Spectroscopic evaluation of polyurea crosslinked aerogels,as a substitute for RTV-based chromatic calibration targets for spacecraft

Room temperature vulcanizing (RTV)-based components have been used on Mars Pathfinder, the Mars rovers, Spirit and Opportunity, as well as the Phoenix Lander as a support matrix for pigmented panoramic camera calibration targets. RTV 655 has demonstrated superiority to other polymers due to its unique range of material properties namely mechanical stability between −115 and 204 °C and UV radiation tolerance. As a result, it has been the number one choice for many space-related missions. However, due to the high mass density and the natural tendency for electrostatic charging RTV materials have caused complications by attracting and retaining dust particles (Sabri et al., 2008). In the current project we have investigated the relevant properties of polymer-reinforced (crosslinked) silica aerogels with the objective of substituting RTV-based calibration targets with an aerogel based design. The lightweight, mechanical strength, ability to accept color pigments, and extremely low dust capture makes polyurea crosslinked aerogels a strong candidate as a chromatic standard for extraterrestrial missions. For this purpose, the reflection spectra, gravimetric analysis, and low temperature response of metal oxide pigmented, polyurea crosslinked silica aerogels have been investigated and reported here.     

Total solar irradiance absolute level from DIARAD/SOVIM on the International Space Station

Current measurements from DIARAD/VIRGO, PMO6V/VIRGO and ACRIM3 radiometers are of the same order of magnitude, but differ from TIM/SORCE by about 4.5 W m⁻². This difference is higher than the sum of the claimed individual absolute uncertainties of the instruments. In this context, the SOLAR payload on the International Space Station embarks the SOVIM package. We give the results of the differential absolute radiometer DIARAD/SOVIM and discuss its associated uncertainties. Compared to DIARAD/VIRGO, all possible efforts have been made to improve the absolute accuracy. Substantial progress has been made in the aperture area and electrical power measurements. The measured TSI value from the left channel of DIARAD/SOVIM during three days of June 2008 is 1364.50 ± 1.38 W m⁻² (Total) or ±0.49 W m⁻² (if we combine the individual contributions in quadrature). The right channel gives 1364.75 W m⁻² with the same uncertainties. These values are about 1.2 W m⁻² lower than DIARAD/VIRGO and about 4 W m⁻² higher than TIM/SORCE. The difference between the left and right channels measurements is as low as 0.25 W m⁻² which is within the improved uncertainty limits.     

Thin film surface treatments for lowering dust adhesion on Mars Rover calibration targets

The current generation of calibration targets on Mars Rover serve as a color and radiometric reference for the panoramic camera. They consist of a transparent silicon-based polymer tinted with either color or grey-scale pigments and cast with a microscopically rough Lambertian surface for a diffuse reflectance pattern. This material has successfully withstood the harsh conditions existent on Mars. However, the inherent roughness of the Lambertian surface (relative to the particle size of the Martian airborne dust) and the tackiness of the polymer in the calibration targets has led to a serious dust accumulation problem. In this work, non-invasive thin film technology was successfully implemented in the design of future generation calibration targets leading to significant reduction of dust adhesion and capture. The new design consists of a μm-thick interfacial layer capped with a nm-thick optically transparent layer of pure metal. The combination of these two additional layers is effective in burying the relatively rough Lambertian surface while maintaining diffuse properties of the samples which is central to the correct operation as calibration targets. A set of these targets are scheduled for flight on the Mars Phoenix mission.