Investigation on a Sol-gel Coating Containing Inhibitors on 2024-T3 Aluminum Alloy |
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引用本文: | SHI Hong-wei LIU Fu-chun HAN En-hou SUN Ming-cheng. Investigation on a Sol-gel Coating Containing Inhibitors on 2024-T3 Aluminum Alloy[J]. 中国航空学报, 2006, 19(B12): 106-112 |
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作者姓名: | SHI Hong-wei LIU Fu-chun HAN En-hou SUN Ming-cheng |
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作者单位: | Environmental Corrosion Center, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China |
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基金项目: | National Natural Science Fundation of China (50499334) |
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摘 要: | For a long time, chromate incorporated conversion coatings have been drawn special attention in corrosion protection of aircraft-used aluminum alloys. However, ever-increasing environmental pressures requires that non-chromate conversion coatings be developed because of the detrimental carcinogenic effects of the chromate compounds. In recent years, the sol-gel coatings doped with inhibitors were developed to replace chromate conversion coatings, and showed real promise; A sol-gel coating was prepared and its anti-corrosion behavior was investigated using the potentiodynamic scanning (PDS) and the electrochemical impedance spectroscopy (EIS). It is found that the sol-gel coating obtained by the hydrolysis and condensation of 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetramethoxysilane (TMOS) is prone to form defects if cured at the room temperature, whereas if cured at a higher temperature (100℃), these flaws can be avoided. Furthermore, it can be seen that addition of anti-foam agents and surfactants will reduce the faults if cured at the room temperature. Effects of the corrosion inhibitors, CeCl3 and mercaptobenzothiazole (MBT), in the sol-gel coatings on 2024-T3 aluminum alloy were also investigated. Results show that the corrosion resistance of the sol-gel coatings containing CeCl3 proves to be better than that of the pure and MBT added sol-gel coatings by the electrochemical methods.
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关 键 词: | 2024-T3 铝合金 溶胶-凝胶法涂层 抑制剂 腐蚀防护 |
收稿时间: | 2006-08-10 |
修稿时间: | 2006-11-06 |
Investigation on a Sol-gel Coating Containing Inhibitors on 2024-T3 Aluminum Alloy |
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