mixture of N₂ and CH₄ gases, as appropriate to Titan’s upper atmosphere, where radiolysis and photolysis produce complex organic compounds (tholins).     

The Hydrogen Exospheric Density Profile Measured with ASPERA-3/NPD

We have evaluated the Lyman-α limb emission from the exospheric hydrogen of Mars measured by the neutral particle detector of the ASPERA-3 instrument on Mars Express in 2004 at low solar activity (solar activity index = 42, F_10.7=100). We derive estimates for the hydrogen exobase density, n _H = 10¹⁰ m^?3, and for the apparent temperature, T > 600 K. We conclude that the limb emission measurement is dominated by a hydrogen component that is considerably hotter than the bulk temperature at the exobase. The derived values for the exosphere density and temperature are compared with similar measurements done by the Mariner space probes in the 1969. The values found with Mars Express and Mariner data are brought in a broader context of exosphere models including the possibility of having two hydrogen components in the Martian exosphere. The present observation of the Martian hydrogen exosphere is the first one at high altitudes during low solar activity, and shows that for low solar activity exospheric densities are not higher than for high solar activity.     

Coronal activity in F-, G-, and K-type stars

Summary Soft X-ray (0.3–3.5 keV) observations with the Imaging Proportional Counter (IPC) onboard Einstein Observatory are presented for a sample of some 20 cool stars of luminosity classes III–V. The results are compared with the Ca II H and K emission, which had served as a selection criterion.The specific X-ray flux F_X is an increasing function of the specific Ca II H and K line-core flux F_H+K. This correlation can be considerably improved by replacing F_H+K by the excess flux (F_H+K) above a certain lower limit which varies with B-V. This relation holds with little scatter over the two decades in F_X in our sample. The F_X-F_H+K relation shows no significant dependence on spectral type or luminosity class, it suits close binaries as well as single stars. However, the coronal X-ray temperature T_c strongly depends on the luminosity class: T_c 3 10⁶ K for dwarfs and 10⁷ K for giants.The results are interpreted in the framework of magnetic activity. The X-ray emission and the excess Ca II H and K flux are attributed to magnetic structure in the corona and chromosphere, the magnetic features emerging from the stellar convective envelope, where they are generated by dynamo action.     

Pollution of the upper atmosphere by rockets

This report estimates the amounts of various constituents that would have to be continually injected by rockets into the upper atmosphere in order to double the worldwide natural concentrations there. Involved in the calculations are: (a) the natural atmospheric abundances of constituents such as H₂O, CO₂, NO, Na, K, Li, H, etc.; (b) the residence times in various regions of the atmosphere, since these determine how rapidly a constituent will be removed; and (c) the chemical or photochemical stability of a substance exposed to the upper atmosphere environment. It is concluded that a doubling of the CO₂, H₂O, or NO content would require per year on the order of 10³ to 10⁵ Saturn-type rockets, each injecting 100 tons of exhaust above 100 km. On the other hand, a few hundred small rockets per year, each containing 10 kg of the chemical, would probably double the Na content; similarly, less than two such rockets per year would be expected to double the Li content. These last conclusions have implications for future tracer experiments using these substances.The author is now an Associate Director of the National Center for Atmospheric Research (NCAR) in Boulder, Colorado. The work reported here was supported by the United States Air Force under Contract AF 49(638)-700 with the RAND Corporation. The views or conclusions contained in this paper should not, however, be interpreted as representing the official opinion of the United States Air Force.     

Large-scale structure of the Galaxy and high-energy gamma-ray observations

Detailed information on the high-energy gamma-ray emission from our Galaxy has become available through the two dedicated satellite missions SAS-2 and COS-B. The consistency of the two datasets is discussed; while a satisfying general agreement is observed, a few distinct discrepancies point to possible time variations within the compact source component of the total galactic emission. The bulk of emission appears very well correlated to the column density of the total interstellar gas, as traced by radio observations of Hi and CO. The gamma-ray observations exclude the possibility that H₂ dominates in the inner Galaxy, its mass should not exceed the mass existing in the form of Hi. Neither a significant galactocentric gradient of the (high-energy) cosmic-ray flux density is suggested inside the solar circle (outside a decrease is needed), nor a linear coupling between the cosmic rays and the gas is indicated by the gamma-ray data. The systematic variation with longitude of the spectrum of the gamma-ray emission points to an increased flux of cosmic-ray electrons in the 100 MeV to 1 GeV energy range in regions where dense clouds are concentrated. The variation could as well be due to the largely unresolved population of compact gamma-ray objects.     

The Stratospheric and Mesospheric NOy in the 2002–2004 Polar Winters as measured by MIPAS/ENVISAT

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on board ENVISAT, provided global (pole-to-pole, the polar night winter regions) measurements of nearly all constituents of the NO_y family (including NO, NO₂, HNO₃ and H₂O₅) from July 2002 to the end of March 2004 from the upper stratosphere up to the middle mesosphere. The inter-annual variability of the NO₂ and HNO₃ abundances in the Arctic and Antarctic winters from September 2002 through March 2004 was enormous with tremendous hemispheric asymmetry and extraordinary values in two winters. The origin of these variations and of the extreme measured values has been analyzed on the basis of the changing atmospheric dynamics (using the CH₄ tracer) and solar activity, including the extraordinary solar protons events of Oct–Nov 2003.     

Presupernova evolution of the most massive stars

Taking as example a 60M _⊙ star of solar metallicity, the state of the art of model calculations for very massive, from the main sequence to the supernova stage, is reviewed. It is argued that — due to the simple internal structure of Wolf-Rayet stars — the post main sequence evolutionary phases are currently those which are better understood. A brief discussion of the supernova outcome from very massive stars is given. Then, the more uncertain main sequence evolution is discussed. A first attempt to incorporate results about pulsational instabilities of very massive stars in stellar evolutionary calculations is performed. On its basis, a new type of evolutionary sequence for very massive stars is obtained, namely O-star → Of-star → H-rich WNL → LBV → H-poor WNL → WNE → WC → SN. This scenario is shown to correspond better to many observed properties of very massive stars than the standard one. It includes a model for the prototype LBV P Cygni.