Modeling of effect of polarization on UV sky radiance during twilight

The spatial distribution of the vector of the Stokes parameters characterizing the radiance intensity and the radiance polarization describes the radiation field in the atmosphere. A simplified treatment of light as the scalar has only restricted application. A few studies compared previously results of the vector and scalar radiative transfer models and showed that scalar models are in error by up to 10% for many cases. Though several observational conditions were exploited, an effect of polarization on modeling of UV radiance has not been investigated yet for twilight. The paper presents a preliminary study of modeled UV radiance during twilight taking into account polarization. The intensity and the degree of linear polarization of the scattered UV radiance for two cases of the ground-based observations are discussed. In the first case, radiation incoming from the zenith for the solar zenith angles (SZA) from 90° to 98° is under investigation. Radiation in the solar principal plane for the beginning of twilight (SZA = 90.1°) was calculated in the second case. The study showed that the UV radiation field in the twilight atmosphere can be handled correctly only using the vector theory. The errors of scalar radiative transfer strongly depend on wavelength, line of an observation and solar position. The revealed distortion of the zenith radiance caused by using of the scalar approximation reaches maximum of 15% at 340 nm for the solar zenith angle (SZA) equal to 98°. The shorter wavelengths have the smaller errors, about 5% at 305 nm for SZA = 98°, due to the larger part of the single scattered radiance. The error of the scalar modeling may be as large as ?17% for radiance incoming from the horizon for SZA = 90.1°. Scalar radiative transfer models underestimate the integral intensity in the principal plane up to 3–4% ± 0.5% at SZA = 90.1° for wavelengths from 320 to 340 nm. This should be taken into account in problems of radiative budget estimation and remote sensing of the atmosphere exploiting the twilight period.