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不同粘合剂RDX/AP推进剂燃烧产物的分析研究
引用本文:涂永珍,徐浩星,王朝珍,叶玲,罗爱琴,付若农.不同粘合剂RDX/AP推进剂燃烧产物的分析研究[J].推进技术,1997,18(5):95-99.
作者姓名:涂永珍  徐浩星  王朝珍  叶玲  罗爱琴  付若农
作者单位:湖北红星化学研究所!襄樊,441003(涂永珍,徐浩星,王朝珍),北京理工大学化工与材料学院!北京,100081(叶玲,罗爱琴,付若农)
摘    要:以聚醚、HTPB、NEPE三种不同粘合剂体系的RDX/AP少烟推进剂为研究对象,用裂解色谱-质谱联用技术分析了它们的裂解产物的组成。发现推进剂中所采用的粘合剂类型不同时,其裂解产物的组成和含量不同,NEPE少烟推进剂基峰44占70%,聚醚少烟推进剂基峰44只占10%,这是造成两类推进剂压强指数不同的原因。

关 键 词:固体推进剂  燃烧产物  仪器分析

COMBUSTION PRODUCTS ANALYSIS OF RDX/AP PROPELLANT WITH DIFFERENT BINDERS
Tu Yongzhen, Xu Haoxing, Wang Chaozhen.COMBUSTION PRODUCTS ANALYSIS OF RDX/AP PROPELLANT WITH DIFFERENT BINDERS[J].Journal of Propulsion Technology,1997,18(5):95-99.
Authors:Tu Yongzhen  Xu Haoxing  Wang Chaozhen
Institution:Coll. of Chemical Engineering and Material Science,Beijing Inst. of Technology, Beijing, 100081;Coll. of Chemical Engineering and Material Science,Beijing Inst. of Technology, Beijing, 100081;Coll. of Chemical Engineering and Material Science,Beijing Inst. of Technology, Beijing, 100081;Coll. of Chemical Engineering and Material Science,Beijing Inst. of Technology, Beijing, 100081;Coll. of Chemical Engineering and Material Science,Beijing Inst. of Technology, Beijing, 100081;Coll. of Chemical Engineering and Material Science,Beijing Inst. of Technology, Beijing, 100081
Abstract:Smoke reduced propellants with different binders such as HTPB, Polyether, NEPEare studied. The composition of the pyrolytic products are measured by PYGC-MS The result showsthat the products and their contents in pyrolytic processes are different. The measured valuerepresenting the 44 peak in the NEPE smoke-reduced propellant is 70% of the total value. while theone in the polyether smoke-reduced propellant is only 10%, which results in the difference in pressureexponent between these two propellants.
Keywords:Solid propellant  Combustion product  Instrumental analysis
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