Quantitative determination of the outgassing water vapor concentrations surrounding space vehicles from ion mass spectrometer measurements

Outgassing from materials as well as deliberate gaseous and liquid releases create contaminant clouds around spacecraft that can degrade both instrumentation and measurements. This paper describes a new method for estimating outgassing water vapor concentrations around space vehicles. Water vapor ions measured in the course of a rocket experiment performed at Eglin AFB, Florida, on December 12, 1980 at 2311 UT are utilized to demonstrate the technique. The H₂O concentration near the payload's surface is calculated using the rate coefficient for the fast charge transfer process, O⁺ + H₂O + H₂O⁺ + O, the source of the observed water vapor ions. It is found that the measured H₂O⁺ ions were produced within 3–4 cm of the sampling plate's surface and that the average H₂O pressure over this distance was relatively constant on ascent at 8 × 10^?6 torr, within a factor two, implying a steady outgassing rate.     

Positive ion composition and electron density in a combined auroral and NLC event

The positive ion composition and electron density were measured in the lower ionosphere above Kiruna in salvo A of CAMP (Cold Arctic Mesopause Project). The CAMP/P (S37/P) payload carrying a magnetic ion spectrometer, positive ion and electron probes, and propagation experiments was launched on 3 August 1982 2332 UT during extended Noctilucent Clouds (NLC) and auroral activities over Kiruna. The measured electron density was 5×10³cm^?3 at 80 km and 2.5×10⁵cm^?3 at 90 km. The increase of ion and electron densities in the D- and E-region during twilight was caused by precipitating auroral particles. The height distribution of the positive ions measured by the mass spectrometer in the mass range 19–280 amu is different from a winter flight with similar auroral conditions. Below 85.5 km proton hydrates H⁺(H₂O)₃ ? H⁺(H₂O)₈ were the dominant ions. The heaviest proton hydrates H⁺(H₂O)₇ and H⁺(H₂O)₈ were most abundant at 82–85.5 km, the altitude of visible NLC. Above 85.5 km O₂⁺ and NO⁺ became dominant. A small metal ion layer was observed between 90.5–93 km with a maximum ion density of 10% of the total positive ion density at 91 km altitude. The metal ion density disappeared within about a km below 90.5 km.     

Occurrence features of simultaneous H+- and He+-band EMIC emissions in the outer radiation belt

As an important loss mechanism of radiation belt electrons, electromagnetic ion cyclotron (EMIC) waves show up as three distinct frequency bands below the hydrogen (H⁺), helium (He⁺), and oxygen (O⁺) ion gyrofrequencies. Compared to O⁺-band EMIC waves, H⁺- and He⁺-band emissions generally occur more frequently and result in more efficient scattering removal of <～5?MeV relativistic electrons. Therefore, knowledge about the occurrence of these two bands is important for understanding the evolution of the relativistic electron population. To evaluate the occurrence pattern and wave properties of H⁺- and He⁺-band EMIC waves when they occur concurrently, we investigate 64 events of multi-band EMIC emissions identified from high quality Van Allen Probes wave data. Our quantitative results demonstrate a strong occurrence dependence of the multi-band EMIC emissions on magnetic local time (MLT) and L-shell to mainly concentrate on the dayside region of L?=?～4–6. We also find that the average magnetic field amplitude of H⁺-band waves is larger than that of He⁺-band waves only when L?<?4.5 and AE¹?<?300?nT, and He⁺-band emissions are more intense under all other conditions. In contrast to 5 events that have average H⁺-band amplitude over 2 nT, 19 events exhibit >2 nT He⁺-band amplitude, indicating that the He⁺-band waves can be more easily amplified than the H⁺-band waves under the same circumstances. For simultaneous occurrences of the two EMIC wave bands, their frequencies vary with L-shell and geomagnetic activity: the peak wave frequency of H⁺-band emissions varies between 0.25 and 0.8 f_cp with the average between 0.25 and 0.6 f_cp, while that of He⁺-band emissions varies between 0.03 and 0.23 f_cp with the average between 0.05 and 0.15 f_cp. These newly observed occurrence features of simultaneous H⁺- and He⁺-band EMIC emissions provide improved information to quantify the overall contribution of multi-band EMIC waves to the loss processes of radiation belt electrons.     

Temporal and spatial variations observed in the ionospheric composition of Venus: Implications for empirical modelling

In situ measurements of the thermal ion composition of the ionosphere of Venus have been obtained for a period of two Venus years from the Bennett rf ion mass spectrometer on the Pioneer Venus Orbiter. Ion measurements within an altitude interval of 160 to 300 kilometers, corresponding to an overall latitude interval of about ?4° to 34°N, are assembled from the interval December 1978 to March 1980. This time interval corresponds to two revolutions of Venus about the Sun, designated as two “diurnal cycles”. The distributions of several ion species in this data base have been sorted to identify temporal and spatial variations, and to determine the feasibility of an analytical representation of the experimental results. The first results from the sorting of several prominent ions including O⁺, O₂⁺, and H⁺ and several minor ions including CO₂⁺, C⁺, and H₂⁺ reveal significant diurnal variations, with superimposed modulation associated with solar activity and solar wind variations. The diurnal variation consists of strong day to night contrast in the ion concentrations, with differences of one to two orders of magnitude, depending upon ion mass and altitude. The concentrations of O₂⁺, O⁺, CO₂⁺ and C⁺ peak throughout the dayside decreasing sharply at the terminators to nightside levels, lower by one to two orders of magnitude relative to the dayside. The diurnal variations of the light ions H⁺ and H₂⁺ peak during the night, exhibiting asymmetric nightside bulges favoring the pre-dawn sector, near 0400 solar hour angle. Superimposed upon the diurnal distributions are modulation signatures which correlate well with modulation in the F_10.7 index, indicating a strong influence of solar variability on the ion production and distribution. The influence of solar wind perturbations upon the ion distributions are also indicated, by a significant increase in the scatter of the observations with increasing altitude as higher altitudes, approaching 300 kilometers, are sampled. Together, these temporal and spatial variations make the task of modelling the ionosphere of Venus both very interesting and challenging.     

The O2+ vibrational distribution in the Venusian ionosphere

Calculations are presented of the vibrational distribution of O₂⁺ in the Venusian ionosphere for a model atmosphere based on Pioneer Venus data. At 100 km, quenching precludes the survival of vibrationally excited O₂⁺. At the exobase, near 200 km, more than half are vibrationally excited. The effects of vibrationally excited O₂⁺ on the hot oxygen corona and the airglow are discussed.     

Measurement of minor species (H2, Cl,O3, NO) in the earth's atmosphere by the occultation technique

The stellar occultation technique is a clean and powerful means of detecting and quantifying minor gases in the earth's atmosphere. The results obtained are totally insensitive to knowledge of the absolute flux of the star, and are not influenced by instrument calibration problems. Pioneering observations of nocturnal mesospheric ozone and thermospheric molecular oxygen by the stellar occultation technique were made in 1970 and 1971 with the Wisconsin stellar photometers on board the Orbiting Astronomical Observatory-2. A limb crossing geometry was used. The high resolution Princeton ultraviolet spectrometer aboard Copernicus was used in the summers of 1975, 1976 and 1977 to measure altitude profiles of molecular hydrogen, atomic chlorine and nitric oxide in addition to ozone and molecular oxygen. A limb grazing geometry was employed. The ozone densities show wide variation from orbit to orbit and particularly betewen the OAO-2 and Copernicus observations. A H₂ density of 1×10⁸ cm^?3 at 95 km, and a NO density less than 10⁶ cm^?3 for altitudes greater than 85 km were measured.     

Mass spectrometric measurements of stratospheric ions

Recent in situ measurements with balloon borne quadrupole mass spectrometers, between 20 and 45 km altitude, are reviewed and discussed.The major stratospheric positive ions observed are proton hydrates [H⁺(H₂O)_n] and non proton hydrates of the form H⁺X_m(H₂O)₂. The data analysis allows a derivation of the vertical mixing ratio profile of X (most probably CH₃CN), which is compared with recent model calculations. From negative ion composition data, showing the presence of NO₃^? and HSO₄^? cluster ions, the density of sulfuric acid in the stratosphere is deduced. The implications of these findings on our understanding of the sulfur chemistry is briefly treated.Finally some other aspects such as contamination, cluster break up and the use of stratospheric ion mass spectra for determination of thermochemical data and other minor constituents are discussed.     

Model calculations of the dayside ionosphere of Venus

Model calculations of the dayside ionosphere of Venus are presented. The coupled continuity and momentum equations were solved for O₂⁺, O⁺, CO₂⁺, C⁺, N⁺, He⁺, and H⁺ density distributions, which are compared with measurements from the Pioneer Venus ion mass spectrometer. The agreement between the model results and the measurements is good for some species, such as O⁺, and rather poor for others, such as N⁺, indicating that our understanding of the dayside ion composition of Venus is incomplete. The coupled heat conduction equations for ions and electrons were solved and the calculated temperatures compared with Pioneer Venus measurements. It is shown that fluctuations in the magnetic field have a significant effect on the energy balance of the ionosphere.     

In situ results on the variation of neutral atmospheric hydrogen at venus

The concentrations of neutral hydrogen within the atmosphere of Venus are investigated for the period 1979–1980. During this period, the planet made nearly three orbits about the Sun, so that nearly three complete diurnal cycles were observed from the Pioneer Venus Orbiter (PVO). Values of n(H) are derived from in-situ ion and neutral composition measurements from the Orbiter Ion Mass Spectrometer (OIMS) and the Orbiter Neutral Mass Spectrometer (ONMS) using a charge exchange relationship involving O⁺, H⁺, O and CO₂. The dawn bulge in the diurnal distribution of n(H), reported from the first diurnal cycle by Brinton et al., is found to persist with n(H) peaking at levels near 2 - 5 × 10⁷/cm³ at altitudes below 165 km. At peak levels, the bulge exhibits a concentration ratio up to 400/1 relative to dayside values. Large day to day variations of up to a factor of five in n(H) are frequently encountered, and are attributed to perturbations induced by the solar wind interaction. These short term variations, plus a suggestion of some local time variation in the bulk location, make precise assessment of interannual variations in the n(H) difficult. Between the first diurnal cycle in early 1979 and the third in mid 1980, the decline in solar euv flux was of the order of 10% or less. Allowing for uncertainties due to short term variations, no clear evidence is found for an interannual variation in the hydrogen concentrations.     

Study on O2 generation and CO2 absorption capability of four co-cultured salad plants in an enclosed system

The ability to generate O₂ and absorb CO₂ of several co-cultured vegetable plants in an enclosed system was studied to provide theoretical reference for the future man-plant integrated tests. Four kinds of salad plants (Lactuca sativa L. var. Dasusheng, Lactuca sativa L. var. Youmaicai, Gynura bicolor and Cichorium endivia L.) were grown in the CELSS Integration Test Platform (CITP). The environmental factors including O₂ and CO₂ concentration were continuously monitored on-line and the plant biomass was measured at the end of the test. The changing rules of O₂ and CO₂ concentration in the system were basically understood and it was found that the O₂ generated by the plants could satisfy the respiratory needs of 1.75 persons by calculation. It was also found that the plants could absorb the CO₂ breathed out by 2 persons when the light intensity was raised to 550 mmol m⁻² s⁻¹ PPF. The results showed that the co-cultured plants hold good compatibility and excellent O₂-generating and CO₂-absorbing capability. They could also supply some fresh edible vegetable for a 2-person crew.     

Pressure,O2, and CO2, in aquatic Closed Ecological Systems

Pressure increased during net photosynthetic O₂ production in the light and decreased during respiratory O₂ uptake during the dark in aquatic Closed Ecological Systems (CESs) with small head gas volumes. Because most CO₂ will be in the liquid phase as bicarbonate and carbonate anions, and CO₂ is more soluble than O₂, volumes of gaseous CO₂ and gaseous O₂ will not change in a compensatory manner, leading to the development of pressure. Pressure increases were greatest with nutrient rich medium with NaHCO₃ as the carbon source. With more dilute media, pressure was greatest with NaHCO₃, and less with cellulose or no-added carbon. Without adequate turbulence, pressure measurements lagged dissolved O₂ concentrations by several hours and dark respiration would have been especially underestimated in our systems (250–1000 ml). With adequate turbulence (rotary shaker), pressure measurements and dissolved O₂ concentrations generally agreed during lights on/off cycles, but O₂ measurements provided more detail. At 20 °C, 29.9 times as much O₂ will distribute into the gas phase as in the liquid, per unit volume, as a result of the limited solubility of O₂ in water and according to Henry’s Law. Thus even a small head gas volume can contain more O₂ than a larger volume of water. When both dissolved and gaseous O₂ and CO₂ are summed, the changes in Total O₂ and CO₂ are in relatively close agreement when NaHCO₃ is the carbon source. These findings disprove an assumption made in some of Taub’s earlier research that aquatic CESs would remain at approximately atmospheric pressure because approximately equal molar quantities of O₂ and CO₂ would exchange during photosynthesis and respiration; this assumption neglected the distribution of O₂ between water and gas phases. High pressures can occur when NaHCO₃ is the carbon source in nutrient rich media and if head-gas volumes are small relative to the liquid volume; e.g., one “worse case” condition developed 800 mm Hg above atmospheric pressure and broke the glass container. Plastic screw cap closures are likely to leak at high pressures and should not be assumed to seal unless tested at appropriate pressures. Pressure can be reduced by having larger head-gas volumes and using less concentrated nutrient solutions. It is important that pressure changes be considered for both safety and closure, and if total O₂ is used as the measure of net photosynthesis and respiration, the O₂ in the gas phase must be added to the dissolved O₂.     

Transport of ions in presence of induced electric field and electrostatic turbulence: Source of ions injected into ring current

The transport of ions from the polar ionosphere to the inner magnetosphere during stormtime conditions has been computed using a Monte Carlo diffusion code. The effect of the electrostatic turbulence assumed to be present during the substorm expansion phase was simulated by a process that accelerated the ions stochastically perpendicular to the magnetic field with a diffusion coefficient proportional to the energization rate of the ions by the induced electric field. This diffusion process was continued as the ions were convected from the plasma sheet boundary layer to the double-spiral injection boundary. Inward of the injection boundary, the ions were convected adiabatically. By using as input an O⁺ flux of 2.8 × 10⁸ cm^?2 s^?1 (w > 10 eV) and an H⁺ flux of 5.5 × 10⁸ cm^?2 s^?1 (w > .63 eV), the computed distribution functions of the ions in the ring current were found to be in good agreement, over a wide range in L (4 to 8), with measurements made with the ISEE-1 satellite during a storm. This O⁺ flux and a large part of the H⁺ flux are consistent with the DE satellite measurements of the polar ionospheric outflow during disturbed times.     

F-Region ion composition modeling

Measurements of the principal ion species of the F₁- and F₂- regions have been used to develop an empirical model of the ion composition for altitudes between 150 and 500 km. The species measured by the S3-1 satellite include N⁺, O⁺, N₂⁺, NO⁺ and O₂⁺. The data were obtained near the minimum of the solar cycle, thus limited information on the ionospheric variation with solar flux is available. However, the range of latitude, altitude, local time and geomagnetic activity does provide a useful basis for modeling the F-region. The ion composition measurements have been used to provide a model for relative ion composition which is compatible with the total ion density from the International Reference Ionosphere model.     

Nightside 135.6 nm emission enhancements of mid/low latitudes during geomagnetic storms as observed by the ionosphere PhotoMeter (IPM) on the Chinese meteorological satellite FY-3D

IPM has detected nightside 135.6 nm emission enhancements over a wide latitude range, from the sub-auroral latitudes to the equatorial regions during geomagnetic storms. Our work, presented in this paper, uses the data of IPM to understand these 135.6 nm emission enhancements during of geomagnetic storms and studies the variations of total electron content (TEC) and the F₂ layer peak electron density (NmF2) in the region of enhanced emissions. Middle and low latitude emission enhancements are presented during several medium storms in 2018. The variations of both the integrated electron content (IEC) derived from the nighttime OI 135.6 nm emission by IPM and TEC from the International GNSS Service (IGS) relative to the daily mean of magnetically quiet days of per each latitude bin (30°≦geographic latitude < 40°, 15°≦geographic latitude < 30°, 0°≦geographic latitude < 15°, ?15°≦geographic latitude < 0°, ?30°≦geographic latitude < -15°, ?40°≦geographic latitude < -30°) are investigated and show that on magnetically storm day, IEC by IPM always increases, while TEC from IGC may increase or decrease. Even if both increase, the increase of IEC is greater than that of TEC. From the comparison of IEC and TEC during magnetic storms, it can be seen that the enhancement of the nighttime 135.6 nm emissions is not entirely due to the ionospheric change. The time of IEC enhancements at each latitude bin is in good agreement, which mainly corresponds to the main phase time of the geomagnetic storm event and lasts until the recovery phase. The available ground-based ionosonde stations provide the values of NmF2 which match the 135.6 nm emissions measured by IPM in space and time. The variations of NmF2 squared can characterize the variations of the OI 135.6 nm emissions caused by O⁺ ions and electrons radiative recombination. The study results show that the OI 135.6 nm emission enhancements caused by O⁺ ions and electrons radiative recombination (where NmF2 squared increases) are obviously a contribution to the measured 135.6 nm emission enhancements by IPM. The contribution accounts for at least one of all contributions to the measured 135.6 nm emission enhancements by IPM. However, where the NmF2 squared provided by ionosonde decrease or change little (where the OI 135.6 nm emissions cause by O⁺ ions and electrons radiative recombination also decrease or change little), the emission enhancements measured by IPM at storm-time appear to come from the contributions of other mechanisms, such as energetic neutral atoms precipitation, or the mutual neutralization emission (O+ + O-→2O + h? (135.6 nm)) which also occupies a certain proportion in 135.6 nm airglow emission at night.     

Ion precipitation into the ionosphere during geomagnetic storms

This review presents numerous recent examples of interesting variations in the composition and intensity of the hot ion flux (10 eV - 15 keV/e) provided by the AUREOL-3 satellite as a function of latitude and local time during periods of magnetic activity. In particular, these results reveal that although H⁺ is the most abundant ion during magnetically quiet periods, the ion composition of hot plasma at ionospheric altitudes is quite variable, and depends strongly on magnetic activity; results obtained during main and recovery phases of several magnetic storms demonstrate clearly (below 15 keV/Q) the great importance of the low altitude ionospheric source (H⁺, O⁺, and to a lesser degree He⁺) particularly at low latitudes (L ～ 3 - 4) where the flux of O⁺ ions becomes very large and even dominates. The results of the AUREOL-3 ion spectrometers establish the fact that upflowing suprathermal ionospheric ions (E_i < 100 eV/e) appear over large regions of the auroral ionosphere, the polar caps, and the polar cusp, as well as in or at the boundary of the plasmasphere during magnetospheric substorms or magnetic storms, and may consequently contribute significantly to the plasma sheet and to the inner storm time ring current. Most of the properties of the storm time ring current found by the GEOS, SCATHA, and ISEE satellites apply to lower altitudes, although the role of the ionospheric and/or plasmaspheric source appears accentuated.     

Collisional excitation of vinylidene (H2CC)

Though H₂CO, H₂CS, H₂CCC, H₂CCCC, H₂CCO have been identified in cool interstellar molecular clouds, identification of H₂CC is still awaited. To analyze its spectrum, collisional rate coefficients are required. We have calculated collisional rate coefficients for rotational transitions between 23 levels of ortho and para H₂CC for kinetic temperatures 10, 20, 30, 40, and 50 K. The scattering problem is analyzed using the computer code MOLSCAT where the colliding partner is He atom. The interaction between H₂CC and He has been calculated with GAUSSIAN 2003. For the interaction potential obtained with GAUSSIAN 2003, MOLSCAT is used to derive the parameters q(L,M,M^′|E)$q(L\text{,}M\text{,}{M}^{\prime }|E)$ as a function of energy E   of the colliding partner. After averaging the parameters q(L,M,M^′|E)$q(L\text{,}M\text{,}{M}^{\prime }|E)$ over a Maxwellian distribution, the parameters Q(L,M,M^′|T)$Q(L\text{,}M\text{,}{M}^{\prime }|T)$ as a function of the kinetic temperature T in the cloud are obtained. Finally, the collisional rate coefficients have been calculated.     

Antioxidant capacity reduced in scallions grown under elevated CO2 independent of assayed light intensity

Long-duration manned space missions mandate the development of a sustainable life support system and effective countermeasures against damaging space radiation. To mitigate the risk of inevitable exposure to space radiation, cultivation of fresh fruits and vegetables rich in antioxidants is an attractive alternative to pharmacological agents. However it has yet to be established whether antioxidant properties of crops can be preserved or enhanced in a space environment where environmental conditions differ from that which plants have acclimated to on earth. Scallion (Allium fistulosum) rich in antioxidant vitamins C and A, and flavonoids was used as a model plant to study the impact of a range of CO₂ concentrations and light intensities that are likely encountered in a space habitat on food quality traits. Scallions were hydroponically grown in controlled environmental chambers under a combination of 3 CO₂ concentrations of 400, 1200 and 4000 μmol mol⁻¹ and 3 light intensity levels of 150, 300, 450 μmol m⁻² s⁻¹. Total antioxidant activity (TAA) of scallion extracts was determined using a radical cation scavenging assay. Both elevated CO₂ and increasing light intensity enhanced biomass accumulation, but effects on TAA (based on dry weight) differed. TAA was reduced for plants grown under elevated CO₂, but remained unchanged with increases in light intensity. Elevated CO₂ stimulated greater biomass production than antioxidants, while an increase in photosynthetic photo flux promoted the synthesis of antioxidant compounds at a rate similar to that of biomass. Consequently light is a more effective stimulus than CO₂ for antioxidant production.     

Composition of the Venus atmosphere below 100 km altitude

Our current knowledge on the composition of the Venus atmosphere in the altitude range from the surface to 100 km is compiled. Gases that have been measured, and whose mixing ratios are assumed to be constant with altitude, are CO₂, N₂, He, Ne, Ar, and Kr. Gases that have been identified in the lower and/or middle atmosphere, but whose mixing ratios may depend on altitude, latitude and/or local time, are CO, H₂O, HCl, HF, and SO₂. Conflicting data or only upper limits exist on some important trace gases, such as O₂, H₂, and Cl₂. The latter two are key constituents in the photochemistry of the middle atmosphere of Venus. The chapter concludes with a listing of the isotopic abundances of elements measured in the Venus atmosphere.     

Measurements of H I and O VI velocity distributions in the extended solar corona with UVCS/SOHO and UVCS/Spartan 201

The Ultraviolet Coronagraph Spectrometer on the Solar and Heliospheric Observatory, UVCS/SOHO, and the Ultraviolet Coronal Spectrometer on the Spartan 201 satellite, UVCS/Spartan, have been used to measure H I 1215.67 Å line profiles in polar coronal holes of the Sun at projected heliocentric heights between 1.5 and 3.0 R_⊙. UVCS/SOHO also measured line profiles for H I 1025.72 Å, O VI 1032/1037 Å, and Mg X 625 Å. The reported UVCS/SOHO observations were made between 5 April and 21 June 1996 and the UVCS/Spartan observations were made between 11 and 12 April 1993. Both sets of measurements indicate that a significant fraction of the protons along the line of sight in coronal holes have velocities larger than those for a Maxwellian velocity distribution at the expected electron temperature. Most probable speeds for O⁵⁺ velocity distributions along the lines of sight are smaller than those of H⁰ at 1.5 R_⊙, are comparable at about 1.7 R_⊙ and become significantly larger than the H⁰ velocities above 2 R_⊙. There is a tendency for the O⁵⁺ line of sight velocity distribution in concentrations of polar plumes to be more narrow than those in regions away from such concentrations. UVCS/SOHO has identified 31 spectral lines in the extended solar corona.