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We used Time Domain (1)H Nuclear Magnetic Resonance (NMR) to characterize changes in proton exchange between water and sugar enantiomers at different concentrations of H(2)(17)O (approximately 15-450 mM) and found that dissociation of the (-)-enantiomers of glucose and ribose occurs at significantly higher rates at higher concentrations of H(2)(17)O. The mechanism behind this enantioselective effect is unclear. The hypothesis we propose is that the large magnetic field (B(o) approximately 0.6T) applied during NMR measurements induces electric moments opposite in sign for the D and L-isomers. Because (17)O has a nuclear electric quadrupole moment not = 0, asymmetrically hydrated complexes may form between the B(o)-polarized enantiomers and H(2)(17)O. Either H(2)(17)O is more often hydrating the (+) than the (-)-enantiomers--and consequently pK differences between H(2)(16)O and H(2)(17)O lead to differences in proton exchange between enantiomers and water--or the orientation of H(2)(17)O relative to the B(o)-polarized enantiomers is different, in total or in part, which leads to hydrated complexes with different spatial geometries and different proton exchange properties. This effect is significant for Magneto-Chiral Stereo-Chemistry (MCSC) and astrobiology, and it may help us better understand specific instances of mass independent isotopic fractionation and aid in the development of new technologies for chiral and isotopic separation. 相似文献
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P. Groza A. Bordeianu S. Cananu A. Boca A. Petrescu D. Lungu 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》1981,1(14):179-185
Rats on board the Soviet Cosmos 936 satellite for 18 days showed a decreased glycoprotein secretion from the salivary mucous glands, stomach and intestine, and an increased leucine aminopeptidase and acid phosphatase content from the small intestine. Grimelius positive cells were activated. One group of rats were centrifuged at 1 g during the flight to simulate terrestrial gravity. Some investigations have suggested that under these conditions muscular and cardiac disorders diminished. In the digestive tract the benefits of centrifugation at 1 g are minimal and limited to a few glycoprotein components. The digestive changes are probably the expression of a stress response, unrelated to weightlessness. Similar changes, concomitant with a glycocorticoid hypersecretion, were found in rats after 15 days of hypokinesia on Earth. These digestive changes persisted even in adrenalectomized rats. 相似文献
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The paper focuses on the design of a new automatic landing system(ALS) in longitudinal plane; the new ALS controls the aircraft trajectory and longitudinal velocity. Aircraft control is achieved by means of a proportional-integral(PI) controller and the instrumental landing system– the first phase of landing(the glide slope) and a proportional-integral-derivative(PID) controller together with a radio-altimeter – the second phase of landing(the flare); both controllers modify the reference model associated with aircraft pitch angle. The control of the pitch angle and longitudinal velocity is performed by a neural network adaptive control system, based on the dynamic inversion concept, having the following as components: a linear dynamic compensator, a linear observer, reference models, and a Pseudo control hedging(PCH) block. The theoretical results are software implemented and validated by complex numerical simulations; compared with other ALSs having the same radio-technical subsystems but with conventional or fuzzy controllers for the control of aircraft pitch angle and longitudinal velocity, the architecture designed in this paper is characterized by much smaller overshoots and stationary errors. 相似文献
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