Expectations for Infrared Spectroscopy of 9P/Tempel 1 from Deep Impact

The science payload on the Deep Impact mission includes a 1.05–4.8 μm infrared spectrometer with a spectral resolution ranging from R∼200–900. The Deep Impact IR spectrometer was designed to optimize, within engineering and cost constraints, observations of the dust, gas, and nucleus of 9P/Tempel 1. The wavelength range includes absorption and emission features from ices, silicates, organics, and many gases that are known to be, or anticipated to be, present on comets. The expected data will provide measurements at previously unseen spatial resolution before, during, and after our cratering experiment at the comet 9P/Tempel 1. This article explores the unique aspects of the Deep Impact IR spectrometer experiment, presents a range of expectations for spectral data of 9P/Tempel 1, and summarizes the specific science objectives at each phase of the mission.     

Spectroscopy peculiarities of thermal plasma of electric arc discharge between electrodes with Zn admixtures

Plasma of the free burning electric arc between Ag–SnO₂–ZnO composite electrodes as well as brass electrodes were investigated. The plasma temperature distributions were obtained by Boltzmann plot method involving Cu I, Ag I or Zn I spectral line emissions. The electron density distributions were obtained from the width and from absolute intensity of spectral lines. The laser absorption spectroscopy was used for measurement of copper atom concentration in plasma. Plasma equilibrium composition was calculated using two independent groups of experimental values (temperature and copper atom concentration, temperature and electron density). It was found that plasma of the free burning electric arc between brass electrodes is in local thermodynamical equilibrium. The experimental verification of the spectroscopic data of Zn I spectral lines was carried out.     

交流阻抗谱法评价热障涂层的热腐蚀行为(英文)

本文利用交流阻抗这种无损检测的方法研究了热障涂层在质量分数为25%NaCl+75%Na2SO4混合盐体系中的热腐蚀行为。实验结果显示,热腐蚀条件下,在陶瓷层和粘结层界面处形成TGO层为混合氧化物层,成分为Cr2O3、(Ni,Co)(Cr,Al)2O4和NiO,其厚度增长符合抛物线规律。热障涂层在110个循环腐蚀之前时,TGO层的电阻值随其厚度的增加而增加;110个循环后,虽然TGO层的厚度还是在增加,但由于TGO层孔隙的增多而导致其电阻值有所下降。陶瓷层的电阻值随着陶瓷层中裂纹的萌生和扩展而不断增大。等效电路中得到的参数可以用来表征热障涂层的失效行为。     

高摩擦性能碳／碳复合材料的微观结构

使用激光拉曼探针和电子显微术对试样的断裂面和薄膜样品观察及电子衍射技术研究了两种抗摩擦性能相差悬殊的碳／碳复合材料的微观结构，发现两种材料的微观结构在石墨晶体的结晶结构完整性和取得性以及纤维和基体间的界面行为上有显著差异。     

Broadening of Fe X (6374 Å) profiles above the limb in a coronal hole

Profiles of the visible Fe X (6374 Å) coronal emission line as a function of height above the limb were obtained out to 1.16 solar radii in a coronal hole using the NSO/Sacramento Peak Observatory Coronagraph, Universal Spectrograph and a CCD camera. These are the first coronal line profiles obtained as a function of height in a coronal hole from the ground. Analysis of the line widths suggests a large component of nonthermal broadening which increases with height ranging from 40 to 60 km/s, depending upon the assumed temperature or thermal component of the profile.     

主成分分析用于近红外光谱定量测定高硅氧／酚醛预浸料树脂含量及挥发份含量研究

采用傅里叶变换近红外漫反射光谱技术分析了酚醛树脂固化过程的光谱变化,发现高硅氧/酚醛预浸料的近红外光谱经一阶导数处理后,被树脂信息掩盖的挥发份(乙醇)的光谱信息显露出来,由此采用处理后的光谱定量分析挥发份能取得更精确的结果。结合主成分分析法研究了高硅氧/酚醛预浸料树脂含量、挥发份含量的定量分析。结果表明,预浸料的第一主成分在树脂含量上有极高的正载荷。用主成分回归所建立的模型对未知样品预测,树脂含量和挥发份含量平均标准偏差分别为0.6114和0.1885。     

老化时间对涂层性能的影响

利用电化学阻抗谱(EIS)技术研究了含有锌铬黄防锈颜料的环氧酯漆涂层的耐蚀性能。研究发现,当老化时间为4周时,涂层的耐蚀性能最佳,时间过长或过短都使得涂层性能下降。并且EIS技术可以用来研究涂层的老化。     

UVCS/SOHO Observations of Spectral Line Profiles in Polar Coronal Holes

Ultraviolet emission line profiles have been measured on 15-29 September 1997 for H I 1216 Å, O VI 1032, 1037 Å and Mg X 625 Å in a polar coronal hole, at heliographic heights ? (in solar radii) between 1.34 and 2.0. Observations of H I 1216 Å and the O VI doublet from January 1997 for ? = 1.5 to 3.0 are provided for comparison. Mg X 625 Å is observed to have a narrow component at ? = 1.34 which accounts for only a small fraction of the observed spectral radiance, and a broad component that exists at all observed heights. The widths of O VI broad components are only slightly larger than those for H I at ? = 1.34, but are significantly larger at ? = 1.5 and much larger for ? > 1.75. In contrast, the Mg X values are less than those of H I up to 1.75 and then increase rapidly up to at least ? = 2.0, but never reach the values of O VI.     

SF6分解气的近红外在线检测技术研究

为满足SF6绝缘电气设备故障监测与预警的实际需求,分析了国内分解气检测研究现状.对比近红外与中红外吸收光谱检测技术,提出近红外吸收光谱技术在线检测的技术方案.计算分析待测气体特征谱线的吸收系数、吸收光程和电路信噪比对精度的影响,完成系统参数设计.提出SF6分解气在线检测系统方案,实现对H2S、HF和CO这3种气体测量.数据分析表明,系统检测精度优于5×10-7,表明该系统满足电力行业在线测量的需求.     

钛合金的离子束改性

钛合金是航空航天工业常用的结构材料,它具有重量轻、强度高、抗腐蚀强等优良性能,但耐磨性较差.为提高其耐磨性,对TC4、TA7航材试件,采用溅射方法在其表面镀上钛膜,并用(N^＋＋N^＋₂)混合离子束进行动态反冲注入及单元素C^＋离子束注入两种方法,进行表面改性.精密摩擦、磨损试验及显微硬度测量结果,试件表面的滑动摩擦系数降低了64%~77%;磨损率减少了22%~48%;显微硬度提高0.3~1.4倍.证明离子注入有效地改善了合金表层的摩擦、磨损性能.对注入样品进行X射线光电子能谱(XPS)分析,发现注入后的钛合金表层,生成了大量的TiO₂,并析出TiN,TiC等金属化合物,这是降低摩擦系数,提高耐磨性的主要因素.添加C^＋离子注入的试件,其力学性能并无进一步改善,原因有待分析.