Si3N4－TiN－SiC复相陶瓷的燃烧合成

Si₃N₄－TiN－SiC Multiphase ceramics was produced by self-propagating high-temperature synthesis with TiSi₂ and SiC. The liqu id phases produced during combustion of TiSi₂ and N₂ will decrease conversi on factor of the products. The effect of the dilution and nitrogen pressure on t he conversion of the products and combustion temperature was analyzed. The contradictory of liquid phases, dilution and combustion temperature was reso lved by increasing nitrogen pressure. Decrease of porosity was resulted from the volume expansion of discomposed TiSi₂,the volume expansion of Si transformed to Si₃N₄ at high temperature. The nitride mechanism of TiSi₂ was studied. TiN was first synthesized,then Si₃N₄ was formed.

Combustion Synthesis of Si3N4