Ti2AlNb基合金的ISM熔炼研究

讨论了Ti2AlNb基合金的熔炼特点,概括介绍了真空水冷铜坩埚感应凝壳熔炼的设备结构原理和工艺技术,结合Ti2AlNb基合金的熔炼实践,研究了合金元素的加入形式、熔炼室真空度对合金铸锭的均匀性以及合金中Al挥发烧损的影响规律。结果表明:采用水冷铜坩埚真空感应凝壳熔炼Ti2AlNb基合金,合金铸锭成分均匀性很好,随着熔炼工艺的不同,Al挥发烧损在5％～10％（质量分数）之间。     

TiAl合金不同钛铝比层片组织的稳定性

对钛铝比为１．１７４、１．１０５和１．０４１的（ＴｉＡｌ）－２．５Ｖ－１Ｃｒ（ａｔ％）合金层片组织在１３２３Ｋ热暴露中的组织变化进行了观察和分析。发现钛铝比对ＴｉＡｌ合金层片组织的稳定性和失稳分解机理有重要影响，钦铝比适当大于１：１（如１．１０５）的合金可以得到稳定性更好的层片组织。     

新型阻燃Ti40合金TIG焊焊接性能研究

研究新型阻燃钛合金Ti40合金的TIG(tungest inert gas)焊焊接性能,采用金相、SEM等方法分析Ti40合金焊缝及热影响区的组织变化.结果表明,Ti40合金钨极氩弧焊焊缝室温、高温拉伸性能良好,冲击性能较低.焊接之后的热处理制度对组织有一定的改善.经500℃×100h热暴露后,晶界粗化,为连续α相.     

Ti-24A1-17 Nb合金的激光焊接

研究了Ti-24Al-17Nb合金的激光焊接及其接头的力学性能.研究结果表明,连续激光氦气双面保护可以获得保护效果可靠、无缺陷、成型良好的焊接接头.焊接热输入增大不利于接头的纵向弯曲塑性,而接头的横向拉伸强度与母材基本相同,塑性可以接近母材的塑性,达到14%～17%.     

Microstructure,porosity and mechanical properties of selective laser melted AlSi10Mg

Finite element modeling (FEM), microscopy, X-ray computed tomography (CT) and mechanical property tests were used to study the microstructure, porosity and mechanical properties of an AlSi10Mg alloy produced by selective laser melting (SLM). The simulation of the melt pool and thermal history under different energy densities produced an optimized result with an energy density of 44.5 J·mm⁻³. The high cooling rate during the SLM process significantly refined the previous α-Al dendrites. The growth direction of the network-like Al-Si eutectic structure at different orientations confirmed the anisotropic nature of the microstructure. Furthermore, the microhardness, tensile testing and fracture analysis results proved that there were no obvious distinctions in the strength between the transverse and longitudinal directions, and that the ductility was anisotropic, possibly due to the shape and distribution of the pores. The pores measured by X-ray CT at different energy densities confirmed that the sphericity of the pores was inversely related to pores volumes. With optimized processing conditions, the porosity of the selective laser melted sample decreased leading to the improved fabricated fuel system component via SLM.     

10cm氙离子推力器变推力特性研究

非重力阻尼的连续、快速、高精度补偿是实现重力梯度测量卫星精细重力场测量的关键技术之一,直接影响到整星工程任务的成败。针对重力梯度测量卫星在轨飞行期间对电推进系统宽范围连续变推力能力的应用需求,分析了10cm氙离子推力器推力调节响应特性。在此基础上,通过对阳极电流、励磁电流和阳极流率等推力高敏感响应参量的组合调节,开展了推力调节试验研究,验证了10cm氙离子推力器宽范围连续变推力调节能力,获得了1～20mN范围内的推力调节性能及其变化规律。试验结果表明：在采用地面供电、供气设备条件下,10cm氙离子推力器能够在100～597W的功率范围内实现0.98～20.29mN的推力宽范围调节,比冲175～3500s,推力分辨率优于50μN。研究为建立10cm氙离子电推进系统的推力控制数学模型及调节控制算法奠定基础。     

Corrosion mechanism investigation of TiN/Ti coating and TC4 alloy for aircraft compressor application

It is imperative to develop multifunctional erosion and corrosion resistant coatings for compressor blades of aircraft engines in harsh environment. PVD (Physical Vapor Deposition) technology has the advances in processing erosion-resistant coatings; however, the performance of PVD coatings to combat corrosion depends on various coating defects. Determining and comparing the corrosion performances of PVD TiN/Ti coating and uncoated TC4 alloy was the main objective of present work. The 960 h salt spray corrosion and 116 h hot corrosion tests were conducted to simulate the grounding and working environments of the aircraft compressors. The corrosion mechanisms due to the coating defects such as pinhole, columnar boundary and large grain were analyzed based on the OM, Confocal microscope, electrochemical measurements, SEM, XRD and EDS results. Owing to the disordered state associated with the columnar boundary and the coating defect, nitrogen could be easily replaced by oxygen in the hot corrosion process, these structures were channels for fast diffusion of oxygen. Moreover, the Gibbs energy changes of Ti oxidation and TiN oxidation were thermodynamically calculated according to the working condition of aircraft compressors, and considerable research effort was focused on mapping out the phase diagram of Ti, TiN and high pressure gases. The findings of this research can provide insights into developing multifunctional coatings for future aircraft engines.     

MA 及原位-热压合成TiC/ Ti5 Si3 复合材料

以Ti粉、Si粉和C粉为原料,利用高能球磨及热压工艺合成了TiC/Ti5Si3陶瓷复合材料。研究了工艺条件尤其是热压温度对合成产物相组成及微观结构的影响,并结合DSC、XRD和SEM对反应合成机理进行探讨。结果表明:通过优化合成工艺,高能球磨12 h,热压温度1 400℃时,烧结6 h得到了高纯度的TiC/Ti5Si3陶瓷复合材料;合成过程为:反应开始时发生Ti+C■TiC,反应ΔG=-167.72 kJ/mol。2 h时发生5TiC+8Si■Ti5Si3+5SiC,反应ΔG=-62.12 kJ/mol,当6 h时发生3SiC+8Ti■Ti5Si3+3TiC,反应ΔG=-697.8 kJ/mol。显微结构表明:TiC/Ti5Si3复合材料的合成过程伴随Si熔融,该材料以TiC-Si-Ti5Si3形式相结合,其中Si为黏结剂。     

TA2/Ni+Nb中间层/1Cr18Ni9Ti扩散焊接头的组织与性能

采用50μm纯Ni箔+10μm纯Nb箔复合中间层,在焊接温度840℃,880℃和920℃,压力4MPa以及保温时间60min的工艺下,对工业纯钛TA2和1Cr18Ni9Ti不锈钢进行了真空扩散焊实验,测试了接头的抗拉强度,并利用光学显微镜(OM)、扫描电镜(SEM)、能谱(EDS)和X射线衍射(XRD)对接头的组织结构、元素分布以及断口形貌和相组成进行了分析。结果表明:Ni+Nb复合中间层的存在成功阻止了Fe,Ti互扩散,实现了TA2与1Cr18Ni9Ti的可靠连接,接头的拉伸强度达到261MPa,该强度主要受剩余Ni箔控制,且焊接温度的变化对其影响不大。接头所生成反应层自不锈钢一侧起分别为FeCrNi固溶体、剩余Ni,Ni3Nb,剩余Nb以及TiNb魏氏体。     

采用Ti-Zr-Cu-Ni真空钎焊Ti_3Al/Ti_3Al和Ti_3Al/GH536接头组织及性能

采用Ti-Zr-Cu-Ni在960℃/1min、960℃/10min和960℃/60min三种规范下真空钎焊Ti3Al/Ti3Al,在960℃/5min和960℃/20min两种规范下真空钎焊Ti3Al/GH536。实验结果表明,随着保温时间的延长,Ti3Al/Ti3Al接头宽度逐渐增加,且剪切强度呈现递增趋势,递增幅度在10MPa左右,接头主要由Ti3Al,NiTi2,CuTi3等化合物相组成,其中NiTi2,CuTi3等脆性化合物的分布对接头性能影响较大;在Ti3Al/GH536接头中由于Fe-Ti,Ni-Ti等脆性化合物分布相对较多,导致出现纵向裂纹,960℃/5min规范下的平均剪切强度为86.4MPa。