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四唑类盐的制备及其在固体推进剂中的应用初探
引用本文:邓敏智,杜恒,赵凤起,罗阳,袁潮.四唑类盐的制备及其在固体推进剂中的应用初探[J].固体火箭技术,2003,26(3):53-54,57.
作者姓名:邓敏智  杜恒  赵凤起  罗阳  袁潮
作者单位:1. 中国科学院上海有机化学研究所,上海,200032
2. 西安近代化学研究所,西安,710065
摘    要:合成了5-苯基四唑、5-亚甲基二四唑,并通过元素分析及质谱方法对其进行了分析鉴定,制备了其铜、铅、锶盐;对3种金属盐在改性双基推进剂配方中的应用进行了探索性研究。初步研究表明,四唑类的金属盐类可以作为复合改性双基推进剂(CMDB)的含能燃烧催化剂。

关 键 词:固体推进剂  配方  燃烧催化剂  5-苯基四唑  5-亚甲基二四唑  质谱  制备
文章编号:1006-2793(2003)03-0053-02

Study on the synthesis of tetrazales salts and their application in solid propellant
DENG Min-zhi,DU Heng,ZHAO Feng-qi,LUO Yang,YUAN Chao//.Study on the synthesis of tetrazales salts and their application in solid propellant[J].Journal of Solid Rocket Technology,2003,26(3):53-54,57.
Authors:DENG Min-zhi  DU Heng  ZHAO Feng-qi  LUO Yang  YUAN Chao//
Institution:DENG Min-zhi,DU Heng,ZHAO Feng-qi,LUO Yang,YUAN Chao2//1. Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China,2. Xian Modern Chemistry Research Institute,Xian 710065,China.
Abstract:5-phenyltetrazale and 5-methylene bistetrazale were synthesized and characterized by MS and element analysis. The Pb (II) , Cu(II) and Sr(II) salts of tetrazales were also prepared and their application in RDX-CMDB propellant were investigated preliminarily. The experimental results suggest that the salts are good energetic catalysts of composite modified double-base ( CMDB) propellant.
Keywords:5-methylene bistetrazale  5-phenyltetrazale  Pb (II)  Cu(II) and Sr(II) salts  energetic catalyst
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