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石墨纤维/改性氰酸酯复合材料的应用研究
引用本文:林大庆%黎昱%董艺.石墨纤维/改性氰酸酯复合材料的应用研究[J].宇航材料工艺,2008,38(5).
作者姓名:林大庆%黎昱%董艺
作者单位:北京卫星制造厂,北京,100190
摘    要:采用环氧树脂对4,4-二氰酸酯基二苯基丙烷(BADCy)进行共聚改性,通过DSC分析,确定了固化工艺参数,并与石墨纤维(UHMCF)复合制成单向板,测试了不同后处理温度制得的单向板力学性能,并与现用UHMCF/树脂基复合材料单向板的力学性能进行了比较,测试了UHMCF/改性氰酸酯的空间环境性能;制备了UHMCF/改性氰酸酯结构件,测试其性能,并与现用UHMCF/树脂基复合材料同类结构件的性能进行了比较。结果表明:UHMCF/改性氰酸酯不论是单向板还是结构件的性能均优于现用UHMCF/树脂基复合材料的性能,且满足空间环境对航天器结构材料性能的要求。

关 键 词:共聚改性  石墨纤维  氰酸酯  后处理  单向层合板  结构件  力学性能  空间环境

Application of UHMCF/Modified Cyanate Composites
Lin Daqing,Li Yu,Dong Yi.Application of UHMCF/Modified Cyanate Composites[J].Aerospace Materials & Technology,2008,38(5).
Authors:Lin Daqing  Li Yu  Dong Yi
Abstract:In this paper the cure parameter of a certain BADCy co-polymerized with epoxy resin was confirmed by DSC. And the mechanical characteristics of UHMCF carbon fiber reinforced BADCy matrix unidirectional laminates manufactured in different post-cured temperatures were measured and compared with the UHMCF/resin unidirectional laminates which was used widely. Also the experimental results of the space environmental characteristics of UHMCF/modified cyanate was expressed. Structures of UHMCF/modified cyanate were produced and their properties were measured and the results were compared with the characteristics of the normal UHMCF/resin structure.The results show that the characteristics of both UHMCF/modified cyanate unidirectional laminates and structures are better than those of normal UHMCF/resin and the UHMCF/modified cyanate, as a new kind of spacecraft structure material, is adaptable to the requests of space environment.
Keywords:Copolymerization  Graphite fiber  Cyanate ester  Post-Cured  Unidirectional laminate  Structure performance  Mechanical properties  Space environment
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