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Marangoni effects under electric fields
Authors:V Mohan  K Chandrasekharan  K Padmanabhan
Institution:Department of Chemical Engineering, A.C. College of Technology, Anna University, Madras 600 025, India;Central Instrumentaton Laboratories, University of Madras, A.C. College Campus, Madras 600 025, India
Abstract:An electric field when applied across liquid-liquid interface was found to cause, due to different susceptibilities of the two phases, what the authors would term as Marangoni “type” of instabilities, that resulted in the generation of bubbles/drops and caused the movement of the interface countering gravity. Thus “mixing” of the two phases would occur and in systems involving mass transfer, enhanced rates of transfer could be expected.Equations for the bubble formation involving parameters such as electrostatic pressure, surface tension, gravity force have been derived.In the case of non-gravitational or weak-gravitational fields such as obtainable in space, the separation of two liquids one below the other, as obtaining on the earth, exhibiting an interface may well nearly be impossible. Under such conditions recourse may have to be taken to super-imposition of other fields as a tool for obtaining the necessary contacting/separation. The dynamics of bubble formation etc. under these contexts are theoretically analysed.
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