A neutral gas mass spectrometer to measure the chemical composition of the stratosphere

The Polar Balloon Atmospheric Composition Experiment (P-BACE) is a new generation of neutral gas mass spectrometer based on the time-of-flight principle. P-BACE is the scientific experiment on the Mars Environment Analog Platform (MEAP) flown successfully on a balloon mission in summer 2008. The MEAP mission was flown with a 334,000 m³ helium balloon in the stratosphere on a semicircular trajectory from northern Sweden around the North Pole to Canada using the summer northern hemispheric wind current. The atmospheric conditions at an atmospheric altitude of 35–40 km are remarkably similar to those on the surface of Mars and thus the balloon mission was an ideal testbed for our mass spectrometer P-BACE. Originally this instrument was designed for in situ measurements of the chemical composition of the Martian atmosphere.P-BACE has a unique mass range from 0 to 1000 amu/q with a mass resolution m/Δm (FWHM) > 1000, and the dynamic range is at least six orders of magnitude. During this experiment, the acquisition of one mass spectrum is a sum of 65,535 single spectra, recorded in a time frame of 66 s.The balloon mission lasted 5 days and had successfully demonstrated the functionality of the P-BACE instrument during flight conditions. We had recorded more than 4500 mass spectra. With little modifications, P-BACE can be used on a planetary mission for Mars, but for example also for Venus or Mercury, if placed on a satellite.     

Hybrid LES/RANS methods for the simulation of turbulent flows

The coupling of large eddy simulation (LES) with statistical turbulence models, i.e. Reynolds-Averaged Navier–Stokes (RANS) models, is arguably the main strategy to drastically reduce computational cost for making LES affordable in a wide range of complex industrial applications. The present paper presents a coherent review of the various approaches proposed in the recent literature on this topic. First, basic concepts and principal strategies highlighting the underlying ideas are introduced. This culminates in a general scheme to classify hybrid LES/RANS approaches. Following the structure of this novel classification, a larger number of individual methods are then described and assessed. Key methods are discussed in greater detail and illustrated with examples from the literature or by own results. The aim of the review is to provide information on how to distinguish different methods and their ingredients and to further the understanding of inherent limitations and difficulties. On the other hand, successful simulation results demonstrate the high potential of the hybrid approach.     

An icy mineralogy package (IMP) for in-situ studies of Titan’s surface

We describe the scientific case for and preliminary design of an instrument whose primary goal is to determine the chemistry (element abundance) and mineralogy (compound identity and abundance) of Titan’s surface using a combination of energy dispersive X-ray fluorescence spectroscopy (EDXRF) and X-ray diffraction (XRD). XRD is capable of identifying any crystalline substance present on Titan’s surface at relative abundances greater than ∼1 wt%, allowing unambiguous identification of, for example, structure I and II clathrates (even in the presence of ice), and various organic solids, which may include C₂H₂, C₂H₄, C₄H₂, HCN, CH₃CN, HC₃N, and C₄N₂). The XRF component of the instrument will obtain elemental abundances for 16 < Z < 60 with minimum detection limits better than 10 ppm (including detection of atmospheric noble gas isotopes), and may achieve detection limits of 0.01–1% for lighter elements down to Z = 6 (carbon). The instrument is well suited to integration with other analytical tools as part of a light-weight surface chemistry and mineralogy package. Although considerably less sensitive to elemental abundance than GC–MS (10⁻² vs. 10⁻⁸) it is likely to be significantly lighter (<0.5 kg vs. 10 kg).     

Initial results of the evaluation of IRI hmF2 performance for minima 22–23 and 23–24

The performance of the International Reference Ionosphere (IRI) in predicting the height of the maximum of electron density (hmF2) has been evaluated for similar geomagnetic latitudes stations in the northern hemisphere (NH) and southern hemisphere (SH), and for the last two minima. As truth-sites, the digisonde stations of Millstone Hill (42.6°N, 288.5°E), USA, and Grahamstown (33.3°S, 26.5°E), South Africa, were considered. A monthly averaged diurnal variation was obtained from all the observations and model output in the months studied, and the corresponding difference was also calculated. For this initial study data from summer and winter in the NH and SH were selected for the solstice comparison, and October data for both stations were used to represent equinox conditions. The choice of these periods depended on data availability and quality. The results show that for the earlier minimum in 1996, in general IRI hmF2 values are in reasonable agreement with the observations. The exceptions are October and December in the SH, where IRI hmF2 tends to high, particularly on the dayside, and also July for which the daytime measured values tend to be larger than the IRI ones. For the recent minimum in 2008, IRI tends to over-estimate the hmF2 in most of the observations. The results support the general assertion that thermospheric temperatures were cooler during the last solar minimum as a consequence of an unusually low, and extended, minimum in solar extreme-ultraviolet flux, and in response to continually increasing long-term trend in anthropogenic carbon dioxide. The cooler temperatures not only decrease density at a fixed height, but also make the corresponding contraction of the atmosphere lower the height of the F-region peak.     

Phase Behaviour of Ices and Hydrates

The primary volatile ‘rock-forming’ minerals in the icy satellites of the outer solar system include water-ice and various hydrated crystals of methane and ammonia. The rich polymorphism of these substances as a function of pressure and temperature are described in this chapter. This polymorphism has a fundamental influence on the exchange of mass and energy between the core and the surface of icy satellites. We describe the current state-of-the-art in our understanding of the high pressure phase behaviour and the measurements of thermoelastic and transport properties of these substances. In addition we describe the structures and properties of hydrated phases of methanol, sulfuric acid, and various sulfate salts.     

The Mars Environment Analogue Platform long duration balloon flight

The MEAP (Mars Environment Analogue Platform) mission was to fly a stratospheric balloon on a semicircular trajectory around the North Pole in summer 2008. The balloon platform carried the high-resolution neutral gas mass spectrometer P-BACE (Polar Balloon Atmospheric Composition Experiment) as scientific payload. MEAP/P-BACE is a joint project between the Esrange Space Center, Sweden, the University of Bern, Switzerland and the Swedish Institute of Space Physics (IRF), Kiruna, Sweden. Mission objectives were to validate the platform for future long duration flights around the North pole, to validate the P-BACE instrument design for planetary mission applications (conditions in the Earth stratosphere are similar to the conditions at the Mars surface), to study variation of the stratospheric composition during the flight and to gain experience in balloon based mass spectrometry. All objectives were fulfilled.