Absorbers seen near the Venus cloud tops from pioneer Venus

Spin-scan images from the Pioneer Venus Orbiter UV Spectrometer and the Cloud Photopolarimeter provide a set of planetary contrast measurements in the wavelength range 1990A to 3650A and phase angles from 33°–130°. The planet is darkest at the point where the UVS line of sight penetrates perpendicular to the cloud tops: thus the absorbing material responsible must be deep in the atmosphere. Sulfur dioxide absorption can explain the amount of contrast seen between 2000A and 3200A. At the longer wavelengths, the persistence of contrast requires another absorber which is deeper in the atmosphere and strongly associated with the location of the SO₂. Part of the observed contrast is due to the high-lying haze discovered from Pioneer Venus polarimetry. The correlation between planetary contrast and polarization does not support large scale clearing or major vertical motions of the cloud tops as the sole cause of the observed contrast. However, a scheme in which absorbers subject to photochemical destruction are mixed upward into the cloud top region provides a consistent explanation for the origin of these markings.