Primordial matter in the outer solar system: A study of its chemical composition from remote spectroscopic analysis

Our knowledge of the primordial matter from the objects of the outer solar system has made a considerable progress over the past years, in spite of the lack of any in situ measurements of these objects at the present time. The recent progress of ground-based instrumentation and the launch of the two Voyager fly-by missions have provided a huge amount of new informations about the origin and the evolution of the primitive Solar System objects.The most significant discoveries concerning the atmospheres of the Giant Planets can be summarized as follows: (1) there does not seem to be any differentiation in the internal structure of Jupiter during the planet's history; thus, the H₂/He ratio measured on Jupiter seems to be representative of the H/He ratio of the Primordial Nebula; (2) there is some evidence for a helium differentiation, relative to hydrogen, in Saturn's interior; (3) there seems to be a carbon enrichment on both Jupiter and Saturn by a factor about 2; this result is consistent with a model in which the planetary core is formed first, and the atmosphere accreted by this core in a second stage; (4) the D/H ratio measured on Jupiter should be representative of the D/H value in the Primordial Nebula, 4.5 billion years ago; this value is 2 to 5 times larger than the mean value measured in the local interstellar medium now; (5) Titan's atmosphere is dominated by nitrogen and contains traces of organic and prebiotic molecules (HCN, C₂N₂, HC₃N); the chemical composition of Titan's atmosphere could be favorable for the early stages of life development.The small bodies of the Solar System — asteroïds and comets — are still very poorly known. However they contain a key information about the physical and chemical properties of dust in the Primordial Nebula and the interstellar medium. With the launch of expected fly-by missions towards Comet Halley and, possibly, towards asteroïds, we may hope to know a new development of our understanding of these objects, comparable to the progress we have known on the Giant Planets over the past ten years.