Spectral behavior of hydrated sulfate salts: implications for Europa mission spectrometer design

Remote sensing of the surface of Europa with near-infrared instruments has suggested the presence of hydrated materials, including sulfate salts. Attention has been focused on these salts for the information they might yield regarding the evolution of a putative interior ocean, and the evaluation of its astrobiological potential. These materials exhibit distinct infrared absorption features due to bound water. The interactions of this water with the host molecules lead to fine structure that can be used to discriminate among these materials on the basis of their spectral behavior. This fine structure is even more pronounced at the low temperatures prevalent on icy satellites. Examination of hydrated sulfate salt spectra measured under cryogenic temperature conditions provides realistic constraints for future remote-sensing missions to Europa. In particular, it suggests that a spectrometer system capable of 2-5 nm spectral resolution or better, with a spatial resolution approaching 100 m, would be able to differentiate among proposed hydrated surface materials, if present, and constrain their distributions across the surface. Such information would provide valuable insights into the evolutionary history of Europa.     

Near-infrared detection of potential evidence for microscopic organisms on Europa

The possibility of an ocean within the icy shell of Jupiter's moon Europa has established that world as a primary candidate in the search for extraterrestrial life within our Solar System. This paper evaluates the potential to detect evidence for microbial life by comparing laboratory studies of terrestrial microorganisms with measurements from the Galileo Near Infrared Imaging Spectrometer (NIMS). If the interior of Europa at one time harbored life, some evidence may remain in the surface materials. Examination of laboratory spectra of terrestrial extremophiles measured at cryogenic temperatures reveals distorted, asymmetric nearinfrared absorption features due to water of hydration. The band centers, widths, and shapes of these features closely match those observed in the Europa spectra. These features are strongest in reddish-brown, disrupted terrains such as linea and chaos regions. Narrow spectral features due to amide bonds in the microbe proteins provide a means of constraining the abundances of such materials using the NIMS data. The NIMS data of disrupted terrains exhibit distorted, asymmetric near-infrared absorption features consistent with the presence of water ice, sulfuric acid octahydrate, hydrated salts, and possibly as much as 0.2 mg cm(-3) of carbonaceous material that could be of biological origin. However, inherent noise in the observations and limitations of spectral sampling must be taken into account when discussing these findings.     

Landforms of Europa and selection of landing sites

Three major features make Europa a unique scientific target for a lander-oriented interplanetary mission: (1) the knowledge of the composition of the surface of Europa is limited to interpretations of the spectral data, (2) a lander could provide unique new information about outer parts of the solar system, and (3) Europa may have a subsurface ocean that potentially may harbor life, the traces of which may occur on the surface and could be sampled directly by a lander. These characteristics of Europa bring the requirement of safe landing to the highest priority level because any successful landing on the surface of this moon will yield scientific results of fundamental importance. The safety requirements include four major components. (1) A landing site should preferentially be on the anti-Jovian hemisphere of Europa in order to facilitate the orbital maneuvers of the spacecraft. (2) A landing site should be on the leading hemisphere of Europa in order to extend the lifetime of a lander and sample pristine material of the planet. (3) Images with the highest possible resolution must be available for the selection of landing sites. (4) The terrain for landing must have morphology (relief) that minimizes the risk of landing and represents a target that is important from a scientific point of view. These components severely restrict the selection of regions for landing on the surface of Europa. After the photogeologic analysis of all Galileo images with a resolution of better than about 70 m/pixel taken for the leading hemisphere of Europa, we propose one primary and two secondary (backup) landing sites. The primary site (51.8°S, 177.2°W) is within a pull-apart zone affected by a small chaos. The first backup site (68.1°S, 196.7°W) is also inside of a pull-apart zone and is covered by images of the lower resolution (51.4 m/pixel). The second backup site (2.4°N, 181.1°W) is imaged by relatively low-resolution images (∼70 m/pixel) and corresponds to a cluster of small patches of dark and probably smooth plains that may represent landing targets of the highest scientific priority from the scientific point of view. The lack of the high-resolution images for this region prevents, however, its selection as the primary landing target.     

Behavioral endpoints for radiation injury.

The relative behavioral effectiveness of heavy particles was evaluated. Using the taste aversion paradigm in rats, the behavioral toxicity of most types of radiation (including 20Ne and 40Ar) was similar to that of 60Co photons. Only 56Fe and 93Nb particles and fission neutrons were significantly more effective. Using emesis in ferrets as the behavioral endpoint, 56Fe particles and neutrons were again the most effective; however, 60Co photons were significantly more effective than 18 MeV electrons. These results suggest that LET does not completely predict behavioral effectiveness. Additionally, exposing rats to 10 cGy of 56Fe particles attenuated amphetamine-induced taste aversion learning. This behavior is one of a broad class of behaviors which depends on the integrity of the dopaminergic system and suggests the possibility of alterations in these behaviors following exposure to heavy particles in a space radiation environment.     

Chemical Composition of Icy Satellite Surfaces

Much of our knowledge of planetary surface composition is derived from remote sensing over the ultraviolet through infrared wavelength ranges. Telescopic observations and, in the past few decades, spacecraft mission observations have led to the discovery of many surface materials, from rock-forming minerals to water ice to exotic volatiles and organic compounds. Identifying surface materials and mapping their distributions allows us to constrain interior processes such as cryovolcanism and aqueous geochemistry. The recent progress in understanding of icy satellite surface composition has been aided by the evolving capabilities of spacecraft missions, advances in detector technology, and laboratory studies of candidate surface compounds. Pioneers 10 and 11, Voyagers I and II, Galileo, Cassini and the New Horizons mission have all made significant contributions. Dalton (Space Sci. Rev., 2010, this issue) summarizes the major constituents found or inferred to exist on the surfaces of the icy satellites (cf. Table 1 from Dalton, Space Sci. Rev., 2010, this issue), and the spectral coverage and resolution of many of the spacecraft instruments that have revolutionized our understanding (cf. Table 2 from Dalton, Space Sci. Rev., 2010, this issue). While much has been gained from these missions, telescopic observations also continue to provide important constraints on surface compositions, especially for those bodies that have not yet been visited by spacecraft, such as Kuiper Belt Objects (KBOs), trans-Neptunian Objects (TNOs), Centaurs, the classical planet Pluto and its moon, Charon. In this chapter, we will discuss the major satellites of the outer solar system, the materials believed to make up their surfaces, and the history of some of these discoveries. Formation scenarios and subsequent evolution will be described, with particular attention to the processes that drive surface chemistry and exchange with interiors. Major similarities and differences between the satellites are discussed, with an eye toward elucidating processes operating throughout the outer solar system. Finally we discuss the outermost satellites and other bodies, and summarize knowledge of their composition. Much of this review is likely to change in the near future with ongoing and planned outer planet missions, adding to the sense of excitement and discovery associated with our exploration of our planetary neighborhood.     

Spectroscopy of Icy Moon Surface Materials

Remote sensing of icy objects in the outer solar system relies upon availability of appropriate laboratory measurements. Surface deposits of specific substances often provide our most direct route to understanding interior composition, thereby informing theories of endogenic surface modification, exogenic surface processing and processes involving exchange of material with the interiors. Visible to near-infrared reflectance spectra of properly prepared compounds are required to enable retrieval of surface abundances through linear and nonlinear mixture analysis applied to spacecraft observations of icy bodies. This chapter describes the techniques, conditions and approaches necessary to provide reference spectra of use to theoretical models of icy satellite surface compositions, and summarizes the current state of knowledge represented in the published literature.     

Methods and measurements to assess physical and geochemical conditions at the surface of Europa

An international effort dedicated to the science exploration of Jupiter system planned by ESA and NASA in the beginning of the next decade includes in-depth science investigation of Europa. In parallel to EJSM (Europa-Jupiter System Mission) Russia plans a Laplace-Europa Lander mission, which will include another orbiter and the surface element: Europa Lander. In-situ methods on the lander provide the only direct way to assess environmental conditions, and to perform the search for signatures of life. A critical advantage of such in situ analysis is the possibility to enhance concentration and detection limits and to provide ground truth for orbital measurements. The science mission of the lander is biological, geophysical, chemical, and environmental characterizations of the Europa surface. This review is dedicated to methods and strategies of geophysical and environmental measurements to be performed at the surface of Europa, and their significance for the biological assessment, basing on the concept of a relatively large softly landed module, allowing to probe a shallow subsurface. Many of the discussed methods were presented on the workshop “Europa Lander: Science Goals and Experiments” held in Moscow in February 2009. Methods and instruments are grouped into geophysical package, means of access to the subsurface, methods of chemical and structural characterization, and methods to assess physical conditions on the surface.