Estimate of the NO concentration in the auroral region based on emission intensities of 391.4, 557.7, and 630.0 nm

Using numerical modeling, the influence of the NO concentration on the intensity of 557.7 nm emission in aurora caused by electron precipitation has been studied. It has been shown that the O₂ ⁺ NO reaction, which reduces the contribution of the dissociative recombination of the O₂ ⁺ ion into the formation of the ¹S state of atomic oxygen, is the main channel of suppression of the intensity of the emission at 557.7 nm. A method of estimating the NO concentration in the aurora based on the data of photometric measurements of emissions at 391.4, 557.7, and 630.0 nm has been proposed. The method has been tested using the data of simultaneous rocket measurements of emissions at 391.4, 557.7, and 630.0 nm and the NO content in aurora. A good agreement of estimates of the NO concentrations performed by the method to the results of direct measurements has been obtained.     

Can enantiomorphic crystals like quartz play a role in the origin of homochirality on earth?

This communication reviews the possible actions of enantiomorphic crystals on the surface of Earth as sources of homochirality of organic compounds. The discovery of asymmetric adsorption and asymmetric catalysis involving optically active quartz crystals has led some authors to conclude that this source of asymmetry played an important role as a source of homochirality in nature, a concept that later proved erroneous. Moreover, data regarding the preponderance in nature of l-quartz crystals have been used to confirm calculations of the parity violation energy difference (PVED) for l-quartz and, hence, to explain the prevalence of L-amino acids and D-sugars in living matter. As discussed here, quartz and other enantiomorphs such as sodium chlorate can produce chiral intermediates active in autocatalytical processes. Our most recent compilation of the literature, however, reveals that the distribution of d- and l-quartz crystals at the surface of the Earth when all possible locations are included is quite random. Although quartz can serve as an effective asymmetric inductor in autocatalytic processes, it cannot be the source of homochirality of living matter because of the random occurrence of the two types of enantiomorphs. The calculations of PVED values for quartz therefore lack a sound physical basis.     

Experimentally tracing the key steps in the origin of life: The aromatic world

Life is generally believed to emerge on Earth, to be at least functionally similar to life as we know it today, and to be much simpler than modern life. Although minimal life is notoriously difficult to define, a molecular system can be considered alive if it turns resources into building blocks, replicates, and evolves. Primitive life may have consisted of a compartmentalized genetic system coupled with an energy-harvesting mechanism. How prebiotic building blocks self-assemble and transform themselves into a minimal living system can be broken into two questions: (1) How can prebiotic building blocks form containers, metabolic networks, and informational polymers? (2) How can these three components cooperatively organize to form a protocell that satisfies the minimal requirements for a living system? The functional integration of these components is a difficult puzzle that requires cooperation among all the aspects of protocell assembly: starting material, reaction mechanisms, thermodynamics, and the integration of the inheritance, metabolism, and container functionalities. Protocells may have been self-assembled from components different from those used in modern biochemistry. We propose that assemblies based on aromatic hydrocarbons may have been the most abundant flexible and stable organic materials on the primitive Earth and discuss their possible integration into a minimal life form. In this paper we attempt to combine current knowledge of the composition of prebiotic organic material of extraterrestrial and terrestrial origin, and put these in the context of possible prebiotic scenarios. We also describe laboratory experiments that might help clarify the transition from nonliving to living matter using aromatic material. This paper presents an interdisciplinary approach to interface state of the art knowledge in astrochemistry, prebiotic chemistry, and artificial life research.     

A theory of circular organization and negative feedback: defining life in a cybernetic context

All life today incorporates a variety of systems controlled by negative feedback loops and sometimes amplified by positive feedback loops. The first forms of life necessarily also required primitive versions of feedback, yet surprisingly little emphasis has been given to the question of how feedback emerged out of primarily chemical systems. One chemical system has been established that spontaneously develops autocatalytic feedback, the Belousov-Zhabotinsky (BZ) reaction. In this essay, I discuss the BZ reaction as a possible model for similar reactions that could have occurred under prebiotic Earth conditions. The main point is that the metabolism of contemporary life evolved from primitive homeostatic networks regulated by negative feedback. Because life could not exist in their absence, feedback loops should be included in definitions of life.     

空气弹簧支撑的Hexapod微激振平台自动调平研究

Hexapod微激振平台具有负载重量大和振动量级小的特点,为了实现精确卸载、作动器小量级精密控制,研制了基于空气弹簧支撑的Hexapod微激振平台。该平台包括负责工作状态承载的4点梯形分布的空气弹簧柔性支撑和负责非工作状态承载的3点刚性辅助支撑两部分。针对该平台自动调平控制的两大问题:即柔性支撑与刚性支撑之间存在的力耦合以及气路控制中存在的非线性和时延性,提出了连续充气和脉冲充气相结合的开关控制策略。为验证自动调平控制的可行性,在负载重量约为200 kg的Hexapod微激振平台上进行试验,结果表明,平台可在140 s内实现自动调平,且6个作动腿位移误差不超过1 mm。     

Chiral symmetry breaking and complete chiral purity by thermodynamic-kinetic feedback near equilibrium: implications for the origin of biochirality

Chiral symmetry breaking occurs when a physical or chemical process spontaneously generates a large excess of one of the two enantiomers--left-handed (L) or right-handed (D)--with no preference as to which of the two enantiomers is produced. From the viewpoint of energy, these two enantiomers can exist with an equal probability, and inorganic processes that involve chiral products commonly yield a racemic mixture of both. The fact that biologically relevant molecules exist only as one of the two enantiomers is a fascinating example of complete symmetry breaking in chirality and has long intrigued the science community. The origin of this selective chirality has remained a fundamental enigma with regard to the origin of life since the time of Pasteur, some 140 years ago. Here, it is shown that two populations of chiral crystals of left and right hand cannot coexist in solution: one of the chiral populations disappears in an irreversible autocatalytic process that nurtures the other one. Final and complete chiral purity seems to be an inexorable fate in the course of the common process of growth-dissolution. This unexpected chiral symmetry breaking can be explained by the feedback between the thermodynamic control of dissolution and the kinetics of the growth process near equilibrium. This "thermodynamic-kinetic feedback near equilibrium" is established as a mechanism to achieve complete chiral purity in solid state from a previously solid racemic medium. The way in which this mechanism could operate in solutions of chiral biomolecules is described. Finally, based on this mechanism, experiments designed to search for chiral purity in a new way are proposed: chiral purity of amino acids or biopolymers is predicted in solid phase from a previously solid racemic medium. This process may have played a key role in the origin of biochirality.     

Sequence analysis of trimer isomers formed by montmorillonite catalysis in the reaction of binary monomer mixtures

Oligonucleotides are structurally similar to short RNA strands. Therefore, their formation via non-enzymatic reactions is highly relevant to Gilbert's RNA world scenario (1986) and the origin of life. In laboratory synthesis of oligonucleotides from monomers, it is necessary to remove the water molecules from the reaction medium to shift the equilibrium in favor of oligonucleotide formation, which would have been impossible for reactions that took place in dilute solutions on the early Earth. Model studies designed to address this problem demonstrate that montmorillonite, a phyllosilicate common on Earth and identified on Mars, efficiently catalyzes phosphodiester-bond formation between activated mononucleotides in dilute solutions and produces RNA-like oligomers. The purpose of this study was to examine the sequences and regiospecificity of trimer isomers formed in the reaction of 5'-phosphorimidazolides of adenosine and uridine. Results demonstrated that regiospecificity and sequence specificity observed in the dimer fractions are conserved in their elongation products. With regard to regiospecificity, 61% of the linkages were found to be RNA-like 3',5'-phosphodiester bonds. With regard to sequence specificity, we found that 88% of the linear trimers were hetero-isomers with 61% A-monomer and 39% U-monomer incorporation. These results lend support to Bernal's hypothesis that minerals may have played a significant role in the chemical processes that led to the origin of life by catalyzing the formation of phosphodiester bonds in RNA-like oligomers.     

Homochirality in an early peptide world

A recently proposed model of non-autocatalytic reactions in dipeptide formation that leads to spontaneous symmetry breaking and homochirality was examined. The model is governed by activation, polymerization, epimerization, and depolymerization of amino acids. Symmetry breaking was determined to result primarily from the different rates of reactions that involve homodimers and heterodimers, i.e., stereoselective reactions, and the fact that epimerization can only occur on the N-terminal residue and not on the C-terminal residue. This corresponds to an auto-inductive cyclic process that works only in one direction. It is argued that epimerization mimics autocatalytic behavior as well as mutual antagonism, both of which are known to be crucial for the production of full homochirality.     

Eutectic phases in ice facilitate nonenzymatic nucleic acid synthesis

Polymeric compounds similar to oligonucleotides are relevant to the origin of life and particularly to the concept of an RNA world. Although short oligomers of RNA can be synthesized nonenzymatically under laboratory conditions by second-order reactions in concentrated solutions, there is no consensus on how these polymers could have been synthesized de novo on the early Earth from dilute solutions of monomers. To address this question in the context of an RNA world, we have explored ice eutectic phases as a reaction medium. When an aqueous solution freezes, the solutes become concentrated in the spaces between the ice crystals. The increased concentration offsets the effect of the lower temperature and accelerates the reaction. Here we show that in the presence of metal ions in dilute solutions, frozen samples of phosphoimidazolide-activated uridine react within days at -18 degrees C to form oligouridylates up to 11 bases long. Product yields typically exceed 90%, and approximately 30% of the oligomers include one or more 3'-5' linkages. These conditions facilitate not only the notoriously difficult oligouridylate synthesis, but also the oligomerization of activated cytidylate, adenylate, and guanylate. To our knowledge, this represents the first report to indicate that ice matrices on the early Earth may have accelerated certain prebiotic polymerization reactions.     

A quantitative evaluation of the iron-sulfur world and its relevance to life's origins

The significance of W?chtersh?user's iron-sulfur world to the origin of life and the limits to its notional autocatalytic cycles are examined in kinetic simulations of the chain polymerization sequence: primitive materials-->amino acids-->oligomers. The simulations were run for the formation of all oligomers up to the 20-mer over a 1 Gy interval from the end of the period of heavy bombardment, during which period life emerged. Upper-limit rate constant estimates developed from the studies of Huber and W?chtersh?user were employed. The simulations showed that oligomer production consistent with life's start within that interval emerges only with an autocatalyst exhibiting a catalytic proficiency comparable to that of contemporary enzymes. The simulations, moreover, ignored likely thermodynamic and statistical burdens which, if included, would have led to the need for catalytic capacities well in excess of those in present-day enzymes. Prebiotic oligomers with such levels of activity are clearly not likely, and it is apparent that the iron-sulfur scheme could not have played a role in life's beginnings.     

BPFER/DSX体系固化反应动力学与热性能

采用DSC研究了有机硅固化剂1,3-二氨丙基-1,1,3,3-四甲基二硅氧烷(DSX)与双酚F环氧树脂(BPFER)的固化动力学。BPFER/DSX体系的非等温固化反应曲线和dα/dt-t曲线表明,该反应符合自催化反应模型的基本特征。T-β曲线预测的固化工艺的凝胶温度、固化温度和后固化温度分别为36、87、138℃。采用E变量法分析得该体系的固化反应表观活化能为46.70～50.54 kJ/mol,与Starink、Kissinger、Ozawa、Boswell等方程的验证结果基本一致。采用E常量法求得该体系不同升温速率下的固化反应动力学方程,动力学方程预测值与实验值十分吻合。TG和DTG曲线表明,BPFER/DSX固化物的耐热性优于BPFER/DDM固化物。     

A numerical study of the charge diameter effect on unsteady detonation

A numerical study for the unsteady detonation of an unconfined tetryl charge of small diameter, which is assumed to be homogeneous, was performed by using the two-dimensional Lagrangian hydrodynamic computer code, 2 DL, with the first order Arrhenius equation of reaction rate. Becker-Kistiakowsky-Wilson (BKW) and Kihara-Hikita (KH) equations of state have been applied to the detonation products.In the case of BKW, it is shown that the rarefaction waves propagating inward from the lateral surface make the reaction rate slow and give a curvature to the front. Then after an induction time, a strong initiation occurs in the reaction zone near the lateral surface and higher pressure zone moves to the axis. This higher pressure accelerates the detonation propagation near the lateral surface and the curvature of detonation front is reduced. Then, the reaction at the lateral surface again begins to decay by the rarefaction waves. Such a sequence of process is repeated periodically.The possibility of the occurrence of the strong initiation depends on the pressure and temperature in the shocked zone near the surface. In a small diameter charge, the delayed explosion becomes weaker near the surface, while its frequency increases. No shock interaction occurs because the direction of the particle flow is always divergent.In the case of KH equation of state, the temperature of detonation is higher than that obtained by BKW and the behaviour of instability becomes rather different from the previous result, i.e. in the axis the pressure oscillates repeating the overdriven and underdriven detonation similar with the case of BKW.     

同轴离心式喷嘴热声不稳定性递归网络分析

为获得同轴离心式喷嘴燃烧动力学特性,开展了喷注单元稳定性试验研究.试验中随着混合比的增加,系统依次经历了燃烧噪声状态、阵发状态和准周期振荡状态.采用递归网络方法对实验结果进行分析,获得了典型工况下的网络拓扑图.燃烧噪声状态体现出随机特征,阵发状态体现出中央聚集和极限环边界特征,准周期振荡状态体现出宽边界圆环特征.利用网...     

On the stabilization of ribose by silicate minerals

The RNA-world theory hypothesizes that early Earth life was based on the RNA molecule. However, the notion that ribose, the sugar in RNA, is unstable still casts a serious doubt over this theory. Recently, it has been found that the silicate-mediated formose reaction facilitates the stabilization of ribose. Using accurate quantum chemical calculations, we determined the relative stability of the silicate complexes of arabinose, lyxose, ribose, and xylose with the intent to determine which would form predominantly from a formose-like reaction. Five stereoisomers were investigated for each complex. The stereoisomers of 2:1 ribose-silicate are the more stable ones, to the extent that the least stable of these is even more stable than the most stable stereoisomer of the other 2:1 sugar-silicate complexes. Thus, thermodynamically, a formose-like reaction in the presence of silicate minerals should preferentially form the silicate complex of ribose over the silicate complex of arabinose, lyxose, and xylose.     

Formation of replicating saponite from a gel in the presence of oxalate: implications for the formation of clay minerals in carbonaceous chondrites and the origin of life

The potential role of clay minerals in the abiotic origin of life has been the subject of ongoing debate for the past several decades. At issue are the clay minerals found in a class of meteorites known as carbonaceous chondrites. These clay minerals are the product of aqueous alteration of anhydrous mineral phases, such as olivine and orthopyroxene, that are often present in the chondrules. Moreover, there is a strong correlation in the occurrence of clay minerals and the presence of polar organic molecules. It has been shown in laboratory experiments at low temperature and ambient pressure that polar organic molecules, such as the oxalate found in meteorites, can catalyze the crystallization of clay minerals. In this study, we show that oxalate is a robust catalyst in the crystallization of saponite, an Al- and Mg-rich, trioctahedral 2:1 layer silicate, from a silicate gel at 60°C and ambient pressure. High-resolution transmission electron microscopy analysis of the saponite treated with octadecylammonium (n(C)=18) cations revealed the presence of 2:1 layer structures that have variable interlayer charge. The crystallization of these differently charged 2:1 layer silicates most likely occurred independently. The fact that 2:1 layer silicates with variable charge formed in the same gel has implications for our understanding of the origin of life, as these 2:1 clay minerals most likely replicate by a mechanism of template-catalyzed polymerization and transmit the charge distribution from layer to layer. If polar organic molecules like oxalate can catalyze the formation of clay-mineral crystals, which in turn promote clay microenvironments and provide abundant adsorption sites for other organic molecules present in solution, the interaction among these adsorbed molecules could lead to the polymerization of more complex organic molecules like RNA from nucleotides on early Earth.     

Vestibular factors influencing the biomedical support of humans in space

This paper will describe the biomedical support aspects of humans in space with respect to the vestibular system. The vestibular system is thought to be the primary sensory system involved in the short-term effects of space motion sickness although there is increasing evidence that many factors play a role in this complex set of symptoms. There is the possibility that an individual's inner sense of orientation may be strongly coupled with the susceptibility to space motion sickness. A variety of suggested countermeasures for space motion sickness will be described. Although there are no known ground-based tests that can predict space motion sickness, the search should go on. The long term effects of the vestibular system in weightlessness are still relatively unknown. Some preliminary data has shown that the otoconia are irregular in size and distribution following extended periods of weightlessness. The ramifications of this data are not yet known and because the data was obtained on lower order animals, definitive studies and results must wait until the space station era when higher primates can be studied for long durations. This leads us to artificial gravity, the last topic of this paper. The vestibular system is intimately tied to this question since it has been shown on Earth that exposure to a slow rotating room causes motion sickness for some period of time before adaptation occurs. If the artificial gravity is intermittent, will this mean that people will get sick every time they experience it? The data from many astronauts returning to Earth indicates that a variety of sensory illusions are present, especially immediately upon return to a 1-g environment. Oscillopsia or apparent motion of the visual surround upon head motion along with inappropriate eye motions for a given head motion, all indicate that there is much to be studied yet about the vestibular and CNS systems reaction to a sudden application of a steady state acceleration field like 1-g. From the above information it is obvious that the vestibular system does have unique requirements when it comes to the biomedical support of space flight. This is not to say that other areas such as cardiovascular, musculo-skeletal, immunological and hematological systems do not have their own unique requirements but that possible solutions to one system can provide continuing problems to another system. For example, artificial gravity might be helpful for long term stabilization of bone demineralization or cardiovascular deconditioning but might introduce a new set of problems in orientation, vestibular conflict and just plain body motion in a rotating space vehicle.     

On the conditions of gas inclusions formation in melts under zero gravity state (after “Pirin” experiment)

Thermodynamics relations have been considered under which gas inclusions may form in melts (closed systems), due to both volatility of components and the presence of dissolved gases. It has been shown that in the melts with sufficient volatility of components, gas inclusions may form under equilibrium conditions if the ampoule is wetted well by the melt, whereas in case of low wettability they form under non-equilibrium state only. The foaming in the tellurium-selenium system has been analysed (“Pirin”, KP-4 experiment).In the melts containing dissolved gases, gas inclusions form under conditions of deviation from equilibrium and it is the main mechanism of outgassing. It has been demonstrated that the melt foaming method using hydrid compounds may be applied to the materials exhibiting a hysteresis of temperature dependence of diluted hydrogen concentration. Production of foam aluminium under zero gravity state has been considered as an example (“Pirin”, SP-3 experiment).     

POLYMERIZATION PROCESSES OF EPOXY PLASTIC IN SIMULATED FREE SPACE CONDITIONS

This paper presents the results of laboratory modeling of polymerization under the action of free-space factors. The relationships between temperature and stoichiometric ratios were obtained for different sublimation parameters of the reaction mixture components and rates of matrix polymerization. It was shown that there exists an optimal relation between the rates of polymerization and sublimation of low-molecular mixture components. The possibility of using low-molecular components with high sublimation rates under certain conditions of reaction development was experimentally verified.Two options for triggering the reaction have been tested—raising the temperature to the value at which polymerization begins and by means of sunlight photoinitiation (ultraviolet spectrum). It was shown that both variants can be used in the conditions of free space.     

Space education, a tool to influence the cultural development in the society

Culture is an organized group of learned responses of a particular society, or the total round of human activities, not due to heredity, shared by members of a group. This means that culture is a dynamic process and it is in tight relationship to the civilization as a tool to master their all day's tasks. Space science is a result of the shift from the mass production civilization to the knowledge civilization. The science had opened new ways of thinking into a new environment, space. The ability to develop thinking to new living areas is already a learned response to the environment and therefore an act of culture.

The next changes in culture are a result of the different view, mankind has from earth looking back out of the spacecraft window. We see now with other eyes the small and vulnerable living area of mankind. We see no political limits partitioning the surface. We understand time zones as systems properties of the regions. This has up to now influenced big groups of the societies. As this view has to be shared by all members of the societies in the same mode, space education has to organize this effect.