Gravity wave mixing effects on the OH*-layer

Based on an advanced numerical model for excited hydroxyl (OH*) we simulate the effects of gravity waves (GWs) on the OH*-layer in the upper mesosphere. The OH* model takes into account (1) production by the reaction of atomic hydrogen (H) with ozone (O₃), (2) deactivation by atomic oxygen (O), molecular oxygen (O₂), and molecular nitrogen (N₂), (3) spontaneous emission, and (4) loss due to chemical reaction with O. This OH* model is part of a chemistry-transport model (CTM) which is driven by the high-resolution dynamics from the KMCM (Kühlungsborn Mechanistic general Circulation Model) which simulates mid-frequency GWs and their effects on the mean flow in the MLT explicitly. We find that the maximum number density and the height of the OH*-layer peak are strongly determined by the distribution of atomic oxygen and by the temperature. As a results, there are two ways how GWs influence the OH*-layer: (1) through the instantaneous modulation by O and T on short time scales (a few hours), and (2) through vertical mixing of O (days to weeks). The instantaneous variations of the OH*-layer peak altitude due to GWs amount to 5–10 km. Such variations would introduce significant biases in the GW parameters derived from airglow when assuming a constant pressure level of the emission height. Performing a sensitivity experiment we find that on average, the vertical mixing by GWs moves the OH*-layer down by ~2 to 7 km and increases its number density by more than 50%. This effect is strongest at middle and high latitudes during winter where secondary GWs generated in the stratopause region account for large GW amplitudes.