Si3N4陶瓷二次部分瞬间液相连接模型

在Si3N4陶瓷PTLP连接的基础上,提出了Si3N4陶瓷二次PTLP连接中间层设计的一般规律为Ti Cu X(X为Ni,Pt,Au,Pd等),X与Cu在固相和液相均是完全互溶的;分析了陶瓷二次PTLP连接过程并建立了连接模型,阐述了利用该模型选择连接参数的方法。     

陶瓷基复合材料界面相设计

综述了陶瓷基复合材料界面相的类型及作用，对SiC1／SiC陶瓷复合材料界面相的设计方法作了简要评述。在此基础上，用能使得纤维表面富碳的先驱体作为纤维涂层，制作了C1／SiC陶瓷基复合材料试样。结果表明，高温处理后，富碳涂层可减少纤维强度损失，使复合材料的强度和韧性同时得到提高。     

含硼富燃燃气燃烧实验研究

为实现固冲发动机二次燃烧模型验证,结合固冲发动机工作条件,设计了一种带透明观察窗燃烧实验装置;营造了简单的燃烧环境,实现了燃烧过程掺混作用的弱化;借助高速摄像进行了以空气速度作为单一变量的含硼富燃燃气燃烧可视化测量,获得了火焰形态结构;采用高速数据采集,获得了燃烧室压力;将实验数据与数值模拟结果进行了对比和分析。结果表明,燃气与空气速度相近时,火焰呈锥角结构,硼粒子的点火距离较长;燃气与空气速度差较小时,同一位置燃烧室压力较大;燃气与空气速度近似程度决定火焰的形态;数值模拟结果与实验结果基本吻合。     

Grinding performance evaluation of porous composite-bonded CBN wheels for Inconel 718

For high-efficiency grinding of difficult-to-cut materials such as titanium and nickel alloys, a high porosity is expected and also a sufficient mechanical strength to satisfy the function.However, the porosity increase is a disadvantage to the mechanical strength. As a promising pore forming agent, alumina bubbles are firstly induced into the abrasive layer to fabricate porous cubic boron nitride（CBN） wheels. When the wheel porosity reaches 45%, the bending strength is still high up to 50 MPa with modified orderly pore distribution. A porous CBN wheel was fabricated with a total porosity around 30%. The grinding performance of the porous composite-bonded CBN wheel was evaluated in terms of specific force, specific grinding energy, and grinding temperature, which were better than those of the vitrified one under the same grinding conditions. Compared to the vitrified CBN wheel, clear straight cutting grooves and less chip adhesion are observed on the ground surface and there is also no extensive loading on the wheel surface after grinding.     

用CBN刀具高速切削灰铸铁的试验研究

研究了CBN刀具高速切削灰铸铁时的刀具前、后刀面磨损、耐用度以及富氧气氛对切削性能的影响,所用的灰铸铁具有不同的铁素体、珠光体比例,最高切削速度达1＇100 m/min.研究表明Amborite刀具的刀尖磨损略大于BZN6000刀具,在较低速度下加工以铁素体为主的灰铸铁时更容易发生月牙洼磨损;BZN6000刀具以700 m/min的切削速度加工铁素体含量较高的灰铸铁时耐用度较高,Amborite刀具的耐用度随切削速度而升高;在富氧气氛中切削可以减轻刀具磨损,这一效果对BZN6000刀具更为显著.文章中对这些现象的原因进行了讨论.     

纳米TiC粉末改性钎料钎焊CBN磨粒的结合界面和磨损特性

采用了Ag-Cu-Ti 合金和纳米 TiC 粉末组成的新型复合钎料钎焊立方氮化硼(CBN)磨粒和工具基体,运用了三维体式显微镜和扫描电镜,研究了CBN磨粒与改性钎料之间的结合体系,包括界面微结构和反应产物,并进行了钎焊磨粒耐磨性试验.试验结果表明:加入的纳米TiC粉末均匀分布在钎料层内,细化了Ag-Cu-Ti合金钎料层的显微组织,有效控制了CBN磨粒与钎料的剧烈反应;磨粒表面化合物均匀致密,确保了CBN磨粒、纳米改性钎料和基体之间的结合强度;钎焊CBN磨粒的磨损形式以磨耗磨损为主,后期出现微小破碎,无磨粒脱落.     

Si3 N4 粉体的分散及表面改性

研究了以聚丙烯酸铵为分散剂的Si3N4悬浮体的分散特性,以及酸洗和热氧化两种表面改性方法对Si3N4悬浮体的分散性和流变特性的影响.结果表明:分散剂聚丙烯酸铵的最佳酸碱环境为pH=9,最佳使用含量为0.2wt％,酸洗可有效去除粉料中的金属杂质,使Si3N4粉体在悬浮体中粒径分布更集中且粒径主峰值向小粒径移动,同时可使悬浮体的黏度降低.热氧化处理可大幅度降低Si3N4悬浮体的黏度,提高其流变特性.     

Friction and Wear Properties of Amorphous Carbon Nitride Coatings in Water Lubrication

The friction and wear properties of amorphous carbon nitride(a-CN x)coatings in water lubrication were reviewed.The influences of mating materials and tribological variables such as normal load(W)and sliding speed(V)on the friction and wear properties of the a-CN x coatings were analyzed.It was indicated that the specific wear rate of the a-CN x coatings was related to the hydration reaction of mating materials with water.If the mating materials were easily hydrated,the specific wear rate of a-CN x coatings was low.The water-lubricated properties of the a-CN x coatings were better in comparison to the a-C coatings.The a-CN x/Si-based non-oxide ceramics tribo-pairs exhibited the lowest friction coefficient and wear rate.To describe their friction and wear properties at the normal loads of 3—15Nand the sliding speeds of 0.05—0.5m/s,the wear-mechanism maps for the a-CN x/SiC(Si3N4)tribo-pairs in water were developed.     

非水体系合成多种形貌氮化硅基纳米孔材料

分别以乙腈、氯仿和甲酰胺为溶剂,十八胺为模板剂,通过非氧化物溶胶-凝胶过程合成了多种形貌的氮化硅基纳米孔材料。利用X射线衍射(X-ray d iffraction,XRD)、透射电子显微镜(T ransm iss ion e lectronm icroscope,TEM)、N2吸附-脱附和电子能谱(Energy d ispers ive spectroscope,EDS)对样品进行了表征。XRD结果显示产物是层间距为4.7 nm和3.6 nm的层状相材料。TEM照片表明,在乙腈、氯仿和甲酰胺溶剂中分别得到花状、片状和核-环状形貌的氮化硅基材料。N2吸附-脱附分析表明,产物具有较高的比表面积和窄的孔径分布。EDS分析证明,产物含有S i,N,C,C l元素而不含有O元素。非水体系中表面活性剂自组装形成的介观相可以作为模板来指导具有特殊介观结构和形貌的纳米材料的合成。     

BN纤维/Nylon1010复合电子基板材料的制备与性能

采用挤压注塑法制备BN／Nylonl010复合电子基板材料,研究了不同BN纤维填充量的复合基板材料的微观组织结构和复合电子基板材料的介电性能及导热性能。结果表明,当BN纤维体积含量小于40％时,BN纤维基本上以孤岛形式分布在Nylon1010基体上;当BN纤维体积含量大于40％时,BN纤维开始形成连续网络。复合基板的介电常数随着BN纤维含量的增加而线性增加,介质损耗则随着BN纤维含量的增加而线性降低,复合基板的热导率随BN纤维的加入量增加而增大,但起初变化较小。当BN纤维体积含量大于40％时,热导率开始迅速增加。