Plasma kinetics in the solar wind

An account is given of the observations and theoretical ideas concerning the role of kinetic processes in the solar wind. This includes, first of all, the measurements on distribution functions of plasma electrons and protons, the relation of the observed non-thermal electron features with the concept of an exospheric expansion of the solar corona, and the connection of non-thermal proton distributions with bulk flow inhomogeneities of the wind. A discussion is given of the present understanding of the connection between observed features of the particle distributions and anomalous values of some plasma transport coefficients, which in turn determine the actual values of macroscopic plasma parameters.A further topic of the review is that of possible kinetic processes occurring within small scale structures in the solar wind, like collisionless shocks, various types of discontinuities and D-sheets.