Nickel Isotopic Composition and Nickel/Iron Ratio in the Solar Wind: Results from SOHO/CELIAS/MTOF

Using the Mass Time-of-Flight Spectrometer (MTOF)—part of the Charge, Elements, Isotope Analysis System (CELIAS)—onboard the Solar Heliospheric Observatory (SOHO) spacecraft, we derive the nickel isotopic composition for the isotopes with mass 58, 60 and 62 in the solar wind. In addition we measure the elemental abundance ratio of nickel to iron. We use data accumulated during ten years of SOHO operation to get sufficiently high counting statistics and compare periods of different solar wind velocities. We compare our values with the meteoritic ratios, which are believed to be a reliable reference for the solar system and also for the solar outer convective zone, since neither element is volatile and no isotopic fractionation is expected in meteorites. Meteoritic isotopic abundances agree with the terrestrial values and can thus be considered to be a reliable reference for the solar isotopic composition. The measurements show that the solar wind elemental Ni/Fe-ratio and the isotopic composition of solar wind nickel are consistent with the meteoritic values. This supports the concept that low-FIP elements are fed without relative fractionation into the solar wind. Our result also confirms the absence of substantial isotopic fractionation processes for medium and heavy ions acting in the solar wind.     

The Composition of the Solar Wind in Polar Coronal Holes

The solar wind charge state and elemental compositions have been measured with the Solar Wind Ion Composition Spectrometers (SWICS) on Ulysses and ACE for a combined period of about 25 years. This most extensive data set includes all varieties of solar wind flows and extends over more than one solar cycle. With SWICS the abundances of all charge states of He, C, N, O, Ne, Mg, Si, S, Ar and Fe can be reliably determined (when averaged over sufficiently long time periods) under any solar wind flow conditions. Here we report on results of our detailed analysis of the elemental composition and ionization states of the most unbiased solar wind from the polar coronal holes during solar minimum in 1994–1996, which includes new values for the abundance S, Ca and Ar and a more accurate determination of the ²⁰Ne abundance. We find that in the solar minimum polar coronal hole solar wind the average freezing-in temperature is ∼1.1×10⁶ K, increasing slightly with the mass of the ion. Using an extrapolation method we derive photospheric abundances from solar wind composition measurements. We suggest that our solar-wind-derived values should be used for the photospheric ratios of Ne/Fe=1.26±0.28 and Ar/Fe=0.030±0.007.     

Solar Elemental Composition Based on Studies of Solar Energetic Particles

Solar abundances can be derived from the composition of the solar wind and solar energetic particles (SEPs) as well as obtained through spectroscopic means. Past comparisons have suggested that all three samples agree well, when rigidity-related fractionation effects on the SEPs were accounted for. It has been known that such effects vary from one event to the next and should be addressed on an event-by-event basis. This paper examines event variability more closely, particularly in terms of energy-dependent SEP abundances. This is now possible using detailed SEP measurements spanning several decades in energy from the Ultra Low Energy Isotope Spectrometer (ULEIS) and the Solar Isotope Spectrometer (SIS) on the ACE spacecraft. We present examples of the variability of the elemental composition with energy and suggest they can be understood in terms of diffusion from the acceleration region near the interplanetary shock. By means of a spectral scaling procedure, we obtain energy-independent abundance ratios for 14 large SEP events and compare them to reported solar wind and coronal abundances as well as to previous surveys of SEP events.     

Standard Solar Composition

We review the current status of our knowledge of the chemical composition of the Sun, essentially derived from the analysis of the solar photospheric spectrum. The comparison of solar and meteoritic abundances confirms that there is a very good agreement between the two sets of abundances. They are used to construct a Standard Abundance Distribution. This revised version was published online in June 2006 with corrections to the Cover Date.     

Pickup Ions and Cosmic Rays from Dust in the Heliosphere

The combination of recent observational and theoretical work has completed the catalog of the sources of heliospheric Pickup Ions (PUIs). These PUIs are the seed population for Anomalous Cosmic Rays (ACRs), which are accelerated to high energies at or beyond the Termination Shock (TS). For elements with high First Ionization Potentials (high-FIP atoms: e.g., H, He, Ne, etc.), the dominant source of PUIs and ACRs is from neutral atoms that drift into the heliosphere from the Local Interstellar Medium (LISM) and, prior to ionization, are influenced primarily by solar gravitation and radiation pressure (for H). After ionization, these interstellar ions are pickup up by the solar wind, swept out, and are either accelerated near the TS or beyond it. Elements with low first ionization potentials (low-FIP atoms: e.g., C, Si, Mg, Fe, etc.) are also observed as PUIs by Ulysses and as ACRs by Wind and Voyager. But the low-FIP composition of this additional component reveals a very different origin. Low-FIP interstellar atoms are predominantly ionized in the LISM and therefore excluded from the heliosphere by the solar wind. Remarkably, a low-FIP component of PUIs was hypothesized by Banks (J. Geophys. Res. 76, 4341, 1971) over twenty years prior to its direct detection by Ulysses/SWICS (Geiss et al., J. Geophys. Res. 100(23), 373, 1995) The leading concept for the generation of Inner Source PUIs involves an effective recycling of solar wind on grains near the Sun, as originally suggested by Banks. Voyager and Wind also observe low-FIP ACRs, and a grain-related source appears likely and necessary. Two concepts have been proposed to explain these low-FIP ACRs: the first concept involves the acceleration of the Inner Source of PUIs, and the second involves a so-called Outer Source of PUIs generated from solar wind interaction with the large population of grains in the Kuiper Belt. We review here the observational and theoretical work over the last decade that shows how solar wind and heliospheric grains interact to produce pickup ions, and, in turn, anomalous cosmic rays. The inner and outer sources of pickup ions and anomalous cosmic rays exemplify dusty plasma interactions that are fundamental throughout the cosmos for the production of energetic particles and the formation of stellar systems.     

Solar Isotopic Composition as Determined Using Solar Energetic Particles

Solar energetic particles (SEPs) provide a sample of the Sun from which solar composition may be determined. Using high-resolution measurements from the Solar Isotope Spectrometer (SIS) onboard NASA’s Advanced Composition Explorer (ACE) spacecraft, we have studied the isotopic composition of SEPs at energies ≥20 MeV/nucleon in large SEP events. We present SEP isotope measurements of C, O, Ne, Mg, Si, S, Ar, Ca, Fe, and Ni made in 49 large events from late 1997 to the present. The isotopic composition is highly variable from one SEP event to another due to variations in seed particle composition or due to mass fractionation that occurs during the acceleration and/or transport of these particles. We show that various isotopic and elemental enhancements are correlated with each other, discuss the empirical corrections used to account for the compositional variability, and obtain estimated solar isotopic abundances. We compare the solar values and their uncertainties inferred from SEPs with solar wind and other solar system abundances and find generally good agreement.     

The Seed Population for Energetic Particles Accelerated by CME-Driven Shocks

Understanding properties of solar energetic particle (SEP) events associated with coronal mass ejections has been identified as a key problem in solar-terrestrial physics. Although recent CME shock acceleration models are highly promising, detailed agreement between theoretical predictions and observations has remained elusive. Recent observations from ACE have shown substantial enrichments in the abundances of ³He and He⁺ ions which are extremely rare in the thermal solar wind plasma. Consequently, these ions act as tracers of their source material, i.e., ³He ions are flare suprathermals and He⁺ ions are interstellar pickup ions. The average heavy ion composition also exhibits unsystematic differences when compared with the solar wind values, but correlates significantly with the ambient suprathermal material abundances. Taken together these results provide compelling evidence that CME-driven shocks draw their source material from the ubiquitous but largely unexplored suprathermal tail rather than from the more abundant solar wind peak. However, the suprathermal energy regime has many more contributors and exhibits much larger variability than the solar wind, and as such needs to be investigated more thoroughly. Answers to fundamental new questions regarding the preferred injection of the suprathermal ions, the spatial and temporal dependence of the various sources, and the causes of their variability and their effects on the SEP properties are needed to improve agreement between the simulations and observations.     

Elemental Abundances of the Bulk Solar Wind: Analyses from Genesis and ACE

Analysis of the Genesis samples is underway. Preliminary elemental abundances based on Genesis sample analyses are in good agreement with in situ-measured elemental abundances made by ACE/SWICS during the Genesis collection period. Comparison of these abundances with those of earlier solar cycles indicates that the solar wind composition is relatively stable between cycles for a given type of flow. ACE/SWICS measurements for the Genesis collection period also show a continuum in compositional variation as a function of velocity for the quasi-stationary flow that defies the simple binning of samples into their sources of coronal hole (CH) and interstream (IS).     

Evidence for a Two-Stage Acceleration Process in Large Solar Energetic Particle Events

Using high-resolution mass spectrometers on board the Advanced Composition Explorer (ACE), we surveyed the event-averaged ∼0.1–60 MeV/nuc heavy ion elemental composition in 64 large solar energetic particle (LSEP) events of cycle 23. Our results show the following: (1) The Fe/O ratio decreases with increasing energy up to ∼10 MeV/nuc in ∼92% of the events and up to ∼60 MeV/nuc in ∼64% of the events. (2) The rare isotope ³He is greatly enhanced over the corona or the solar wind values in 46% of the events. (3) The heavy ion abundances are not systematically organized by the ion’s M/Q ratio when compared with the solar wind values. (4) Heavy ion abundances from C–Fe exhibit systematic M/Q-dependent enhancements that are remarkably similar to those seen in ³He-rich SEP events and CME-driven interplanetary (IP) shock events. Taken together, these results confirm the role of shocks in energizing particles up to ∼60 MeV/nuc in the majority of large SEP events of cycle 23, but also show that the seed population is not dominated by ions originating from the ambient corona or the thermal solar wind, as previously believed. Rather, it appears that the source material for CME-associated large SEP events originates predominantly from a suprathermal population with a heavy ion enrichment pattern that is organized according to the ion’s mass-per-charge ratio. These new results indicate that current LSEP models must include the routine production of this dynamic suprathermal seed population as a critical pre-cursor to the CME shock acceleration process.     

FIP Effect in the Solar Upper Atmosphere: Spectroscopic Results

Recent spectroscopic measurements from instruments on the Solar and Heliospheric Observatory (SOHO) find that the coronal composition above a polar coronal hole is nearly photospheric. However, similar SOHO observations show that in coronal plasmas above quiet equatorial regions low-FIP elements are enhanced by a factor of ≈ 4. In addition, the process of elemental settling in coronal plasmas high above the solar surface was shown to exist. Measurements by the Ulysses spacecraft, which are based on non-spectroscopic particle counting techniques, show that, with the exception of He, the elemental composition of the fast speed solar wind is similar to within a factor of 1.5 to the composition of the photosphere. In contrast, similar measurements in the slow speed wind show that elements with low first ionization potential (FIP < 10 eV) are enhanced, relative to the photosphere, by a factor of 4-5. By combining the SOHO and Ulysses results, ideas related to the origin of the slow speed solar wind are presented. Using spectroscopic measurements by the Solar Ultraviolet Measurement of Emitted Radiation (SUMER) instrument on SOHO the photospheric abundance of He was determined as 8.5 ± 1.3% (Y = 0.248). This revised version was published online in June 2006 with corrections to the Cover Date.     

Composition and Opacity in the Solar Interior

Detailed abundances of elements from hydrogen up to iron are necessary to perform a precise model of the solar structure. Most of them have been deduced from photospheric observed values, some others from the meteoritic composition. Nowadays, thanks to helioseismic constraints, they seem more and more under control. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Expansion of Coronal Plumes in the Fast Solar Wind

Coronal plumes are believed to be essentially magnetic features: they are rooted in magnetic flux concentrations at the photosphere and are observed to extend nearly radially above coronal holes out to at least 15 solar radii, probably tracing the open field lines. The formation of plumes itself seems to be due to the presence of reconnecting magnetic field lines and this is probably the cause of the observed extremely low values of the Ne/Mg abundance ratio. In the inner corona, where the magnetic force is dominant, steady MHD models of coronal plumes deal essentially with quasi-potential magnetic fields but further out, where the gas pressure starts to be important, total pressure balance across the boundary of these dense structures must be considered. In this paper, the expansion of plumes into the fast polar wind is studied by using a thin flux tube model with two interacting components, plume and interplume. Preliminary results are compared with both remote sensing and solar wind in situ observations and the possible connection between coronal plumes with pressure-balance structures (PBS) and microstreams is discussed. This revised version was published online in June 2006 with corrections to the Cover Date.     

Element Settling in the Solar Interior

Element settling inside the Sun now becomes detectable from the comparison of the observed oscillation modes with the results of the theoretical models. This settling is due, not only to gravitation, but also to thermal diffusion and radiative acceleration (although this last effect is small compared to the two others). It leads to abundance variations of helium and heavy elements of ≅ 10% below the convective zone. Although not observable from spectroscopy, such variations lead to non-negligible modifications of the solar internal structure and evolution. Helioseismology is a powerful tool to detect such effects, and its positive results represent a great success for the theory of stellar evolution. Meanwhile, evidences are obtained that the element settling is slightly smoothed down, probably due to mild macroscopic motions below the convective zone. Additional observations of the abundances of both 7Li and 3He lead to specific constraints on these particular motions. This revised version was published online in June 2006 with corrections to the Cover Date.     

An Update on Ultra-Heavy Elements in Solar Energetic Particles above 10 MeV/Nucleon

Measurements below several MeV/nucleon from Wind/LEMT and ACE/ULEIS show that elements heavier than Zn (Z=30) can be enhanced by factors of ∼100 to 1000, depending on species, in ³He-rich solar energetic particle (SEP) events. Using the Solar Isotope Spectrometer (SIS) on ACE we find that even large SEP (LSEP) shock-accelerated events at energies from ∼10 to >100 MeV/nucleon are often very iron rich and might contain admixtures of flare seed material. Studies of ultra-heavy (UH) SEPs (with Z>30) above 10 MeV/nucleon can be used to test models of acceleration and abundance enhancements in both LSEP and ³He-rich events. We find that the long-term average composition for elements from Z=30 to 40 is similar to standard solar system values, but there is considerable event-to-event variability. Although most of the UH fluence arrives during LSEP events, UH abundances are relatively more enhanced in ³He-rich events, with the (34<Z<40)/O ratio on average more than 50 times higher in ³He-rich events than in LSEP events. At energies >10 MeV/nucleon, the most extreme event in terms of UH composition detected so far took place on 23 July 2004 and had a (34<Z<40)/O enhancement of ∼250–300 times the standard solar value.     

A cosmochemical view of cosmic rays and solar particles

The composition of cosmic rays and solar particles is reviewed with emphasis on the question of whether they are representative samples of Galactic and solar matter. The composition of solar particles changes with energy and from flare to flare. A strong excess of heavy elements at energies below a few MeV/nuc decreases with energy, and at energies above 15 MeV/nuc the composition of solar particles resembles that of galactic cosmic rays somewhat better than that of the solar atmosphere. The elements Ne through Pb have remarkably similar abundances in cosmic ray sources and in the matter of the solar system. The lighter elements are depleted in cosmic rays, whereas U and Th may be enriched or not, depending on whether the meteoritic or solar abundance of Th is used. Two prototype sources of cosmic rays are considered: gas with solar system composition but enriched in elements with Z > 8 during acceleration and emission (by analogy with solar particle emission), and highly evolved matter enriched in r-process elements such as U, Th and transuranic elements. The energy-dependence of cosmic ray composition suggests that both sources may contribute at different energies.Miller Institute Professor, 1972–73.     

Composition Variations in the Solar Corona and Solar Wind

Order of magnitude variations in relative elemental abundances are observed in the solar corona and solar wind. The instruments aboard SOHO make it possible to explore these variations in detail to determine whether they arise near the solar surface or higher in the corona. A substantial enhancement of low First Ionization Potential (FIP) elements relative to high FIP elements is often seen in both the corona and the solar wind, and that must arise in the chromosphere. Several theoretical models have been put forward to account for the FIP effect, but as yet even the basic physical mechanism responsible remains an open question. Evidence for gravitational settling is also found at larger heights in quiescent streamers. The question is why the heavier elements don't settle out completely. This revised version was published online in June 2006 with corrections to the Cover Date.     

Elemental Abundances in Coronal Structures

A great deal of evidence for elemental abundance variations among different structures in the solar corona has accumulated over the years. Many of the observations show changes in the relative abundances of high- and low-First Ionization Potential elements, but relatively few show the absolute elemental abundances. Recent observations from the SOHO satellite give absolute abundances in coronal streamers. Along the streamer edges, and at low heights in the streamer, they show roughly photospheric abundances for the low-FIP elements, and a factor of 3 depletion of high-FIP elements. In the streamer core at 1.5 R·, both high- and low-FIP elements are depleted by an additional factor of 3, which appears to result from gravitational settling. This revised version was published online in June 2006 with corrections to the Cover Date.     

Johannes Geiss’ Investigations of Solar, Heliospheric and Interstellar Matter

Johannes Geiss is a world leader and foremost expert on measurements and interpretation of the composition of matter that reveals the history, present state, and future of astronomical objects. With his Swiss team he was first to measure the composition of the noble gases in the solar wind when in the late 1960s he flew the brilliant solar wind collecting foil experiments on the five Apollo missions to the moon. Always at the forefront of the art of composition measurements, he with his colleagues determined the isotopic and elemental composition of the solar wind using instruments characterized by innovative design that have provided the most comprehensive record of the solar wind composition under all solar wind conditions at all helio-latitudes. He discovered heavy interstellar pickup ions, from which the composition of the neutral gas of the Local Interstellar Cloud is determined, and the “Inner Source” of pickup ions. Johannes Geiss played a key role both in the in-situ measurements and modeling of molecular ions in comets, and the interpretation of these data. He and co-workers measured the composition of plasmas in the magnetospheres of Earth and Jupiter. Here we highlight Johannes Geiss’ many discoveries and seminal contributions to our knowledge of the composition of matter of the Sun, solar wind, interstellar gas, early universe, comets and magnetospheres.     

Abundances,Ionization States,Temperatures, and FIP in Solar Energetic Particles

The relative abundances of chemical elements and isotopes have been our most effective tool in identifying and understanding the physical processes that control populations of energetic particles. The early surprise in solar energetic particles (SEPs) was 1000-fold enhancements in \({}^{3}\mbox{He}/{}^{4}\mbox{He}\) from resonant wave-particle interactions in the small “impulsive” SEP events that emit electron beams that produce type III radio bursts. Further studies found enhancements in Fe/O, then extreme enhancements in element abundances that increase with mass-to-charge ratio \(A/Q\), rising by a factor of 1000 from He to Au or Pb arising in magnetic reconnection regions on open field lines in solar jets. In contrast, in the largest SEP events, the “gradual” events, acceleration occurs at shock waves driven out from the Sun by fast, wide coronal mass ejections (CMEs). Averaging many events provides a measure of solar coronal abundances, but \(A/Q\)-dependent scattering during transport causes variations with time; thus if Fe scatters less than O, Fe/O is enhanced early and depleted later. To complicate matters, shock waves often reaccelerate impulsive suprathermal ions left over or trapped above active regions that have spawned many impulsive events. Direct measurements of ionization states \(Q\) show coronal temperatures of 1–2 MK for most gradual events, but impulsive events often show stripping by matter traversal after acceleration. Direct measurements of \(Q\) are difficult and often unavailable. Since both impulsive and gradual SEP events have abundance enhancements that vary as powers of \(A/Q\), we can use abundances to deduce the probable \(Q\)-values and the source plasma temperatures during acceleration, ≈3 MK for impulsive SEPs. This new technique also allows multiple spacecraft to measure temperature variations across the face of a shock wave, measurements otherwise unavailable and provides a new understanding of abundance variations in the element He. Comparing coronal abundances from SEPs and from the slow solar wind as a function of the first ionization potential (FIP) of the elements, remaining differences are for the elements C, P, and S. The theory of the fractionation of ions by Alfvén waves shows that C, P, and S are suppressed because of wave resonances during chromospheric transport on closed magnetic loops but not on open magnetic fields that supply the solar wind. Shock waves can accelerate ions from closed coronal loops that easily escape as SEPs, while the solar wind must emerge on open fields.     

Element Separation in the Chromosphere Ionization-Diffusion Models for the FIP-Effect

Ionization-diffusion mechanisms to understand the first ionization potential (FIP) fractionation as observed in the solar corona and the solar wind are reviewed. The enrichment of the low-FIP elements (<10 eV) compared to the high-FIP elements, seen in e.g. slow and fast wind or polar plumes, is explained. The behaviour of the heavy noble gases becomes understandable. The absolute fractionation, i.e. in relation to hydrogen, can be calculated and fits well to the measurements. The theoretical velocity-dependence of the fractionation will with used to determine the velocities of the solar wind in the chromosphere. This revised version was published online in June 2006 with corrections to the Cover Date.