Composition of the Venus atmosphere below 100 km altitude

Our current knowledge on the composition of the Venus atmosphere in the altitude range from the surface to 100 km is compiled. Gases that have been measured, and whose mixing ratios are assumed to be constant with altitude, are CO₂, N₂, He, Ne, Ar, and Kr. Gases that have been identified in the lower and/or middle atmosphere, but whose mixing ratios may depend on altitude, latitude and/or local time, are CO, H₂O, HCl, HF, and SO₂. Conflicting data or only upper limits exist on some important trace gases, such as O₂, H₂, and Cl₂. The latter two are key constituents in the photochemistry of the middle atmosphere of Venus. The chapter concludes with a listing of the isotopic abundances of elements measured in the Venus atmosphere.     

Recent advances in upper atmospheric structure

A possible quantitative explanation of the semi-annual variation in thermospheric density has been obtained in terms of a semi-annual variation in the computed globally averaged vertical energy carried by propagating tides from the lower and middle atmosphere into the thermosphere. The effect is primarily due to seasonal changes in the distribution of water vapor and in the solar declination angle and Sun-Earth distance. An MSIS-83 empirical model of the thermosphere, representing a revision of the earlier MSIS models, has been prepared. The database used covers a wider range of solar activity than previous models and an improved magnetic storm representation is included. Atomic oxygen profiles in the 100 to 160 km altitude region of the auroral thermosphere have been recalculated from measured quenching of N₂(A³∑_u⁺) using the latest laboratory rates and the results are in good agreement with the mean CIRA 1972 profile. A new empirical model of thermospheric variations with geomagnetic activity has been developed incorporating variations with local magnetic time, latitude dependent terms which can vary with the magnitude of the geomagnetic disturbance, and an altitude dependent expression for the equatorial wave. A new index ML, derived from the AL index, has been developed that appears to have promise to represent the variations of thermospheric species with geomagnetic activity. Satellite measured values of solar UV flux, ground-based observations of CaK plages, sunspot numbers and 10.7 cm solar radio flux have been analyzed for temporal variations. Some differences have been identified and the significance to empirical and theoretical upper atmosphere models is discussed.     

利用COSMIC数据研究顶部电离层O+扩散流的统计特征

从等离子体运动方程出发, 利用COSMIC星座的掩星数据, 借助相关经验模式, 计算了太阳活动低年顶部电离层O+场向扩散速度和扩散通量, 并分析了其全球分布和日变化特征. 结果表明, 白天等离子体扩散速度的方向随高度增加由向下(极向)逐步变为向上(赤道向), 方向转变的高度一般在hmF2+80 km以下. 在白天较高高度, 南北磁纬10o ~20 o存在着向上方向的最大扩散速度和扩散通量; 而在夜间, 南北磁纬30o~40 o存在向下方向的最大扩散速度和扩散通量. 在分点, 南北半球的扩散通量和扩散速度大致对称; 而在至点, 扩散通量存在着明显的南北半球不对称现象. 另外, 不同纬度的扩散速度有着不同的日变化特征.      

Vertical distribution of NH3 in the upper Jovian atmosphere from IUE observations

The first unambiguous identification of ammonia in the upper atmosphere of Jupiter has been obtained from the observation of individual NH₃ bands in an IUE high resolution spectrum in the 2100–2400 Å spectral range. The variation with wavelength of the strengths of these NH₃ bands implies that the NH₃ abundance has to be strongly reduced by photolysis in the upper jovian atmosphere. Preliminary analysis by means of scattering models shows that the ammonia mixing ratio cannot be constant with altitude. The mixing ratio NH₃/H₂ ranges from 5 10^?8 to 5 10^?7 at the 250 mb pressure level, and decreases as P or P² toward higher altitudes.     

Low altitude dose measurements from APEX, CRRES and DMSP

Dosimeter data taken on the APEX (1994–1996), CRRES (1990–1991) and DMSP (1984–1987) satellites have been used to study the low altitude (down to 350 km) radiation environment. Of special concern has been the inner edge of the inner radiation belt due to its steep gradient. We have constructed dose models of the inner edge of the belt from all three spacecraft and put them into a personal computer utility, called APEXRAD, that calculates dose for user-selected orbits. The variation of dose for low altitude, circular orbits is given as a function of altitude, inclination and particle type. Dose-depth curves show that shielding greater than 1/4 in Al is largely ineffectual for low altitude orbits. The contribution of outer zone electrons to low altitude dose is shown to be important only for thin shields and to have significant variation with magnetic activity and solar cycle.     

Temporal and spatial variations observed in the ionospheric composition of Venus: Implications for empirical modelling

In situ measurements of the thermal ion composition of the ionosphere of Venus have been obtained for a period of two Venus years from the Bennett rf ion mass spectrometer on the Pioneer Venus Orbiter. Ion measurements within an altitude interval of 160 to 300 kilometers, corresponding to an overall latitude interval of about ?4° to 34°N, are assembled from the interval December 1978 to March 1980. This time interval corresponds to two revolutions of Venus about the Sun, designated as two “diurnal cycles”. The distributions of several ion species in this data base have been sorted to identify temporal and spatial variations, and to determine the feasibility of an analytical representation of the experimental results. The first results from the sorting of several prominent ions including O⁺, O₂⁺, and H⁺ and several minor ions including CO₂⁺, C⁺, and H₂⁺ reveal significant diurnal variations, with superimposed modulation associated with solar activity and solar wind variations. The diurnal variation consists of strong day to night contrast in the ion concentrations, with differences of one to two orders of magnitude, depending upon ion mass and altitude. The concentrations of O₂⁺, O⁺, CO₂⁺ and C⁺ peak throughout the dayside decreasing sharply at the terminators to nightside levels, lower by one to two orders of magnitude relative to the dayside. The diurnal variations of the light ions H⁺ and H₂⁺ peak during the night, exhibiting asymmetric nightside bulges favoring the pre-dawn sector, near 0400 solar hour angle. Superimposed upon the diurnal distributions are modulation signatures which correlate well with modulation in the F_10.7 index, indicating a strong influence of solar variability on the ion production and distribution. The influence of solar wind perturbations upon the ion distributions are also indicated, by a significant increase in the scatter of the observations with increasing altitude as higher altitudes, approaching 300 kilometers, are sampled. Together, these temporal and spatial variations make the task of modelling the ionosphere of Venus both very interesting and challenging.     

An experimental and empirical model of electron temperature for altitudes of 500 to 1000 km and for a high solar activity period

On the basis of systematic electron temperature measurements onboard the Interkosmos-19 satellite, an experimental global model of electron temperature T_e has been constructed; namely, a set of samples representing 10 intervals of measured T_e, accompanied by values of the geographic longitude, solar zenith angle, season of the year, Covington index, Dst and Kp, grouped according to the invariant latitude, geomagnetic time and altitude. On the basis of the experimental model, the coefficients of the empirical models for the summer and winter seasons, for geophysically quiet conditions, and for heights of 520, 600, 920 and 1000 km are calculated. For heights of 680, 760 and 840 km with fewer data available, the coefficients are provisional.     

Vertical profiles of halocarbons in the stratosphere

Stratospheric air samples collected between 10 and 35 km altitude my means of a cryogenic sampler were analyzed by gaschromatography. Thus vertical profiles of source gases for halogen radicals were derived, such as CCl₄, CCl₃F, CCl₂F₂, CClF₃, CF₄, C₂F₃Cl₃, C₂F₄Cl₂, C₂F₅Cl, C₂F₆, CH₃Cl, CH₃CCl₃, CHF₂Cl, CH₃Br, CBrF₃, and CBrCl₂F. Systematic discrepancies between measured and modelled halocarbon profiles point to deficiencies of present one- and two-dimensional models. Measurements of fully halogenated hydrocarbons provide a tool for systematically studying these deficiencies and thus improving the models.     

Mass spectrometry in the stratosphere

During the last few years a gas expansion system, combined with a mass spectrometer has been developed and successfully flown in the stratosphere. Neutral gas particles are formed into a molecular beam which traverses the ion source of the mass spectrometer without wall interactions. Vertical profiles of constituents such as H₂O, CO₂ and O₃ have been measured in the altitude range of 20 to 40 km during balloon descents. Isotopes of major atmospheric gases (N₂, O₂, Ar) provided in-flight calibration standards.Before each flight the mass spectrometer system was calibrated in the laboratory for many gases of interest, including ozone. Mixing ratios of ozone determined from recent flights have accuracies of better than 5%. The sensitivity of the system was sufficiently high to detect, in addition, the heavy isotope of ozone at mass 50. A pronounced enhancement of heavy ozone in the upper stratosphere has been found. The mass spectrometer system provides the unique opportunity to perform in the stratospherein-situ measurements combined with isotopic studies.     

Comparing ionospheric models with mid-latitude ionosonde observations

The purpose of this research work is to validate the ionospheric models (IRI and CHIU) to assess its suitability and usefulness as an operational tool. The ionospheric model is a computer model designed to predict the state of the global ionosphere for 24 h. The scope was limited to conduct comparisons between the predicted F₂ layer critical frequencies (f₀F₂) against observed ionosonde data. The ionospheric prediction model (IPM) was designed to predict by using monthly median sunspot number, while the observation data are taken from two digital ionospheric sounding stations (Okinawa, 26.28N, 127.8E and Wakkanai, 45.38N, 141.66E) which lies within the mid-latitude region of the globe. Analysis of the f₀F₂ data from stations for year (2001) with high solar activity and year (2004) with low solar activity, four months (March, June, September and December) chosen based primarily on data availability. From results it seen that the ratio between monthly median predicted and observed f₀F₂ values for each model used in this research work and for the chosen months was nonlinear with local time, so the empirical formula for applying correction factors were determined, these formula can be used to correct the error occurred in predicted f₀F₂ value.     

F-Region ion composition modeling

Measurements of the principal ion species of the F₁- and F₂- regions have been used to develop an empirical model of the ion composition for altitudes between 150 and 500 km. The species measured by the S3-1 satellite include N⁺, O⁺, N₂⁺, NO⁺ and O₂⁺. The data were obtained near the minimum of the solar cycle, thus limited information on the ionospheric variation with solar flux is available. However, the range of latitude, altitude, local time and geomagnetic activity does provide a useful basis for modeling the F-region. The ion composition measurements have been used to provide a model for relative ion composition which is compatible with the total ion density from the International Reference Ionosphere model.     

Trace constituents measurements deduced from spectrometric observations on-board spacelab

The observation of infrared absorption lines by means of a grille spectrometer on board Spacelab 1 allows the determination of Co₂ and CO in the low thermosphere and in the middle atmosphere. Equal abundances of CO and CO₂ are found at 115 ± 5 km altitude. CO₂ is observed to depart from its homospheric volume mixing ratio near 100 km, dropping by a factor of 10,15 km higher. The CO largest number density is observed near 70 km altitude, close to the H Lyman alpha photoproduction peak.The analysis of one run dedicated to the observation of water vapor shows a middle atmospheric mixing ratio of this species within the limits : 3 to 8 ppmv up to 70 km altitude, with the indication of an increase from 30 to 50 km altitude. The H₂O mixing ratio drops very rapidly above 70 km.The comparison of the results from strong and weak H₂O and CO₂ lines shows the need to refine the line profile model.     

基于相控阵雷达波束篱笆的空间碎片数量与分布估计方法

随着载人航天与空间站等航天活动的增多,不能有效防护、也无法定期跟踪和编目的小尺寸(尤其是1～10 cm)碎片的危害越来越受到关注,这些碎片信息的获取依赖于统计采样技术.针对简化的相控阵雷达波束篱笆空间碎片探测模式,提出了一种采用统计技术估计空间碎片总数量以及高度和倾角分布的方法.将碎片穿越波束篱笆的过程用Poisson分布来建模,根据观测时段内穿越波束篱笆目标的平均到达率及测量的轨道高度和倾角数据来估计给定轨道高度范围或倾角范围内碎片的数量,进而得到碎片的总数量以及碎片数量随轨道高度或倾角的分布.在获取雷达散射截面信息时,该方法还可用于估计碎片数量随尺寸的分布.通过仿真实验验证了该方法的有效性.      

Properties of the neutral density and composition in the thermosphere

Measurements of the density and composition of the thermosphere between 150 and 500 km, which were obtained by the S3-1 satellite, have been compared with the Jacchia and MSIS models. The measurements of the densities of O, N₂, N and Ar show some differences from the current models which should be considered during the preparation of the next CIRA model. The Ar measurements are particularly useful in examining the response of the neutral atmosphere to geomagnetic heating. These results are useful in establishing the appropriate lower boundary conditions for modeling of the thermosphere.     

Forecasting space weather: Can new econometric methods improve accuracy?

Space weather forecasts are currently used in areas ranging from navigation and communication to electric power system operations. The relevant forecast horizons can range from as little as 24 h to several days. This paper analyzes the predictability of two major space weather measures using new time series methods, many of them derived from econometrics. The data sets are the A_p geomagnetic index and the solar radio flux at 10.7 cm. The methods tested include nonlinear regressions, neural networks, frequency domain algorithms, GARCH models (which utilize the residual variance), state transition models, and models that combine elements of several techniques. While combined models are complex, they can be programmed using modern statistical software. The data frequency is daily, and forecasting experiments are run over horizons ranging from 1 to 7 days. Two major conclusions stand out. First, the frequency domain method forecasts the A_p index more accurately than any time domain model, including both regressions and neural networks. This finding is very robust, and holds for all forecast horizons. Combining the frequency domain method with other techniques yields a further small improvement in accuracy. Second, the neural network forecasts the solar flux more accurately than any other method, although at short horizons (2 days or less) the regression and net yield similar results. The neural net does best when it includes measures of the long-term component in the data.     

The influence of radiative cooling and turbulence on the heat budget of the thermosphere

Numerical models of the thermal budget of the Earth's upper atmosphere in the height range of 90–500km are developed. The main sources and sinks of energy including infra-red radiative cooling by vibrational-rotational bands of NO, CO₂, OH and O₃ as well as heating and cooling arising from dissipation of turbulent energy and eddy heat transport are taken into account. The calculated temperature and density height profiles are in good agreement with the respective profiles from CIRA 72 and Jacchia 1977 models. It is shown for the models considered that IR-radiative cooling by CO₂ and NO in the 15μ and 5.3μ bands, not eddy turbulence provides the major loss of heat from 90 to 180km.     

Latitudinal variation of the topside electron temperature at different levels of solar activity

A database of electron temperature (T_e) measurements comprising of most of the available satellite measurements in the topside ionosphere is used for studying the solar activity variations of the electron temperature T_e at different latitudes, altitudes, local times and seasons. The T_e data are grouped into three levels of solar activity (low, medium, high) at four altitude ranges, for day and night, and for equinox and solstices. We find that in general T_e changes with solar activity are small and comparable in magnitude with seasonal changes but much smaller than the changes with altitude, latitude, and from day to night. In all cases, except at low altitude during daytime, T_e increases with increasing solar activity. But this increase is not linear as assumed in most empirical T_e models but requires at least a parabolic approximation. At 550 km during daytime negative as well as positive correlation is found with solar activity. Our global data base allows to quantify the latitude range and seasonal conditions for which these correlations occur. A negative correlation with solar activity is found in the invdip latitude range from 20 to 55 degrees during equinox and from 20 degrees onward during winter. In the low latitude (20 to −20 degrees invdip) F-region there is almost no change with solar activity during solstice and a positive correlation during equinox. A positive correlation is also observed during summer from 30 degrees onward.     

The global distribution and variability of stratospheric constituents measured by LIMS

The purpose of the Nimbus 7 LIMS experiment was to sound the composition and structure of the upper atmosphere and provide data for study of photochemistry, radiation, and dynamics processes. Vertical profiles were measured of temperature and ozone (O₃) over the 10-km to 65-km range and water vapor (H₂O), nitrogen dioxide (NO₂), and nitric acid (HNO₃) over the 10-km to ～50-km range. Latitude coverage extended from 64°S to 84°N. Several general features of the atmosphere have emerged from data analyses thus far. Nitrogen dioxide exhibits rapid latitudinal variations in winter and shows hemispheric asymmetry with generally higher vertical column amount in the summer hemisphere. HNO₃ data show that this gas is highly variable with altitude, latitude, and season. Smallest mixing ratios occur in the tropics, and the largest values occur in the high latitude winter hemisphere. The results show that O₃, NO₂, and HNO₃ are strongly affected during a stratospheric warming. There is a persistently low water vapor mixing ratio in the tropical lower stratosphere (～2–3 ppmv), a poleward gradient at all times in the mission, and evidence of increasing mixing ratio with altitude at tropical and middle latitudes.     

Impacts on Hubble Space Telescope solar arrays: Discrimination between natural and man-made particles

A Post-Flight Investigation was initiated by the European Space Agency to analyze impacts on solar arrays of the Hubble Space Telescope (HST), exposed to space for 8.25 years at approximately 600 km altitude. The solar cells deployed during the first Service Mission (SM-1 in December 1993) were retrieved in March 2002 as part of Service Mission 3B (SM-3B). A sub-panel of 2 m² was cut from the arrays for subsequent selection and removal of individual solar cells for analysis. Six cells (4.8 × 10⁻³ m²) were surveyed for flux of all craters of sizes greater than 5 microns. Analytical scanning electron microscopy was used to analyse residues in 111 features of 3–4000 micron conchoidal detachment diameter (D_co), examined on 23 solar cells. Eighty three show identifiable residue: 38 are Space Debris impacts and 45 Micrometeoroid impacts. Of the remaining 28, 2 contain residue of ambiguous origin, 1 is probably a minor manufacturing flaw, 1 is obscured by contamination, and 24 are unresolved, lacking recognizable residue.The majority of space debris impacts on the SM-3B cells are less than 80 microns D_co, dominated by Al-rich residue, probably of solid rocket motor origin, although three may be due to sodium metal droplet impacts. Three larger features include paint pigment and binder, ferrous alloy, and possible carbon-fibre composite material debris.Micrometeoroid residues are found across the entire crater size range and dominate features of between 100 and 1000 microns, their residues are similar to those found in earlier SM-1 surveys. Fe- and Mg-rich silicates dominate; Fe sulphides are common and there are occasional vesicular Ni- and S-bearing mafic silicates of hydrous phyllosilicate origin. A single sodium aluminosilicate residue and one Fe Ni metal residue were found; as well as enigmatic Mg- and S-bearing residues, all considered as probably of micrometeoroid origin. A few Fe-, O- and C-bearing residues were classified as of ambiguous origin.