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S A Liebman R A Pesce-Rodriguez C N Matthews 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》1995,15(3):71-80
Hydrogen cyanide polymerizes readily to a black solid from which a yellow-brown powder can be extracted by water and further hydrolyzed to alpha-amino acids. These macromolecules could be major components of the dark matter observed on many bodies in the outer solar system, including comets and asteroids. Primitive Earth might therefore have been covered with HCN polymers through bolide bombardment or be terrestrial synthesis. Several instrumental methods were used for the separation and identification of these intriguing polymeric materials, including photoacoustic Fourier transform infrared spectroscopy, supercritical fluid extraction chromatography and pyrolysis mass spectrometry. Our integrated analytical approach revealed fragmentation patterns and chemical functionalities consistent with the presence of polymeric peptide precursors both in HCN polymers and in the Murchison meteorite. 相似文献
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瑞士威力铭-马科黛尔公司 《航空制造技术》2008,(13)
瑞士加工中心制造商威力铭-马科黛尔公司着重于质量和生产效率,主要活跃于航空/航天、精密机械、钟表和医疗行业,并以其为用户提供的高性能交钥匙解决方案而著称. 相似文献
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Macromolecules derived from hydrogen cyanide (HCN) may be major components of the dark matter observed in bodies in the outer Solar System, which include comets and asteroids. HCN oligomers and polymers are readily formed at room temperature and react with water to produce polypeptides and alpha-amino acids or undergo pyrolysis to produce nitrogen heterocycles. Electron spin resonance (ESR) spectroscopy shows that HCN polymer mixtures contain a significant amount of long-lived organic free radicals that are primarily carbon-based. For comparison, we have also examined samples of tholins produced from experimental analogs of Titan aerosols, which has been shown by trace organic analysis to consist partly of HCN polymer. The "Titan tholin" exhibits at least two ESR signals that can be assigned to nitrogen- and carbon-centered radicals, although heating the sample eliminates the nitrogen centers and increases the signal from the carbon centers. This result suggests that the nitrogen-centered radicals may be thermodynamically less stable, but are kinetically trapped during the spark-discharge reactions that produce tholins from mixtures of gases such as methane and nitrogen. The results strongly support previous proposals of free radical mechanisms for HCN polymerization. 相似文献
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采用基于密度泛函理论(DFT)的第一性原理计算方法,研究了M2CoA型Heusler合金Mn2CoAl、Mn2CoSi、Ti2CoAl和Ti2CoSi的电子结构和磁学性质。发现Heusler合金Mn2CoAl是亚铁磁性自旋无带隙半导体,Mn2CoSi与Ti2CoAl是亚铁磁性自旋半金属,而Ti2CoSi是铁磁性自旋半金属。它们的总自旋磁矩均为整数,符合Slater-Pauling规则。然后,在分析电子能带结构和态密度的基础上,探讨了自旋无带隙半导体与半金属性的根源。最后,声子谱和弹性常数计算结果表明所有M2CoA型Heusler合金在晶格动力学和力学上均是稳定的。 相似文献
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