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酚醛树脂基蒙脱土纳米复合材料的力学性能与增强增韧机理 总被引:7,自引:0,他引:7
利用三种蒙脱土(即S-MMT,TG-2,OLS,统称MMT)和一种短切纤维(Short-cutGlassFiber,简记为SGF),分别与酚醛树脂熔融混合,制得酚醛树脂基复合材料。通过缺口冲击实验和弯曲实验,对这些复合材料的力学性能和增强增韧机理进行了研究,取得了一些有规律性的结果。PF/NBR/SGF复合材料的缺口冲击强度、弯曲强度和弯曲模量都随SGF含量的增加而增大;PF/NBR基蒙脱土纳米复合材料的缺口冲击强度随纳米材料(即S-MMT,TG-2和OLS)含量的增加而增大,在含量为5份时达到最大值;弯曲强度和弯曲模量也随纳米材料含量的增加而增大,在含量为9份时达到最大值。其次,所有PF/NBR基复合材料的缺口冲击强度均在60℃取得最大值,PF/NBR/OLS,PF/NBR/TG-2,PF/NBR/S-MMT等三种纳米复合材料的力学性能与体系中蒙脱土的层间距密切相关。层间距越大,力学性能越好。最后,探讨了纳米蒙脱土增强增韧PF/NBR体系的机理,指出聚合物体系中的蒙脱土具有两种效应,并建立了模型。 相似文献
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采用双酚E型氰酸酯树脂(BECE)和端羟基聚醚砜(Mx)共改性酚醛型氰酸酯树脂(NovolacCE),并将其与石英布复合制备出了一种耐温400℃、低损耗的改性氰酸酯载体胶膜。结果表明,适量的BECE和Mx热混合加入Novolac-CE树脂中,改善了Novolac-CE的浸润性和韧性,其与石英纤维的接触角降至72.8°,冲击韧性提高到13 kJ/m~2。相比于没经过处理的石英布,经过0.5%KH550/乙醇溶液处理的石英布与Novolac-CE树脂间的粘接强度最大提高70%,但是过多的KH550加入影响胶膜的耐热性。胶膜经200℃/4 h固化后,400℃时剪切强度大于5 MPa,且连续使用60 min后强度保持率大于80%,介电损耗为0.014。胶膜具有良好的自黏性并且室温适用期大于15 d,可作为耐高温(400℃)透波粘接材料应用。 相似文献
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一种活性环氧增韧固化剂性能分析 总被引:1,自引:0,他引:1
以壬基酚和甲醛所形成的二聚体为原料,合成了一种新型结构的环氧固化剂双(2-羟基-3 -胺乙基胺甲基-5-壬基苯基)甲烷(BA),利用红外光谱(IR)、核磁共振谱(1HNMR)表征了产物结构.通过差 示扫描量热(DSC)研究了该固化剂的反应活性,确定固化剂最佳质量分数为43.19%.固化 树脂动态力学分析(DMA)表明,由于BA分子结构中存在正壬基,固化后会发生β- 松弛, 能够提高树脂韧性.力学性能测试发现BA固化树脂的冲击强度比普通芳香胺固化树脂提高了 36.91%,证明BA具有高活性和增韧双重效果. 相似文献
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《中国航空学报》2019,32(9):2211-2221
Carbon fiber reinforced plastic and titanium alloy (CFRP/Ti) stacks have been widely used as aerospace structures because of their excellent combination of physical properties. Interface damage caused by interface gaps, significantly different from that of metal/metal stacks, is a common problem in the through-hole drilling of CFRP/Ti stacks with low stiffness. In this study, a force–deformation coupling model was developed to further examine the formation mechanism and the control method of interface damage. Firstly, the coupling model was built considering the interaction between the thrust force and the deformation. To solve this model, a numerical method was proposed in which specific cutting coefficients were calibrated using only the thrust force of rigid stacks. Secondly, drilling experiments were performed with different feed rates and bending stiffness. Experimental results indicate that interface damage mainly includes interlayer chips and surface damage of CFRP layers. The surface damage, which is irreparable, is caused by the rotary extension of metal chips along the interlayer gap. Thirdly, variations of the interface gap were calculated with the coupling model that had been verified by measured thrust forces. The damage area was found to have a linear dependence relation with the interlayer gap. However, in conditions of large gap sizes, the interface damage areas increased with the interlayer gap at high feed rates, while decreasing slightly at low feed rates. This phenomenon was satisfactorily explained by the presented model. Finally, a method was proposed to determine the appropriate pressure exceeding which no interlayer damage will occur. Additional drilling experiments proved the method effective. This study leads to further understanding of the forming mechanism of interlayer damage and of selecting appropriate parameters in drilling low-stiffness composite/metal stacks. 相似文献
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热塑性树脂增韧MBMI/DABPA复合材料效果研究 总被引:6,自引:0,他引:6
以韧性较高的4,4'-二氨基二苯甲烷双马来酰亚胺/3,3'-二烯丙基双酚A共聚树脂(MBMI/DABPA)作为对象,研究了共混热塑性树脂对其纤维增强复合材料性能的影响。结果表明,分子链刚性大的酚酞聚芳醚砜(PES-C)比刚性较小的酚酞聚芳醚酮(PEK-C)的增韧效果差,含端羟基的PEK-C增韧复合材料的断裂韧性G1c并不比普通封端PEK-C增韧的高,PEK-C分子量和用量的适当增加,有利于复合材料韧性的提高。共混12.5%的PEK-C,改性树脂玻璃纤维复合材料G1c高达938J/m^2,碳纤维复合材料G1c为552J/m^2,比未增韧的T300/XU292提高163%。 相似文献
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综述了碳/环氧复合材料层间增韧的研究现状与发展趋势,着重对碳/环氧复合材料层间增韧方法与性能的关系进行了介绍. 相似文献