Interstellar hydrogen bonding

This paper reports the first extensive study of the existence and effects of interstellar hydrogen bonding. The reactions that occur on the surface of the interstellar dust grains are the dominant processes by which interstellar molecules are formed. Water molecules constitute about 70% of the interstellar ice. These water molecules serve as the platform for hydrogen bonding. High level quantum chemical simulations for the hydrogen bond interaction between 20 interstellar molecules (known and possible) and water are carried out using different ab-intio methods. It is evident that if the formation of these species is mainly governed by the ice phase reactions, there is a direct correlation between the binding energies of these complexes and the gas phase abundances of these interstellar molecules. Interstellar hydrogen bonding may cause lower gas abundance of the complex organic molecules (COMs) at the low temperature. From these results, ketenes whose less stable isomers that are more strongly bonded to the surface of the interstellar dust grains have been observed are proposed as suitable candidates for astronomical observations.     

空间尘埃的充电过程及与等离子体参数的关系

考虑了地球附近的彗星、行星环、行星际介质等空间尘埃等离子体环境中尘埃颗粒的充电问题．应用典型的空间尘埃等离子体参数，计算了不同种类的尘埃颗粒，以及不同等离子体成分下等离子体中尘粒的平衡电势，得到了尘埃颗粒的平衡电势与尘埃等离子体成分、温度，及其他等离子体参数之间的相互关系．     

Formation of amino acid precursors in cometary ice environments by cosmic radiation.

Cometary ices are believed to contain water, carbon monoxide, methane and ammonia, and are possible sites for the formation and preservation of organic compounds relating to the origin of life. Cosmic rays, together with ultraviolet light, are among the most effective energy sources for the formation of organic compounds in space. In order to study the possibility of the formation of amino acids in comets or their precursory bodies (interstellar dust grains), several types of ice mixtures made in a cryostat at 10 K ("simulated cometary ices") were irradiated with high energy protons. After irradiation, the volatile products were analyzed with a quadrupole mass spectrometer, while temperature of the cryostat was raised to room temperature. The non-volatile products remaining in the cryostat at room temperature were collected with water. They were acid-hydrolyzed, and analyzed by ion-exchange chromatography. When an ice mixture of carbon monoxide (or methane), ammonia and water was irradiated, some hydrocarbons were formed, and amino acids such as glycine and alanine were detected in the hydrolyzate. These results suggest the possible formation of "amino acid precursors" (compounds yielding amino acids after hydrolysis) in interstellar dust grains by cosmic radiation. We previously reported that amino acid precursors were formed when simulated primitive planetary atmospheres were irradiated with cosmic ray particles. It will be of great interest to compare the amount of bioorganic compounds that were formed in the primitive earth and that brought by comets to the earth.     

On the possible detection of solid O2 and O3 interstellar grains with ISO

In various models of interstellar grain chemistry, solid O₂ is formed by accretion as well as by surface reactions on grains. In dense molecular cloud models, at a later stage of the evolution, the O₂ molecule may become a substantial grain mantle constituent. Since IR dipole vibrational transitions for the homonuclear diatomic molecule O₂ are forbidden, the abundance of this potentially important grain mantle component can not be determined. However, embedded in a dirty ice matrix, the fundamental vibration of O₂ at 1550 cm⁻¹ becomes observable at 10 K, due to interactions with surrounding molecules, which break the symmetry of molecular oxygen. This process might be applicable for the dust mantle environment of interstellar grains. We have studied the role of solid O₂ and O₃ in astrophysically relevant ice mixtures and discuss the possible detection of solid O₂ and its major photolysis product O₃ in interstellar grains, in dense molecular clouds. Both molecules represent a specific target to be observed by the ISO satellite in the near future.     

Impacts of the PAH size and the radiation intensity on the IR features of illuminated dust within the reflection nebulae

Interstellar dust grains are illuminated in the reflection nebulae. Under conditions of the PAH size and the intensity of the interstellar radiation field, we follow their impact on the PAH aromatic infrared bands using the numerical DustEM code. For a dust model consisting of PAH, amorphous C and amorphous silicate, the PAH size varies in a range from 0.31 to 4.9 nm while the radiation intensity varies by a scale factor from 0.1 to 10⁴. Various trends of the results show the effect of varying both the PAH size and the radiation intensity on the strength of the aromatic mid-IR bands. Through small PAH sizes less than 0.7 nm, the grain temperature distribution of PAHs shows a small variation within 2–3 K at low radiation intensity while it increases to 15 and 8 K for PAH⁰ and PAH⁺, respectively, at higher radiation intensity. In final the variability in these results reveals the evolution of the dust grains under the physical space conditions of the reflection nebulae. In the mid-IR region, the contributions of PAH⁰ and PAH⁺ in the total SED intensity agree with the proportions of these PAHs observed in some reflection nebulae having higher radiation intensities.     

Interactions of solar wind plasma with dust grains: Effects of strong plasma anisotropy

In this paper we re-examined the fundamental physics of charging of a dust particle in the moon environment by tenuous anisotropic solar wind plasma. The majority of work on dusty (complex) plasmas is largely concerns with laboratory plasmas, in which charging process of dust grains is very fast, thus making practical the working concept of dynamically equilibrium floating potential and grain charge. However, solar wind plasma parameters are considerably different at the moon orbit, and we found the characteristic charging time of lunar dust grains to be considerably longer, ranging from 3 to 4.6 min for micron size particles, and up to 7.6 h for 10-nm grains, depending on the value of plasma streaming velocity. These findings make it clear that the transient stage of charging process is important in the moon environment, and equilibrium floating potential and grain charge could be considered as long time asymptotic values. For this reason we re-formulated the moon dust charging process as an inherently time-dependent problem and derived the time-dependent charging equation for the grain potential for general case of anisotropic solar wind plasma. Using the results of our kinetics analysis we found that the distribution of charge density over grain surface submerged into solar wind plasma is highly anisotropic, thus making the OML model, which is based on the assumption of isotropic distribution of surface charge density, not applicable to the grain charging problem by the solar wind plasma.     

Models of P/Borrelly: Activity and dust mantle formation

Comet 19P/Borrelly was observed by Deep Space One spacecraft on September 22, 2001 (Soderblom et al., 2002).The DS1 images show a very dark and elongate nucleus with a complex topography; the IR spectra show a strong red-ward slope consistent with a very hot and dry surface (345K to 300K). During DS1 encounter the comet coma was dominated by a prominent jet but most of the comet was inactive, confirming the Earth-based observations that <10% of the surface is actively sublimating. We have developed a thermal evolution model of comet PBorrelly, using a numerical code that is able to solve the heat conduction and gas diffusion equations at the same time across an idealized spherical nucleus ( De Sanctis et al., 1999, 2000; Capria et al., 2000; Coradini et al., 1997a,b). The comet nucleus is composed by water, volatiles ices and dust in different proportions. The refractory component is made by grains that are embedded in the icy matrix. The code is able to account for the dust release, contributing to the dust flux, and the formation of dust mantles on the comet surface. The model was applied to a cometary nucleus with the estimated physical and dynamical characteristics of P/Borrelly in order to infer the status and activity level of a body on such an orbit during the DS1 observation. The comet gas flux, differentiation and thermal behavior were simulated and reproduced. The model results are in good agreement with the DS1 flyby results and the ground based observations, in terms of activity, dust coverage and temperatures of the surface.     

A fine mist of very small comet dust particles

A comet nucleus considered as an aggregate of interstellar dust would produce a mist of very finely divided (radius ～ 0.01 μm) particles of carbon and metal oxides accompanying the larger dust grains. These small particles which are very abundant in the interstellar dust size spectrum would provide substantial physical effects because of their large surface area. They may show up strongly in particle detectors on the Halley probes. A strong basis for serious consideration of these particles comes from the other evidence that interstellar dust grains are the building blocks of comets; e.g. (1) the explanation of the “missing” carbon in comets; (2) The S₂ molecule detection which suggests that the comet solid ice materials have been previously subjected to ultraviolet radiation (as are interstellar grains) before aggregation into the comet; (3) the predicted dust to gas ratio.     

Evaluation and utilization of CloudSat and CALIPSO data to analyze the impact of dust aerosol on the microphysical properties of cirrus over the Tibetan Plateau

The present study elucidates on the evaluation of two versions (V3 and V4.10) of vertical feature mask (VFM) and aerosol sub-types data derived from the Cloud-Aerosol LiDAR and Infrared Pathfinder Satellite Observations (CALIPSO), and its utilization to analyze the impact of dust aerosol on the microphysical properties of cirrus over the Tibetan Plateau (TP). In conjunction to the CALIPSO, we have also used the CloudSat data to study the same during the summer season for the years 2007–2010 over the study area 25–40°N and 75–100°E. Compared to V3 of CALIPSO, V4.10 was found to have undergone substantial changes in the code, algorithm, and data products. Intercomparison of both versions of data products in the selected grid between 30–31°N and 83–84°E within the study area during 2007–2017 revealed that the VFM and aerosol sub-types are in good agreement of ～95.27% and ～82.80%, respectively. Dusty cirrus is defined as the clouds mixed with dust aerosols or existing in dust aerosol conditions, while the pure cirrus is that in a dust-free environment. The obtained results illustrated that the various microphysical properties of cirrus, namely ice water content (IWC), ice water path (IWP), ice distribution width (IDW), ice effective radius (IER), and ice number concentration (INC) noticed a decrease of 17%, 18%, 4%, 19%, and 10%, respectively due to the existence of dust aerosol, consistent with the classical “Twomey effect” for liquid clouds. Moreover, the aerosol optical depth (AOD) showed moderate negative correlations between ?0.4 and ?0.6 with the microphysical characteristics of cirrus. As our future studies, in addition to the present work undertaken, we planned to gain knowledge and interested to explore the impact of a variety of aerosols apart from the dust aerosol on the microphysical properties of cirrus in different regions of China.     

Interstellar dust models

Interstellar dust models, previously constrained only from the extinction curve, have been radically changed with the arrival of IRAS observations of the dust infrared emission. An important component of interstellar dust is likely to be made of small particles that show a fluctuating temperature upon impinging single photons and which can produce large near and mid infrared excesses ubiquitously observed in the Galaxy and external galaxies. The analysis of COBE data should soon improve our understanding of dust infrared emissivity and particularly for big grains in the submillimeter domain. We will discuss the key observations (spectral features, broad-band colors, correlations with gas tracers…) which put the best constraints on any dust models and show that the next generation of IR/submm satellites (ISO, SIRTF…) should improve our knowledge of interstellar dust composition and the dust redistribution of the stellar energy inside galaxies.     

Interpretation of the measurements of secondary electron currents induced by impacts during the flyby of comet Halley

The Giotto, Vega-1 and Vega-2 spacecraft flew through the environment of comet Halley at a relatively close range with velocities of the order of 70–80 km/s. The fore sections of their surface were bombarded by neutral molecules and dust grains which caused the emission of secondary electrons and sputtered ions. This paper makes use of the secondary electron current measurements performed on Vega-1 to infer some characteristic features of the cometary atmosphere. The total gas production rate is estimated to be of the order of 10³⁰ molecules/s and is found to vary with time; the presence of a major jet is also detected at closest approach.     

Dust grain orbital behavior around ceres

Many asteroids show indications they have undergone impacts with meteoroid particles having radii between 0.01 m and 1 m. During such impacts, small dust grains will be ejected at the impact site. The possibility of these dust grains (with radii greater than 2.2 μm) forming a halo around a spherical asteroid (such as Ceres) is investigated using standard numerical integration techniques. The orbital elements, positions, and velocities are determined for particles with varying radii taking into account both the influence of gravity, radiation pressure, and the interplanetary magnetic field (for charged particles). Under the influence of these forces it is found that dust grains (under the appropriate conditions) can be injected into orbits with lifetimes in excess of one year. The lifetime of the orbits is shown to be highly dependent on the location of the ejection point as well as the angle between the surface normal and the ejection path. It is also shown that only particles ejected within 10° relative to the surface tangential survive more than a few hours and that the longest-lived particles originate along a line perpendicular to the Ceres-Sun line.     

Catalytic activity of interstellar grains: Formation of molecular hydrogen on amorphous silicates

Silicates constitute an important class of interstellar grain material and are the site of catalytic activities, most notably the formation of molecular hydrogen. Here we report an analysis of experiments conducted in the laboratory to measure the efficiency of formation of molecular hydrogen on amorphous silicates, a realistic analogue of interstellar dust grains. From the measurements, we also obtain the energetics of key processes in the reaction and information on the mechanism of reaction. Comparison with earlier measurements of molecular hydrogen formation on a sample of polycrystalline olivine shows that amorphous materials are more efficient catalysts.     

Trapping of gases by water ice and implications for icy bodies.

The trapping of various gases by water ice at low temperatures (20-80K) and their release from the ice upon warming, was studied experimentally. The results of these experiments, together with a computation of the thermal evolution of a cometary nucleus, can explain the gas and dust jets which were observed to emanate from the nucleus of P/Halley. The experimental results are important also to the gas content of Titan.     

Experimental investigation on silica dust lofting due to charging within micro-cavities and surface electric field in the vacuum chamber

The charged dust particles can be mobilized electrostatically by the repulsion between the adjacent grains and the surface electric field due to the incoming electron current and the charge accumulation within the micro-cavities. In this study, the experimental results of the initial vertical launching velocities and the maximum dust heights are compared with the estimated values for the lofted spherical dust grains by the patch surface charging equations. Silica particles with the sizes between <6 and 45?µm in radius are loaded on a graphite plate, and they are exposed to the electron beam with 450?eV energy under 4?×?10^?3?Pa vacuum chamber pressure. During the first set of the experiments, the dust samples are tested without an initial compression process and an additional horizontal electric field. Second, the dust samples are compressed by two different weights in order to increase the packing density under approximately 780.7?Pa and 3780?Pa. Finally, the dust grains are placed between the two parallel aluminum plates to apply approximately 2000?V/m and 4800?V/m horizontal electric field. A high-speed camera is used to record the transportation of the dust grains together with a microscopic telescope, and the results point out that the patch surface dust-charging model estimations are in agreement with the first experiments. On the other hand, the dust particles from the compressed samples are lofted with higher velocities than the estimations, and the number of the dust lofting observations decreases significantly, which demonstrates the importance of the micro-cavities and the increased charging requirement to overcome the contact forces. When the horizontal electric field is present, the initial vertical launching velocities are measured to be lower than the other experiments, which can be attributed to the decreased charging requirement for the dust lofting as a result of inter-particle collisions and rolling motion. According to the experimental results, the electrostatic dust transportation can be controlled not only by the ambient plasma and the solar irradiation on the airless planetary bodies, but also by the surface properties such as the contact surfaces between the dust grains, the number of the micro-cavities related to the packing density, and the presence of the horizontal electric field contributing to the external forces by other particle motions.     

月尘静电迁移研究进展

月尘的静电悬浮和迁移是Apollo时期留下的最有争议的问题之一. 其既是研 究月球表面物质演化历史的重要线索, 也是探月工程必须考虑的重要因素. 月尘在月表环境下易因电子附着、光电效应、二次电子发射等过程带电, 并 在月球全球性静电场作用下发生迁移运动. 但目前对月尘静电迁移过程的认 识还不全面, 其主要原因在于对月尘静电特性的了解不够准确, 对静电迁移 过程的地面模拟不够充分以及对月球尘埃环境的探测较为缺乏. 未来需进一 步开展模拟月尘的研制, 月尘静电特性的分析, 静电迁移过程模拟以及尘埃 环境的探测等工作.      

非晶态Fe_1—xBx-Fe_(1-x)B_x合金的电子结构

以四面体Fe_4B为原子团,利用多重散射X_a自洽场的方法,对非晶态Fe_(1-x)B_x合金的电子结构进行了计算。分析、对比了原子团Fe_4和Fe_4B的能级分布、轨道等高线图和状态密度分布,讨论了B原子的加入对非晶态Fe_(1-x)B_x合金的电子结构的影响。     

Giotto/Cometary dust interaction event near the comet Halley ionopause

Plasma and magnetic field disturbances accompanying dust particle impacts are explained by means of creation of a secondary cloud around the spacecraft. Cold cometary ions impinging upon the cloud are scattered by atoms of the cloud. This scattering changes initial angular distribution of cometary ions. Magnetic field perturbation is created by the friction between the electron component of the cometary plasma flow and the cloud.     

Martian cloud systems: Current knowledge and future observations

In this paper we summarise the current understanding of Martian condensate and dust clouds. The paper is particularly concerned with the spatial, temporal and seasonal characteristics of the clouds. The condensate clouds are composed of water and ice particles and occasionally CO₂ particles. Dust clouds are composed of material from the surface and redistributed over the planet through the weather systems. The apparent lack of annual reproductivity of these dust storms forms a major unresolved problem. We discuss in this paper the types of observations needed in future space missions, in particular the requirements for the NASA Mars Geochemical Climatology Orbiter Mission planned for the end of this decade.     

Dirty ice grains in comets

Based on the computed equilibrium temperature of evaporating dirty water-ice grains, dirty water-ice halo is examined, taking into account of a size dependence of terminal velocity of dust at P/Halley. It is found that due to an enhanced grain's temperature caused by dirtiness, icy halo cannot extend over 100 km from the nucleus when comet approaches inside a solar distance r of 1 AU. Therefore, it is unlikely that the ice bands in the near infrared wavelengths could be detected in the cometary coma at r<1 AU.