Boundary of nighttime ozone chemical equilibrium in the mesopause region: Improved criterion of determining the boundary from satellite data

A modified derivation of the criterion of nighttime ozone chemical equilibrium (NOCE) in the mesopause region is presented. According to 3D model calculations, the improved criterion reproduces the lower boundary of the equilibrium much better than its earlier version. Processing of the SABER/TIMED data of 2021 has shown that the modified criterion elevates the NOCE boundary by ～ 0.1–1.7 km, depending on latitude and season. The proposed method of determining the condition of chemical equilibrium can be used to analyse the equilibrium of many trace gases in the stratosphere and troposphere important for different practical applications.