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含燃速催化剂的丁羟推进剂高压燃烧性能研究
引用本文:徐浩星,鲁国林,赵秀媛. 含燃速催化剂的丁羟推进剂高压燃烧性能研究[J]. 推进技术, 1999, 20(3): 81-85
作者姓名:徐浩星  鲁国林  赵秀媛
作者单位:湖北红星化学研究所,襄樊,441003
摘    要:对含T27(一种二茂铁衍生物)、卡托辛、Fe2O3三种燃速催化剂的HTPB/AP/Al推进剂在16MPa~22MPa下的燃速和燃速压强指数进行了研究。结果表明:二茂铁衍生物能大幅度提高HTPB/AP/Al推进剂的燃速,同时可使高压下的压强指数大幅度地下降;Fe2O3对HTPB/AP/Al推进剂有着显著的燃速催化效果,但其推进剂压强指数较高;Fe2O3的催化效率较T27高,但不及卡托辛;Fe2O3和二茂铁衍生物组合使用能进一步提高HTPB/AP/Al推进剂的燃速,并使推进剂具有较低的压强指数。

关 键 词:端羟基聚丁二烯,燃烧性能,推进剂燃速,燃速调节剂

COMBUSTION PROPERTIES OF HTPB PROPELLANTS WITH BURNING RATE CATALYSTS AT HIGH PRESSURE
Xu Haoxing,Lu Guolin and Zhao Xiuyuan. COMBUSTION PROPERTIES OF HTPB PROPELLANTS WITH BURNING RATE CATALYSTS AT HIGH PRESSURE[J]. Journal of Propulsion Technology, 1999, 20(3): 81-85
Authors:Xu Haoxing  Lu Guolin  Zhao Xiuyuan
Affiliation:Guo Shufen jia Bo(Dept.of Jet Propulsion,Beijing Univ.of Aeronautics and Astronautics,Beijing,100083;Guo Shufen jia Bo(Dept.of Jet Propulsion,Beijing Univ.of Aeronautics and Astronautics,Beijing,100083;Guo Shufen jia Bo(Dept.of Jet Propulsion,Beijing Univ.of Aeronautics and Astronautics,Beijing,100083
Abstract:An experimental investigation on the burning rates and pressure exponents of HTPB propellants with burning rate catalysts T 27 (ferrocenyl derivative),Catocene,Fe 2O 3 is carried out at high pressure in the range from 16 to 22 MPa.The results show that ferrocenyl derivatives can increase the burning rates of HTPB/AP/Al propellants and decrease their pressure exponents greatly.Fe 2O 3 has an obvious effect on the burning rates of HTPB/AP/Al popellants,but the pressure exponents are very high.The catalytic efficiency of Fe 2O 3 is higher than that of T 27 ,but lower than that of Catocene.Adding Fe 2O 3 and ferrocenyl derivative together in the propellant can increase the burning rate further and at the same time the pressure exponent is low.
Keywords:Hydroxy terminated polybutadiene propellant  Combustion performance  Propellant burning rate  Burning rate modifior
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