The chemical profiles of polar ice on Earth and Mars: What we read from the first; what we could read from the second

An analogy is drawn between the current knowledge on terrestrial snow and ice-cap chemistry and the possible composition of snowfall and ice caps of Mars. Terrestrial snowfall reflects the composition of the Earth's atmosphere. Snow cover further interacts with the atmosphere and is the recipient of aerosol and particulate fall-out. The snow is transformed to firn and ice and the chemical signatures become locked into the perennial ice sheets. The chemical profiles of ice thus constitute environmental records of the Earth's past. By considering the present knowledge on the hydrologie cycle of Mars and the chemistry of the atmosphere, a simple analogous model for the chemical profile of the North polar ice cap is proposed. Three major constituents of the ice are discussed: water ice, dust, and occluded air bubbles. The seasonal fluctuations and interannual variability of these components are examined as possible chemical signatures for the dating of ice, elucidating hydrologie processes, and recording long-term climatic change. The model of the north polar cap in summer consists of water-ice fine-dust layers (30–200 m thick) sandwiched between annual dust layers of variable size distribution and thickness (< 1m– > 66 m). The water ice is subjected to metamorphism and grain growth. The interpretation of the physico-chemical profile could lead to increased knowledge on the recent climatic past (1,000–2,000 years), hydrologic reservoirs, and seasonal cycles in the atmospheric dynamics of the planet.