Martian Volatiles: Isotopic Composition, Origin, and Evolution

Information about the composition of volatiles in the Martian atmosphere and interior derives from Viking spacecraft and ground-based measurements, and especially from measurements of volatiles trapped in Martian meteorites, which contain several distinct components. One volatile component, found in impact glass in some shergottites, gives the most precise measurement to date of the composition of Martian atmospheric Ar, Kr, and Xe, and also contains significant amounts of atmospheric nitrogen showing elevated ¹⁵N/¹⁴N. Compared to Viking analyses, the ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are larger in shergottites, the ¹²⁹Xe/¹³²Xe ratio is similar, and the ⁴⁰Ar/³⁶Ar and ³⁶Ar/³⁸Ar ratios are smaller. The isotopic composition of atmospheric Kr is very similar to solar Kr, whereas the isotopes of atmospheric Xe have been strongly mass fractionated in favor of heavier isotopes. The nakhlites and ALH84001 contain an atmospheric component elementally fractionated relative to the recent atmospheric component observed in shergottites. Several Martian meteorites also contain one or more Martian interior components that do not show the mass fractionation observed in atmospheric noble gases and nitrogen. The D/H ratio in the atmosphere is strongly mass fractionated, but meteorites contain a distinct Martian interior hydrogen component. The isotopic composition of Martian atmospheric carbon and oxygen have not been precisely measured, but these elements in meteorites appear to show much less variation in isotopic composition, presumably in part because of buffering of the atmospheric component by larger condensed reservoirs. However, differences in the oxygen isotopic composition between meteorite silicate minerals (on the one hand) and water and carbonates indicate a lack of recycling of these volatiles through the interior. Many models have been presented to explain the observed isotopic fractionation in Martian atmospheric N, H, and noble gases in terms of partial loss of the planetary atmosphere, either very early in Martian history, or over extended geological time. The number of variables in these models is large, and we cannot be certain of their detailed applicability. Evolutionary data based on the radiogenic isotopes (i.e., ⁴⁰Ar/³⁶Ar, ¹²⁹Xe/¹³²Xe, and ¹³⁶Xe/¹³²Xe ratios) are potentially important, but meteorite data do not yet permit their use in detailed chronologies. The sources of Mars' original volatiles are not well defined. Some Martian components require a solar-like isotopic composition, whereas volatiles other than the noble gases (C, N, and H₂O) may have been largely contributed by a carbonaceous (or cometary) veneer late in planet formation. Also, carbonaceous material may have been the source of moderate amounts of water early in Martian history.     

Isotopic Composition of H,HE and NE in the Protosolar Cloud

Observations and measurements in the solar wind, the Jovian atmosphere and the gases trapped in lunar surface material provide the main evidence from which the isotopic composition of H, He and Ne in the Protosolar Cloud (PSC) is derived. These measurements and observations are reviewed and the corrections are discussed that are needed for obtaining from them the PSC isotopic ratios. The D/H, ³He/⁴He (D+³He)/H, ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios adopted for the PSC are presented. Protosolar abundances provide the basis for the interpretation of isotopic ratios measured in the various solar system objects. In this article we discuss constraints derived from the PSC abundances on solar mixing, the origin of atmospheric neon, and the nature of the “SEP” component of neon trapped at the lunar surface. We also discuss constraints on the galactic evolution provided by the isotopic abundances of H and He in the PSC. This revised version was published online in August 2006 with corrections to the Cover Date.     

Virtis: An Imaging Spectrometer for the Rosetta Mission

The VIRTIS (Visual IR Thermal Imaging Spectrometer) experiment has been one of the most successful experiments built in Europe for Planetary Exploration. VIRTIS, developed in cooperation among Italy, France and Germany, has been already selected as a key experiment for 3 planetary missions: the ESA-Rosetta and Venus Express and NASA-Dawn. VIRTIS on board Rosetta and Venus Express are already producing high quality data: as far as Rosetta is concerned, the Earth-Moon system has been successfully observed during the Earth Swing-By manouver (March 2005) and furthermore, VIRTIS will collect data when Rosetta flies by Mars in February 2007 at a distance of about 200 kilometres from the planet. Data from the Rosetta mission will result in a comparison – using the same combination of sophisticated experiments – of targets that are poorly differentiated and are representative of the composition of different environment of the primordial solar system. Comets and asteroids, in fact, are in close relationship with the planetesimals, which formed from the solar nebula 4.6 billion years ago. The Rosetta mission payload is designed to obtain this information combining in situ analysis of comet material, obtained by the small lander Philae, and by a long lasting and detailed remote sensing of the comet, obtained by instrument on board the orbiting Spacecraft. The combination of remote sensing and in situ measurements will increase the scientific return of the mission. In fact, the “in situ” measurements will provide “ground-truth” for the remote sensing information, and, in turn, the locally collected data will be interpreted in the appropriate context provided by the remote sensing investigation. VIRTIS is part of the scientific payload of the Rosetta Orbiter and will detect and characterise the evolution of specific signatures – such as the typical spectral bands of minerals and molecules – arising from surface components and from materials dispersed in the coma. The identification of spectral features is a primary goal of the Rosetta mission as it will allow identification of the nature of the main constituent of the comets. Moreover, the surface thermal evolution during comet approach to sun will be also studied.     

Ultraviolet spectroscopy and remote sensing of the upper atmosphere

The Earth's ultraviolet airglow contains fundamental diagnostic information about the state of its upper atmosphere and ionosphere. Our understanding of the excitation and emission processes which are responsible for the airglow has undergone dramatic evolution from the earliest days of space research through the past several years during which a wealth of new information has been published from high-resolution spectroscopy and imaging experiments. This review of the field begins with an overview of the phenomenology: how the Earth looks in the ultraviolet. Next the basic processes leading to excitation of atomic and molecular energy states are discussed. These concepts are developed from first principles and applied to selected examples of day and night airglow; a detailed review of radiation transport theory is included. This is followed by a comprehensive examination of the current status of knowledge of individual emission features seen in the airglow, in which atomic physics issues as well as relevant atmospheric observations of major and minor neutral and ionic constituents are addressed. The use of airglow features as remote sensing observables is then examined for the purpose of selecting those species most useful as diagnostics of the state of the thermosphere and ionosphere. Imaging of the plasmasphere and magnetosphere is also briefly considered. A summary of upcoming UV remote sensing missions is provided.     

Nickel Isotopic Composition and Nickel/Iron Ratio in the Solar Wind: Results from SOHO/CELIAS/MTOF

Using the Mass Time-of-Flight Spectrometer (MTOF)—part of the Charge, Elements, Isotope Analysis System (CELIAS)—onboard the Solar Heliospheric Observatory (SOHO) spacecraft, we derive the nickel isotopic composition for the isotopes with mass 58, 60 and 62 in the solar wind. In addition we measure the elemental abundance ratio of nickel to iron. We use data accumulated during ten years of SOHO operation to get sufficiently high counting statistics and compare periods of different solar wind velocities. We compare our values with the meteoritic ratios, which are believed to be a reliable reference for the solar system and also for the solar outer convective zone, since neither element is volatile and no isotopic fractionation is expected in meteorites. Meteoritic isotopic abundances agree with the terrestrial values and can thus be considered to be a reliable reference for the solar isotopic composition. The measurements show that the solar wind elemental Ni/Fe-ratio and the isotopic composition of solar wind nickel are consistent with the meteoritic values. This supports the concept that low-FIP elements are fed without relative fractionation into the solar wind. Our result also confirms the absence of substantial isotopic fractionation processes for medium and heavy ions acting in the solar wind.     

Remote sensing of winds and atmospheric turbulence by cross-correlation of passive optical signals

This paper describes a new method for the remote measurement of winds and atmospheric turbulence by the cross-correlation of passive optical signals. If small local variations in atmospheric density, temperature or other parameter cause fluctuations in scattered or thermal radiation detected by a radiometer on the ground, then the cross-correlation of the fluctuations detected by two radiometers with crossed fields of view can yield turbulence information pertaining to the region about this intersection point. When the fields of view are not quite crossed turbulent eddies will be convected through the fields of view sequentially, and the transit times of the eddies identified by the correlation procedure will yield wind information.The successful application of this technique, detecting fluctuations in scattered sunlight, has demonstrated both the potential, and the present limitations of the method, which are discussed in this paper. Results for the power spectrum of the fluctuations and for winds at an altitude of 61 m are shown, and the wind measurements are compared to similar measurements made with a standard anemometer located on top of a 61 m tower.     

Johannes Geiss’ Investigations of Solar, Heliospheric and Interstellar Matter

Johannes Geiss is a world leader and foremost expert on measurements and interpretation of the composition of matter that reveals the history, present state, and future of astronomical objects. With his Swiss team he was first to measure the composition of the noble gases in the solar wind when in the late 1960s he flew the brilliant solar wind collecting foil experiments on the five Apollo missions to the moon. Always at the forefront of the art of composition measurements, he with his colleagues determined the isotopic and elemental composition of the solar wind using instruments characterized by innovative design that have provided the most comprehensive record of the solar wind composition under all solar wind conditions at all helio-latitudes. He discovered heavy interstellar pickup ions, from which the composition of the neutral gas of the Local Interstellar Cloud is determined, and the “Inner Source” of pickup ions. Johannes Geiss played a key role both in the in-situ measurements and modeling of molecular ions in comets, and the interpretation of these data. He and co-workers measured the composition of plasmas in the magnetospheres of Earth and Jupiter. Here we highlight Johannes Geiss’ many discoveries and seminal contributions to our knowledge of the composition of matter of the Sun, solar wind, interstellar gas, early universe, comets and magnetospheres.     

Structure of the Solar Wind and Compositional Variations

The composition of the solar wind is largely determined by the composition of the source material, i.e. the present-day composition of the outer convective zone. It is then modified by the processes which operate in the transition region and in the inner corona. In situ measurements of the solar wind composition give a unique opportunity to obtain information on the isotopic and elemental composition of the Sun. However, elemental — and to some degree also isotopic — fractionation can occur in the flow of matter from the outer convective zone into the interplanetary space. The most important examples of elemental fractionation are the well-known FIP/FIT effect (First Ionization Potential/Time) and the sometimes dramatic variations of the helium abundance relative to hydrogen in the solar wind. A thorough investigation of fractionation processes which cause compositional variations in different solar wind regimes is necessary to make inferences about the solar source composition from solar wind observations. Our understanding of these processes is presently improving thanks to the detailed diagnostics offered by the optical instrumentation on SOHO. Correlated observations of particle instruments on Ulysses, WIND, and SOHO, together with optical observations will help to make inferences for the solar composition. Continuous in situ observations of several isotopic species with the particle instruments on WIND and SOHO are currently incorporated into an experimental database to infer isotopic fractionation processes which operate in different solar wind regimes between the solar surface and the interplanetary medium. Except for the relatively minor effects of secular gravitational sedimentation which works at the boundary between the outer convective zone and the radiative zone, refractory elements such as Mg can be used as faithful witnesses to monitor the magnitude of these processes. With theoretical considerations it is possible to make inferences about the importance of isotopic fractionation in the solar wind from a comparison of optical and in situ observations of elemental fractionation with the corresponding models. Theoretical models and preliminary results from particle observations indicate that the combined isotope effects do not exceed a few percent per mass unit. In the worst case, which concerns the astrophysically important 3He/4He ratio, we expect an overall effect of at most several percent in the sense of a systematic depletion of the heavier isotope. Continued observations with WIND, SOHO, and ACE, and, with the revival of the foil technique, with the upcoming Genesis mission will further consolidate our knowledge about the relation between solar wind dynamics and solar wind composition. This revised version was published online in June 2006 with corrections to the Cover Date.     

Estimating fire properties by remote sensing

Contemporary knowledge of the role of fire in the global environment is limited by inadequate measurements of the extent and impact of individual fires. Observations by operational polar-orbiting and geostationary satellites provide an indication of fire occurrence but are ill-suited for estimating the temperature, area, or radiant emissions of active wildland and agricultural fres. Simulations here of synthetic remote sensing pixels comprised of observed high-resolution fire data together with ash or vegetation background demonstrate that fire properties including flame temperature, fractional area, and radiant-energy flux can best be estimated from concurrent radiance measurements at wavelengths near 1.6, 3.9, and 12 pm. Successful observations at night may be made at scales to at least 1 kmn for the cluster of fire data simulated herein. During the daytime, uncertainty in the composition of the background and its reflection of solar radiation would limit successful observations to a scale of approximately 100 mn or less. Measurements at three wavelengths in the long-wave infrared would be unaffected by reflected solar radiation and could be applied to separate flame properties in a binary system of flame and background. However, likely variation in the composition of the background and its temperature limit the approach to measurements that are of high resolution in relation to the scale of the flaming front. Alternative approaches using radiances at wavelengths near 4 and 12 pm alone must fail absent a correction for the background, yet the correction is made imprecise by uncertainty in composition of the background where it comprises more than one-third of a pixel.     

Element Abundances and Isotope Ratios in the Giant Planets and Titan

This paper reviews our present knowledge about elemental and isotopic ratios in the Giant Planets and Titan. These parameters can provide key information about the formation and evolution of these objects. Element abundances, especially after the results of the Galileo Probe Mass Spectrometer in Jupiter, strongly support the formation model invoking an initial core formation (Mizuno, 1980; Pollack et al., 1996). They also suggest that solar composition icy planetesimals (SCIPs) brought the heavy elements to Jupiter. The Jupiter value of D/H appears to be representative of the protosolar value, while the D/H enrichment observed on Uranus and Neptune is consistent with the formation scenario of these planets. The ¹⁵N/¹⁴N measurement in Jupiter seems to be representative of its protosolar value. Future measurements are expected to come from the Cassini and Herschel space mission, as well as the ALMA submillimeter observatory. This revised version was published online in August 2006 with corrections to the Cover Date.     

基于条件随机场的遥感图像语义标注

遥感图像包含的信息丰富,纹理复杂,而遥感图像语义标注又为后续的目标识别、检测、场景分析及高层语义的提取提供了重要信息和线索,这使其成为遥感图像理解领域中一个关键且极具挑战性的任务。首先针对遥感图像语义标注问题,提出采用条件随机场(CRF)框架对遥感图像的底层特征和上下文信息建模的方法,将Texton纹理特征与CRF中的自相关势能结合来捕捉遥感图像中的纹理信息及其上下文分布,采用组合Boosting算法进行Texton纹理特征选择和参数学习;然后将Lab空间中的颜色信息与CRF中的互相关势能结合来描述颜色上下文;最后用Graph Cut算法对CRF进行推导求解,得到图像自动语义标注结果。同时,建立了可见光遥感图像数据库Google-4,并对全部图像进行了人工标注。Google-4上的实验结果表明:采用CRF框架与Texton纹理特征和颜色特征相结合对遥感图像建模的方法与基于支持向量机(SVM)的方法相比较,能够取得更准确的语义标注结果。     

Venus Atmospheric Thermal Structure and Radiative Balance

From the discovery that Venus has an atmosphere during the 1761 transit by M. Lomonosov to the current exploration of the planet by the Akatsuki orbiter, we continue to learn about the planet’s extreme climate and weather. This chapter attempts to provide a comprehensive but by no means exhaustive review of the results of the atmospheric thermal structure and radiative balance since the earlier works published in Venus and Venus II books from recent spacecraft and Earth based investigations and summarizes the gaps in our current knowledge. There have been no in-situ measurements of the deep Venus atmosphere since the flights of the two VeGa balloons and landers in 1985 (Sagdeev et al., Science 231:1411–1414, 1986). Thus, most of the new information about the atmospheric thermal structure has come from different remote sensing (Earth based and spacecraft) techniques using occultations (solar infrared, stellar ultraviolet and orbiter radio occultations), spectroscopy and microwave, short wave and thermal infrared emissions. The results are restricted to altitudes higher than about 40 km, except for one investigation of the near surface static stability inferred by Meadows and Crisp (J. Geophys. Res. 101:4595–4622, 1996) from 1 \(\upmu\)m observations from Earth. Little information about the lower atmospheric structure is possible below about 40 km altitude from radio occultations due to large bending angles. The gaps in our knowledge include spectral albedo variations over time, vertical variation of the bulk composition of the atmosphere (mean molecular weight), the identity, properties and abundances of absorbers of incident solar radiation in the clouds. The causes of opacity variations in the nightside cloud cover and vertical gradients in the deep atmosphere bulk composition and its impact on static stability are also in need of critical studies. The knowledge gaps and questions about Venus and its atmosphere provide the incentive for obtaining the necessary measurements to understand the planet, which can provide some clues to learn about terrestrial exoplanets.     

Isotopic Abundances in Comets

Isotopic ratios in comets provide keys for the understanding of the origin of cometary material, and the physical and chemical conditions in the early Solar Nebula. We review here measurements acquired on the D/H, ¹²C/¹³C, ¹⁶O/¹⁸O, ¹⁴N/¹⁵N, ³²S/³⁴S ratios in dust and gases, and discuss their cosmogonic implications. The prospects for future measurements from cometary space missions and remote sensing observations at millimeter and submillimeter wavelengths are presented. This revised version was published online in August 2006 with corrections to the Cover Date.     

Radio physics of the outer solar system

The remote sensing of low frequency nonthermal radio emission is the astronomy of field and particle phenomena. Observations conducted from space lead to information about the composition and dynamic processes occurring in planetary magnetospheres as well as within the interplanetary and interstellar medium. The potential of this technique is demonstrated by considering observations obtained from Earth orbit missions.This is one of the publications by the Science Advisory Group.     

Solar Isotopic Composition as Determined Using Solar Energetic Particles

Solar energetic particles (SEPs) provide a sample of the Sun from which solar composition may be determined. Using high-resolution measurements from the Solar Isotope Spectrometer (SIS) onboard NASA’s Advanced Composition Explorer (ACE) spacecraft, we have studied the isotopic composition of SEPs at energies ≥20 MeV/nucleon in large SEP events. We present SEP isotope measurements of C, O, Ne, Mg, Si, S, Ar, Ca, Fe, and Ni made in 49 large events from late 1997 to the present. The isotopic composition is highly variable from one SEP event to another due to variations in seed particle composition or due to mass fractionation that occurs during the acceleration and/or transport of these particles. We show that various isotopic and elemental enhancements are correlated with each other, discuss the empirical corrections used to account for the compositional variability, and obtain estimated solar isotopic abundances. We compare the solar values and their uncertainties inferred from SEPs with solar wind and other solar system abundances and find generally good agreement.     

FTIR发射光谱遥测飞机发动机排放指数

根据飞机发动机排放测量的要求,针对传统测试系统复杂、技术难度大、成本高和实时性差的缺点,引入傅里叶变换红外（FTIR）被动遥测技术,使用FTIR发射光谱对飞机发动机排放气体组分进行定量分析,计算出排放指数。介绍了遥感测量原理和大气辐射的一个3层计算模型。采用Tensor27在无人机测试台获得某型发动机的一系列单通道光谱,计算出在14%,26%,50%,69%最大推力下,对应CO的排放指数分别为40.00,30.70,6.67,2.56 g/kg,对应NO的排放指数分别为0.79,2.09,8.24,38.70 g/kg。结果表明,FTIR发射光谱技术在飞行中的飞机发动机排放测试中具有巨大的应用前景。     

Reservoir for Comet Material: Circumstellar Grains

Primitive meteorites and interplanetary dust particles contain small quantities of dust grains with highly anomalous isotopic compositions. These grains formed in the winds of evolved stars and in the ejecta of stellar explosions, i.e., they represent a sample of circumstellar grains that can be analyzed with high precision in the laboratory. Such studies have provided a wealth of information on stellar evolution and nucleosynthesis, Galactic chemical evolution, grain growth in stellar environments, interstellar chemistry, and the inventory of stars that contributed dust to the Solar System. Among the identified circumstellar grains in primitive solar system matter are diamond, graphite, silicon carbide, silicon nitride, oxides, and silicates. Circumstellar grains have also been found in cometary matter. To date the available information on circumstellar grains in comets is limited, but extended studies of matter returned by the Stardust mission may help to overcome the existing gaps.     

Remote Observations of the Composition of Cometary Volatiles

The volatile species released in the coma are an important clue to the composition of the cometary nucleus ices. Their identification and the measurement of their abundances is possible by remote sensing. Considerable progress has been made recently using radio and infrared spectroscopy, especially with the observations of the two exceptional comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp).) 24 molecules likely to be parent molecules outgassed from the nucleus have now been identified. Significant upper limits exist for many other species, and the presence of unidentified lines suggests that further species are to be identified. In addition, isotopic varieties have been observed for hydrogen, carbon, nitrogen and sulphur. We will review these results with a special emphasis on the reliability of the identifications and of the molecular production rate determinations. A critical point is to assess whether a given species is a genuine parent molecule outgassed from nuclear ices, or is a secondary product coming from grains or from gas-phase photochemistry. Ground-based spectral imaging, such as radio interferometry, may help resolving this problem. This revised version was published online in June 2006 with corrections to the Cover Date.     

Validation of techniques for space based remote sensing of auroral precipitation and its ionospheric effects

Knowledge of the spatial distribution of auroral precipitation and its associated ionospheric effects is important both to scientific studies of the Earth's environment and successful operation of defense and communication systems. Observations with the best spatial and temporal coverage are obtained through remote sensing from space-based platforms. Various techniques have been used, including the detection of visible, ultraviolet and X-ray emissions produced by the precipitating particles. Interpretation of the measurements is enabled through theoretical modeling of the interaction of precipitating particles with atmospheric constituents. A great variety of auroral precipitation exists, with each kind differing in the type and energy distribution of the particles, as well as in its spatial and temporal behavior. Viable remote sensing techniques must be able to distinguish at least the species of particle, the total energy flux, and the average energy. Methods based on visible, ultraviolet and X-ray emissions meet these requirements to varying degrees. These techniques and the associated space instrumentation have evolved in parallel over the last two decades. Each of the methods has been tested using simultaneous measurements made by space-based imaging systems and ground-based measurements made by radars and optical instruments. These experiments have been extremely helpful in evaluating the performance and practicality of the instruments and the results have been crucial in improving instrument design for future remote sensing platforms. The next decade will see continued development and test of remote sensing instruments and the measurements, in addition to providing important operational data, will be increasingly more critical in addressing a number of scientific problems in auroral and atmospheric physics.     

Geology and Physical Properties Investigations by the InSight Lander

Although not the prime focus of the InSight mission, the near-surface geology and physical properties investigations provide critical information for both placing the instruments (seismometer and heat flow probe with mole) on the surface and for understanding the nature of the shallow subsurface and its effect on recorded seismic waves. Two color cameras on the lander will obtain multiple stereo images of the surface and its interaction with the spacecraft. Images will be used to identify the geologic materials and features present, quantify their areal coverage, help determine the basic geologic evolution of the area, and provide ground truth for orbital remote sensing data. A radiometer will measure the hourly temperature of the surface in two spots, which will determine the thermal inertia of the surface materials present and their particle size and/or cohesion. Continuous measurements of wind speed and direction offer a unique opportunity to correlate dust devils and high winds with eolian changes imaged at the surface and to determine the threshold friction wind stress for grain motion on Mars. During the first two weeks after landing, these investigations will support the selection of instrument placement locations that are relatively smooth, flat, free of small rocks and load bearing. Soil mechanics parameters and elastic properties of near surface materials will be determined from mole penetration and thermal conductivity measurements from the surface to 3–5 m depth, the measurement of seismic waves during mole hammering, passive monitoring of seismic waves, and experiments with the arm and scoop of the lander (indentations, scraping and trenching). These investigations will determine and test the presence and mechanical properties of the expected 3–17 m thick fragmented regolith (and underlying fractured material) built up by impact and eolian processes on top of Hesperian lava flows and determine its seismic properties for the seismic investigation of Mars’ interior.