Submicron magnetite grains and carbon compounds in Martian meteorite ALH84001: inorganic, abiotic formation by shock and thermal metamorphism

Purported biogenic features of the ALH84001 Martian meteorite (the carbonate globules, their submicron magnetite grains, and organic matter) have reasonable inorganic origins, and a comprehensive hypothesis is offered here. The carbonate globules were deposited from hydrothermal water, without biological mediation. Thereafter, ALH84001 was affected by an impact shock event, which raised its temperature nearly instantaneously to 500-700K, and induced iron-rich carbonate in the globules to decompose to magnetite and other minerals. The rapidity of the temperature increase caused magnetite grains to nucleate in abundance; hence individual crystals were very small. Nucleation and growth of magnetite crystals were fastest along edges and faces of the precursor carbonate grains, forcing the magnetite grains to be platy or elongated, including the "truncated hexa-octahedra" shape. ALH84001 had formed at some depth within Mars where the lithostatic pressure was significantly above that of Mars' surface. Also, because the rock was at depth, the impact heat dissipated slowly. During this interval, magnetite crystals approached chemical equilibria with surrounding minerals and gas. Their composition, nearly pure Fe(3)O(4), reflects those of equilibria; elements that substitute into magnetite are either absent from iron-rich carbonate (e.g., Ti, Al, Cr), or partitioned into other minerals during magnetite formation (Mg, Mn). Many microstructural imperfections in the magnetite grains would have annealed out as the rock cooled. In this post-shock thermal regime, carbon-bearing gas from the decomposition of iron carbonates reacted with water in the rock (or from its surroundings) to produce organic matter via Fischer-Tropschlike reactions. Formation of such organic compounds like polycyclic aromatic hydrocarbons would have been catalyzed by the magnetite (formation of graphite, the thermochemically stable phase, would be kinetically hindered).     

Characterization and Calibration of the CheMin Mineralogical Instrument on Mars Science Laboratory

A principal goal of the Mars Science Laboratory (MSL) rover Curiosity is to identify and characterize past habitable environments on Mars. Determination of the mineralogical and chemical composition of Martian rocks and soils constrains their formation and alteration pathways, providing information on climate and habitability through time. The CheMin X-ray diffraction (XRD) and X-ray fluorescence (XRF) instrument on MSL will return accurate mineralogical identifications and quantitative phase abundances for scooped soil samples and drilled rock powders collected at Gale Crater during Curiosity’s 1-Mars-year nominal mission. The instrument has a Co X-ray source and a cooled charge-coupled device (CCD) detector arranged in transmission geometry with the sample. CheMin’s angular range of 5^° to 50^° 2θ with <0.35^° 2θ resolution is sufficient to identify and quantify virtually all minerals. CheMin’s XRF requirement was descoped for technical and budgetary reasons. However, X-ray energy discrimination is still required to separate Co?Kα from Co?Kβ and Fe?Kα photons. The X-ray energy-dispersive histograms (EDH) returned along with XRD for instrument evaluation should be useful in identifying elements Z>13 that are contained in the sample. The CheMin XRD is equipped with internal chemical and mineralogical standards and 27 reusable sample cells with either Mylar^? or Kapton^? windows to accommodate acidic-to-basic environmental conditions. The CheMin flight model (FM) instrument will be calibrated utilizing analyses of common samples against a demonstration-model (DM) instrument and CheMin-like laboratory instruments. The samples include phyllosilicate and sulfate minerals that are expected at Gale crater on the basis of remote sensing observations.     

Computational aerodynamic analysis on perimeter reinforced （PR）-compliant wing

Abstract Implementing the morphing technique on a micro air vehicle （MAV） wing is a very chal- lenging task, due to the MAWs wing size limitation and the complex morphing mechanism. As a result, understanding aerodynamic characteristics and flow configurations, subject to wing structure deformation of a morphing wing MAV has remained obstructed. Thus, this paper presents the investigation of structural deformation, aerodynamics performance and flow formation on a pro- posed twist morphing MAV wing design named perimeter reinforced （PR）-compliant wing. The numerical simulation of two-way fluid structure interaction （FSI） investigation consist of a quasi- static aeroelastic structural analysis coupled with 3D incompressible Reynolds-averaged Navier- Stokes and shear-stress-transport （RANS-SST） solver utilized throughout this study. Verification of numerical method on a rigid rectangular wing achieves a good correlation with available exper- imental results. A comparative aeroelastic study between PR-compliant to PR and rigid wing per- formance is organized to elucidate the morphing wing performances. Structural deformation results show that PR-compliant wing is able to alter the wing＇s geometric twist characteristic, which has directly influenced both the overall aerodynamic performance and flow structure behavior. Despite the superior lift performance result, PR-compliant wing also suffers from massive drag penalty, which has consequently affected the wing efficiency in general. Based on vortices investigation, the results reveal the connection between these aerodynamic performances with vortices formation on PR-comoliant wing.