Comparative neutral composition instrumentation and new results

Composition and gas density measurement at all altitudes in the atmospheres of earth and other planets are made by mass spectrometers. Because of the impartiality and large dynamic range they are particularly favored for exploratory missions. Measurements of trace constituents, inert gases and height profiles, especially below clouds, are objectives where mass spectrometry is most useful. Significant advances have been made in recent years in development of light weight automated instruments. Experiments conducted in rarified atmospheres have been more successful or results were less controversial than in attempts to analyze high pressure atmospheres. Gas sampling and conditioning techniques are highly specific because of measurement environments and engineering constraints on the mission, and are usually the most critical elements in the experiment. Chemical sample enrichment and scrubbing for noble gas enhancement are additional sample conditioning techniques now employed. Dynamic range of more than 10⁸ is achievable. Reliable measurements of complex organic or chemically active trace constituents with mixing ratios of less than 10^?9 still require significant instrument development particularly where weight, power and sampling time are severely restricted. Adaptation of familiar and proven laboratory techniques for flight instruments is usually not straightforward and practical.     

The Cassini Ion and Neutral Mass Spectrometer (INMS) Investigation

The Cassini Ion and Neutral Mass Spectrometer (INMS) investigation will determine the mass composition and number densities of neutral species and low-energy ions in key regions of the Saturn system. The primary focus of the INMS investigation is on the composition and structure of Titan’s upper atmosphere and its interaction with Saturn’s magnetospheric plasma. Of particular interest is the high-altitude region, between 900 and 1000 km, where the methane and nitrogen photochemistry is initiated that leads to the creation of complex hydrocarbons and nitriles that may eventually precipitate onto the moon’s surface to form hydrocarbon–nitrile lakes or oceans. The investigation is also focused on the neutral and plasma environments of Saturn’s ring system and icy moons and on the identification of positive ions and neutral species in Saturn’s inner magnetosphere. Measurement of material sputtered from the satellites and the rings by magnetospheric charged particle and micrometeorite bombardment is expected to provide information about the formation of the giant neutral cloud of water molecules and water products that surrounds Saturn out to a distance of ∼12 planetary radii and about the genesis and evolution of the rings.The INMS instrument consists of a closed ion source and an open ion source, various focusing lenses, an electrostatic quadrupole switching lens, a radio frequency quadrupole mass analyzer, two secondary electron multiplier detectors, and the associated supporting electronics and power supply systems. The INMS will be operated in three different modes: a closed source neutral mode, for the measurement of non-reactive neutrals such as N₂ and CH₄; an open source neutral mode, for reactive neutrals such as atomic nitrogen; and an open source ion mode, for positive ions with energies less than 100 eV. Instrument sensitivity is greatest in the first mode, because the ram pressure of the inflowing gas can be used to enhance the density of the sampled non-reactive neutrals in the closed source antechamber. In this mode, neutral species with concentrations on the order of ≥10⁴ cm⁻³ will be detected (compared with ≥10⁵ cm⁻³ in the open source neutral mode). For ions the detection threshold is on the order of 10⁻² cm⁻³ at Titan relative velocity (6 km sec⁻¹). The INMS instrument has a mass range of 1–99 Daltons and a mass resolutionM/ΔM of 100 at 10% of the mass peak height, which will allow detection of heavier hydrocarbon species and of possible cyclic hydrocarbons such as C₆H₆.The INMS instrument was built by a team of engineers and scientists working at NASA’s Goddard Space Flight Center (Planetary Atmospheres Laboratory) and the University of Michigan (Space Physics Research Laboratory). INMS development and fabrication were directed by Dr. Hasso B. Niemann (Goddard Space Flight Center). The instrument is operated by a Science Team, which is also responsible for data analysis and distribution. The INMS Science Team is led by Dr. J. Hunter Waite, Jr. (University of Michigan).This revised version was published online in July 2005 with a corrected cover date.     

Chemical composition measurements of the atmosphere of Jupiter with the Galileo Probe mass spectrometer.

The Galileo Probe entered the atmosphere of Jupiter on December 7, 1995. Measurements of the chemical and isotopic composition of the Jovian atmosphere were obtained by the mass spectrometer during the descent over the 0.5 to 21 bar pressure region over a time period of approximately 1 hour. The sampling was either of atmospheric gases directly introduced into the ion source of the mass spectrometer through capillary leaks or of gas, which had been chemically processed to enhance the sensitivity of the measurement to trace species or noble gases. The analysis of this data set continues to be refined based on supporting laboratory studies on an engineering unit. The mixing ratios of the major constituents of the atmosphere hydrogen and helium have been determined as well as mixing ratios or upper limits for several less abundant species including: methane, water, ammonia, ethane, ethylene, propane, hydrogen sulfide, neon, argon, krypton, and xenon. Analysis also suggests the presence of trace levels of other 3 and 4 carbon hydrocarbons, or carbon and nitrogen containing species, phosphine, hydrogen chloride, and of benzene. The data set also allows upper limits to be set for many species of interest which were not detected. Isotope ratios were measured for 3He/4He, D/H, 13C/12C, 20Ne/22Ne, 38Ar/36Ar and for isotopes of both Kr and Xe.