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天宫二号碲化锌晶体生长
引用本文:陆液,王仍,杜云辰,焦翠灵,李向阳.天宫二号碲化锌晶体生长[J].空间科学学报,2018,38(2):234-238.
作者姓名:陆液  王仍  杜云辰  焦翠灵  李向阳
作者单位:中国科学院上海技术物理研究所 红外成像材料与器件重点实验室 上海 200083
基金项目:中国载人空间站工程项目(TGJZ800-2-RW024),上海市自然科学基金项目(16ZR1441300),中国科学院上海技术物理研究所创新专项项目(Sciences CX-132)和中国科学院实验室创新基金项目(CXJJ-17S066)共同资助
摘    要:在天宫二号飞船综合材料实验炉六工位采用碲熔剂法生长了碲化锌晶体,生长时最高温度为800℃,以0.5mm·h-1的提拉速度向炉膛内部提拉生长晶体.飞行实验后,用相同实验参数在地面进行了对比实验.结果发现,空间样品尾部有一个非常大的橙色结晶区域(约10mm×6mm×2mm),而地面生长样品中碲化锌晶体尺寸仅为约3mm×3mm×1mm,空间生长的碲化锌晶粒尺寸明显优于地面.空间微重力环境下,由于毛细作用,空间样品的塞子处有Te和ZnTe的外延膜生成.而地面生长的锭条在塞子处只有零星点状气相生产物.因此微重力条件有利于碲化锌晶体材料的生长.

关 键 词:碲化锌    微重力    天宫二号    碲熔剂法
收稿时间:2017-08-22
修稿时间:2018-01-11

Growth of ZnTe Crystal in Microgravity on Tiangong-2 Spaceshipormalsize
LU Ye,WANG Reng,DU Yunchen,JIAO Cuiling,LI Xiangyang.Growth of ZnTe Crystal in Microgravity on Tiangong-2 Spaceshipormalsize[J].Chinese Journal of Space Science,2018,38(2):234-238.
Authors:LU Ye  WANG Reng  DU Yunchen  JIAO Cuiling  LI Xiangyang
Institution:Key Laboratory of Infrared Imaging Materials and Detectors, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083
Abstract:Zinc telluride crystal was grown by Te-solvent method in microgravity on Tiangong-2 spaceship in 2016. The growth temperature is 800℃, and the growth rate is 0.5mm·h-1. A ground-truth experiment was performed following the space experiment, and a comparison between the two samples was studied. An orange ZnTe crystal (its size is about 10mm×6mm×2mm) can be found in the space sample. It is shown that the crystal size of space sample is larger than that of the ground sample. Because of the capillary phenomenon in microgravity, Te and ZnTe film were grown at the surface of the silicon rod of the space sample. However, a little bit of gaseous product was found at the ground sample. This result underlines the importance of microgravity for crystal growth of Group Ⅱ~VI semiconductor material. It gives the positive guidance on the growth of infrared semiconductor materials on ground such as HgCdTe, CdZnTe and ZnTe. 
Keywords:Zinc telluride  Microgravity  Tiangong-2 spaceship  Te-solvent method
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