Ultraviolet spectroscopy and remote sensing of the upper atmosphere

The Earth's ultraviolet airglow contains fundamental diagnostic information about the state of its upper atmosphere and ionosphere. Our understanding of the excitation and emission processes which are responsible for the airglow has undergone dramatic evolution from the earliest days of space research through the past several years during which a wealth of new information has been published from high-resolution spectroscopy and imaging experiments. This review of the field begins with an overview of the phenomenology: how the Earth looks in the ultraviolet. Next the basic processes leading to excitation of atomic and molecular energy states are discussed. These concepts are developed from first principles and applied to selected examples of day and night airglow; a detailed review of radiation transport theory is included. This is followed by a comprehensive examination of the current status of knowledge of individual emission features seen in the airglow, in which atomic physics issues as well as relevant atmospheric observations of major and minor neutral and ionic constituents are addressed. The use of airglow features as remote sensing observables is then examined for the purpose of selecting those species most useful as diagnostics of the state of the thermosphere and ionosphere. Imaging of the plasmasphere and magnetosphere is also briefly considered. A summary of upcoming UV remote sensing missions is provided.