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Comparative Study on Super Fine Mesophase Powder and MCMB Used to Manufacture High-Density Isotropic Carbon Bulks
作者姓名:LI  Tong-qi  HU  Zi-jun  WANG  Jun-shan  GUO  Yu-ming  WANG  Cheng-yang
作者单位:[1]National Key Laboratory of Advanced Functional Composite Materials, Aerospace Research Institute of Materials and Processing Technology, Beijing 100076, China [2]Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072,China
摘    要:Mesocarbon microbeads (MCMB) and super fine mesophase powder (SFMP) were prepared firstly from a coal tar pitch and then hot-condensed into high-density isotropic carbon (HDIC) bulks under 160 MPa and finally sintered at 1 000 ℃. By analyzing the thermogravimetric behavior of the MCMB and SFMP powders, their volume shrinkage and weight loss during sintering and the bulk density and flexural strengths of their sintered bulks, it was found that the smaller sizes and the richer β-resin contents of SFMP ha)re facilitated formation of sintered bulks with more compact isotropic structure and higher flexural strengths than MCMB. Because of the filling and bonding effects of SFMP on MCMB bulks, addition of SFMP, albeit a little, can greatly increase the flexural strengths of sintered bulks of MCMB. However, adding MCMB, even a slight amount, into SFMP can severely impair the flexural strength of sintered bulks. This might be attributed to both the crack initiation along the boundaries between MCMB and SFMP and the formation of layered texture of MCMB sphere.

关 键 词:超细中间相粉末  MCMB  高密度各向同性碳块  制造  比较研究
收稿时间:2006-08-10
修稿时间:2006-11-06

Comparative Study on Super Fine Mesophase Powder and MCMB Used to Manufacture High-Density Isotropic Carbon Bulks
LI Tong-qi HU Zi-jun WANG Jun-shan GUO Yu-ming WANG Cheng-yang.Comparative Study on Super Fine Mesophase Powder and MCMB Used to Manufacture High-Density Isotropic Carbon Bulks[J].Chinese Journal of Aeronautics,2006,19(B12):187-191.
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