Gravitational Sensitivity of Solutions–Melts at the Crystallization of Two-Phase InSb–InBi Alloys under Space Conditions

Analyzing the results of space and ground-based experiments carried out in the Baikov Institute of Metallurgy and Materials Science to study the processes of the melting and crystallization of two-phase InSb–InBi alloys of an indium–antimony–bismuth (In–Sb– Bi) triple system, we have demonstrated the gravitational sensitivity of the InSb-based solution– melt. It manifests itself as a certain asymmetry of the boundary of the dissolution of the InSb ingot by the InSb–InBi melt and heterogeneity of the melt along this boundary depending on the magnitude and direction of the gravity force acceleration gin the range (1–10^–3–10^–5)g ₀, where g ₀is the acceleration of the gravity force on Earth. For the first time, it is established in the experiments under analysis that the homogeneity of melts of a complex composition with components of various densities can be reached only at magnitudes of quasistationary (residual) microaccelerations g< 10^–6 g ₀.     

Influence of Microaccelerations on the Impurity Distribution in the InSb:Te Crystals Grown in Orbital Flights by the Method of Floating Zone Melting

The periodicity of the structure of impurity heterogeneities in the longitudinal section of an indium antimonide monocrystal doped by tellurium (InSb:Te) is investigated. The monocrystal was grown by the method of floating zone melting onboard the Foton-3 satellite. It is shown that the frequencies of harmonic components of heterogeneities converted into the time region coincide with frequencies of microaccelerations in the range 0–0.005 Hz arising onboard the Foton satellites. This fact confirms the hypothesis stated previously that residual microaccelerations onboard the satellite were the cause of occurrence of indicated periodicities.     

The Influence of Arrangement of Growth Setups onboard a Spacecraft on Microgravity Conditions of Experiments: An Example of Floating Zone Melting of InSb:Te onboard the Foton-3 Satellite

The results of experiments on the growth of InSb:Te by the floating zone melting in the Zona-4 setup during a flight of the Foton-3 satellite are discussed in comparison with the data on the microgravity situation typical for satellites of this type. When analyzing inhomogeneities in the crystals obtained, we reveal the frequencies corresponding to periodical variations of the impurity channel position (the facet effect), to interleaving of packs in which the growth layers are grouped, and to location of subgroups of the growth layers inside the packs. These frequencies are close to those discovered during measurements of low-frequency (quasistationary) microaccelerations (g) onboard the spacecraft Foton-8, Foton-10, Foton-11, and Foton-12. Calculated values of g at the place where the Zona-4 setup is installed confirm the possibility of impact of such g on the heat and mass transfer in the melt.     

Gravitational Sensitivity of Melts at the Growth of InSb:Te Crystals by the Bridgman and Floating Zone Methods under the Conditions of Microgravity

The comparative analysis of the results of space and ground-based experiments IMET RAS on the growth of InSb:Te crystals by the Bridgman method and floating zone method (FZM) is made for the purpose of studying the influence of microgravity on the growth, structure, and properties of grown crystals, and thus the gravity sensitivity of InSb melt is demonstrated. It is shown that, under microgravity conditions, the Bridgman method makes it possible to grow InSb:Te crystals without contact with the ampoule walls, which provides for the single crystal structure, the absence of striations, and a low dislocation density. For the first time, InSb:Te monocrystals were grown with the FZM under microgravity. The anomalous behavior of the impurity core (facet effect) in these crystals correlates with the changed magnitude and direction of the quasi-stationary (residual) microaccelerations.