| 马尔科夫尼可夫规则机理的讨论 |
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| 引用本文： | 郭守田.马尔科夫尼可夫规则机理的讨论[J].沈阳航空工业学院学报,1994(1):59-65. |
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| 作者姓名： | 郭守田 |
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| 作者单位： | 沈阳航空工业学院化学教研室 |
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| 摘 要： | 不对称烯烃与不对称试剂进行亲电加成反应时,遵守马尔科夫尼可夫规则,本文从生成碳正离子和环状高价正离子的两种反应途径对其反应机理加以讨论,并指出决定两种途径的主要因素.
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| 关 键 词： | 碳正离子 环状高价正离子 诱导效应 不对称烯烃 |
The Discussion on Reaction Mechanim of Mar Kovnikov's Rule |
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| Guo shoutian.The Discussion on Reaction Mechanim of Mar Kovnikov''''s Rule[J].Journal of Shenyang Institute of Aeronautical Engineering,1994(1):59-65. |
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| Authors: | Guo shoutian |
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| Institution: | Guo shoutian |
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| Abstract: | The Markovnikov's Rule is abserved in the process of AdE reaction the unsymmet-rica! Alkenes with unsymmetrical reagent. In this article,the reactian mechanism will bediscussed through two roud of producing Carbonium ion and ring -shaped high price positive ion. At the same time point out two important factors affecting two rouds. |
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| Keywords: | carbonium ion ring-shaped nigh price positive ion induction hybrid atomic orbital Markovnikov's rule |
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