Volatile Trapping in Martian Clathrates

Thermodynamic conditions suggest that clathrates might exist on Mars. Despite observations which show that the dominant condensed phases on the surface of Mars are solid carbon dioxide and water ice, clathrates have been repeatedly proposed to play an important role in the distribution and total inventory of the planet’s volatiles. Here we review the potential consequences of the presence of clathrates on Mars. We investigate how clathrates could be a potential source for the claimed existence of atmospheric methane. In this context, plausible clathrate formation processes, either in the close subsurface or at the base of the cryosphere, are reviewed. Mechanisms that would allow for methane release into the atmosphere from an existing clathrate layer are addressed as well. We also discuss the proposed relationship between clathrate formation/dissociation cycles and how potential seasonal variations influence the atmospheric abundances of argon, krypton and xenon. Moreover, we examine several Martian geomorphologic features that could have been generated by the dissociation of extended subsurface clathrate layers. Finally we investigate the future in situ measurements, as well as the theoretical and experimental improvements that will be needed to better understand the influence of clathrates on the evolution of Mars and its atmosphere.     

Geochemical Consequences of Widespread Clay Mineral Formation in Mars’ Ancient Crust

Clays form on Earth by near-surface weathering, precipitation in water bodies within basins, hydrothermal alteration (volcanic- or impact-induced), diagenesis, metamorphism, and magmatic precipitation. Diverse clay minerals have been detected from orbital investigation of terrains on Mars and are globally distributed, indicating geographically widespread aqueous alteration. Clay assemblages within deep stratigraphic units in the Martian crust include Fe/Mg smectites, chlorites and higher temperature hydrated silicates. Sedimentary clay mineral assemblages include Fe/Mg smectites, kaolinite, and sulfate, carbonate, and chloride salts. Stratigraphic sequences with multiple clay-bearing units have an upper unit with Al-clays and a lower unit with Fe/Mg-clays. The typical restriction of clay minerals to the oldest, Noachian terrains indicates a distinctive set of processes involving water-rock interaction that was prevalent early in Mars history and may have profoundly influenced the evolution of Martian geochemical systems. Current analyses of orbital data have led to the proposition of multiple clay-formation mechanisms, varying in space and time in their relative importance. These include near-surface weathering, formation in ice-dominated near-surface groundwaters, and formation by subsurface hydrothermal fluids. Near-surface, open system formation of clays would lead to fractionation of Mars’ crustal reservoir into an altered crustal reservoir and a sedimentary reservoir, potentially involving changes in the composition of Mars’ atmosphere. In contrast, formation of clays in the subsurface by either aqueous alteration or magmatic cooling would result in comparatively little geochemical fractionation or interaction of Mars’ atmospheric, crustal, and magmatic reservoirs, with the exception of long-term sequestration of water. Formation of clays within ice would have geochemical consequences intermediate between these endmembers. We outline the future analyses of orbital data, in situ measurements acquired within clay-bearing terrains, and analyses of Mars samples that are needed to more fully elucidate the mechanisms of martian clay formation and to determine the consequences for the geochemical evolution of the planet.     

Recent Advancements and Motivations of Simulated Pluto Experiments

This review of Pluto laboratory research presents some of the recent advancements and motivations in our understanding enabled by experimental simulations, the need for experiments to facilitate models, and predictions for future laboratory work. The spacecraft New Horizons at Pluto has given a large amount of scientific data already rising to preliminary results, spanning from the geology to the atmosphere. Different ice mixtures have now been detected, with the main components being nitrogen, methane, and carbon monoxide. Varying geology and atmospheric hazes, however, gives us several questions that need to be addressed to further our understanding. Our review summarizes the complexity of Pluto, the motivations and importance of laboratory simulations critical to understanding the low temperature and pressure environments of icy bodies such as Pluto, and the variability of instrumentation, challenges for research, and how simulations and modeling are complimentary.     

A facility for simulating Titan’s environment

As a result of measurements acquired by the Cassini–Huygens mission of Titan’s near surface atmospheric composition and temperature, Titan conditions can now be simulated in the laboratory and samples can subsequently be subjected to those conditions. Titan demonstrates an active hydrological-like cycle with its thick atmosphere, dynamic clouds, polar lakes of methane and ethane, moist regolith, and extensive fluvial erosive features. Unlike Earth, Titan’s hydrological-like cycle likely involves several constituents, primarily methane and ethane. Here the properties of a new Titan simulation facility are presented, including conceptual methodology, design, implementation, and performance results. The chamber maintains Titan’s surface temperature and pressure, and the sample cryogenic liquids undergoing experimentation are condensed within the chamber itself. During the experiments, the evaporation rates of the sample liquids are directly determined by continually measuring mass. Constituents are analyzed utilizing a Fourier Transform Infrared Spectroscopy (FTIR), and vapor concentrations are determined using a gas chromatograph fitted with a Flame Ionization Detector (FID). All pertinent data is logged via computer. Under laboratory conditions, the direct measurements of the evaporation rates of methane, ethane, and mixtures thereof can be achieved. Among the processes to be studied are the effects of regolith on transport from the subsurface to the atmosphere, the freezing point depression effects of dissolved nitrogen, and the solubility of various relevant organic compounds.     

Magnetism, iron minerals, and life on Mars

A short critical review is provided on two questions linking magnetism and possible early life on Mars: (1) Did Mars have an Earth-like internal magnetic field, and, if so, during which period and was it a requisite for life? (2) Is there a connection between iron minerals in the martian regolith and life? We also discuss the possible astrobiological implications of magnetic measurements at the surface of Mars using two proposed instruments. A magnetic remanence device based on magnetic field measurements can be used to identify Noachian age rocks and lightning impacts. A contact magnetic susceptibility probe can be used to investigate weathering rinds on martian rocks and identify meteorites among the small regolith rocks. Both materials are considered possible specific niches for microorganisms and, thus, potential astrobiological targets. Experimental results on analogues are presented to support the suitability of such in situ measurements.     

Penetration testing for the Optical Probe for Regolith Analysis (OPRA)

The Optical Probe for Regolith Analysis (OPRA) is a spike-shaped subsurface analytical probe that will be delivered to a planet, asteroid, or cometary body by a lander and/or rover. OPRA will be pushed down into the subsurface to record near infrared spectra as a function of depth down to maximum of 50 cm. Therefore, knowledge of the required penetration force to specific depths can be helpful in estimating the length of the probe. Test probes covering the anticipated diameter (2.5, 1.9, 1.2 and 0.9 cm diameter) and tip angle (T.A. = 30°, 60°, 90° and 120°) of OPRA were inserted mechanically into dry playground sand. The results showed that tip angle does not have a major effect, while probe diameter and density of the regolith are the most important parameters. Increasing probe diameter from 0.9 to 1.9 cm (i.e. a factor of 2) leads to an increase in penetration force from 200 to 1000 N (i.e. a factor of 5) at 20 cm depth. An increase in bulk density (B.D.) from 1550 to 1700 kg m⁻³ leads to an increase in penetration force from 10 to 200 N at 20 cm depth. Bearing capacity theory was used to explain the downward movement of the penetrometer through regolith and showed good agreement with the experimental results. This model was then used to take into account the effect of gravity on other planetary bodies. We observed a good agreement between the theoretical model and results from penetration testings on the Moon by the Apollo missions. Since the maximum allowed force for penetration is the weight of the lander/rover on their targeted planetary surface, our results put a strong constraint on the maximum reachable depth without endangering the whole mission.