The ‘soot line’: Destruction of presolar polycyclic aromatic hydrocarbons in the terrestrial planet-forming region of disks

Interstellar material is highly processed when subjected to the physical conditions that prevail in the inner regions of protoplanetary disks, the potential birthplace of habitable planets. Polycyclic aromatic hydrocarbons (PAHs) are abundant in the interstellar medium, and they have also been observed in the disks around young stars, with evidence for some modification in the latter. Using a chemical model developed for sooting flames, we have investigated the chemical evolution of PAHs in warm (1000–2000 K) and oxygen-rich (C/O < 1) conditions appropriate for the region where habitable planets may eventually form. Our study focuses on (1) delineating the conditions under which PAHs will react and (2) identifying the key reaction pathways and reaction products characterizing this chemical evolution. We find that reactions with H, OH and O are the main pathways for destroying PAHs over disk timescale at temperatures greater than about 1000 K. In the process, high abundances of C₂H₂ persist over long timescales due to the kinetic inhibition of reactions that eventually drive the carbon into CO, CO₂ and CH₄. The thermal destruction of PAHs may thus be the cause of the abundant C₂H₂ that has been observed in disks. We propose that protoplanetary disks have a ‘soot line’, within which PAHs are irreversibly destroyed via thermally-driven reactions. The soot line will play an important role, analogous to that of the ‘snow line’, in the bulk carbon content of meteorites and habitable planets.     

Laser measurements to space debris from Graz SLR station

In order to test laser ranging possibilities to space debris objects, the Satellite Laser Ranging (SLR) Station Graz installed a frequency doubled Nd:YAG pulse laser with a 1 kHz repetition rate, a pulse width of 10 ns, and a pulse energy of 25 mJ at 532 nm (on loan from German Aerospace Center Stuttgart – DLR). We developed and built low-noise single-photon detection units to enable laser ranging to targets with inaccurate orbit predictions, and adapted our standard SLR software to include a few hundred space debris targets. With this configuration, we successfully tracked – within 13 early-evening sessions of each about 1.5 h – 85 passes of 43 different space debris targets, in distances between 600 km and up to more than 2500 km, with radar cross sections from >15 m² down to <0.3 m², and measured their distances with an average precision of about 0.7 m RMS.     

NEOs as stepping stones to Mars and main-belt asteroids

Human interplanetary missions are constrained by the problem of astronaut exposure to galactic cosmic radiation. This paper surveys the existing on-line near-Earth object (NEO) data base in an effort to identify NEOs that cross both Earth's ad Mars’ orbits and could be used as cosmic ray shields by interplanetary voyagers. The search concentrated on low-inclination Mars-crossing NEOs that approach Earth, Mars, and main-belt asteroids in the 2020–2100 time frame. Both outbound and return transfers were searched for. Several candidates for Earth–Mars, Mars–Earth, and Earth–Vesta transfers have been found from the very incomplete August 2008 data base. Other aspects of this interplanetary transfer option are considered.     

Interior Evolution of Mercury

The interior evolution of Mercury—the innermost planet in the solar system, with its exceptional high density—is poorly known. Our current knowledge of Mercury is based on observations from Mariner 10’s three flybys. That knowledge includes the important discoveries of a weak, active magnetic field and a system of lobate scarps that suggests limited radial contraction of the planet during the last 4 billion years. We review existing models of Mercury’s interior evolution and further present new 2D and 3D convection models that consider both a strongly temperature-dependent viscosity and core cooling. These studies provide a framework for understanding the basic characteristics of the planet’s internal evolution as well as the role of the amount and distribution of radiogenic heat production, mantle viscosity, and sulfur content of the core have had on the history of Mercury’s interior. The existence of a dynamo-generated magnetic field suggests a growing inner core, as model calculations show that a thermally driven dynamo for Mercury is unlikely. Thermal evolution models suggest a range of possible upper limits for the sulfur content in the core. For large sulfur contents the model cores would be entirely fluid. The observation of limited planetary contraction (∼1–2 km)—if confirmed by future missions—may provide a lower limit for the core sulfur content. For smaller sulfur contents, the planetary contraction obtained after the end of the heavy bombardment due to inner core growth is larger than the observed value. Due to the present poor knowledge of various parameters, for example, the mantle rheology, the thermal conductivity of mantle and crust, and the amount and distribution of radiogenic heat production, it is not possible to constrain the core sulfur content nor the present state of the mantle. Therefore, it is difficult to robustly predict whether or not the mantle is conductive or in the convective regime. For instance, in the case of very inefficient planetary cooling—for example, as a consequence of a strong thermal insulation by a low conductivity crust and a stiff Newtonian mantle rheology—the predicted sulfur content can be as low as 1 wt% to match current estimates of planetary contraction, making deep mantle convection likely. Efficient cooling—for example, caused by the growth of a crust strongly in enriched in radiogenic elements—requires more than 6.5 wt% S. These latter models also predict a transition from a convective to a conductive mantle during the planet’s history. Data from future missions to Mercury will aid considerably our understanding of the evolution of its interior.     

The MESSENGER Gamma-Ray and Neutron Spectrometer

A Gamma-Ray and Neutron Spectrometer (GRNS) instrument has been developed as part of the science payload for NASA’s Discovery Program mission to the planet Mercury. Mercury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) launched successfully in 2004 and will journey more than six years before entering Mercury orbit to begin a one-year investigation. The GRNS instrument forms part of the geochemistry investigation and will yield maps of the elemental composition of the planet surface. Major elements include H, O, Na, Mg, Si, Ca, Ti, Fe, K, and Th. The Gamma-Ray Spectrometer (GRS) portion detects gamma-ray emissions in the 0.1- to 10-MeV energy range and achieves an energy resolution of 3.5 keV full-width at half-maximum for ⁶⁰Co (1332 keV). It is the first interplanetary use of a mechanically cooled Ge detector. Special construction techniques provide the necessary thermal isolation to maintain the sensor’s encapsulated detector at cryogenic temperatures (90 K) despite the intense thermal environment. Given the mission constraints, the GRS sensor is necessarily body-mounted to the spacecraft, but the outer housing is equipped with an anticoincidence shield to reduce the background from charged particles. The Neutron Spectrometer (NS) sensor consists of a sandwich of three scintillation detectors working in concert to measure the flux of ejected neutrons in three energy ranges from thermal to ∼7 MeV. The NS is particularly sensitive to H content and will help resolve the composition of Mercury’s polar deposits. This paper provides an overview of the Gamma-Ray and Neutron Spectrometer and describes its science and measurement objectives, the design and operation of the instrument, the ground calibration effort, and a look at some early in-flight data.     

Collisional excitation of vinylidene (H2CC)

Though H₂CO, H₂CS, H₂CCC, H₂CCCC, H₂CCO have been identified in cool interstellar molecular clouds, identification of H₂CC is still awaited. To analyze its spectrum, collisional rate coefficients are required. We have calculated collisional rate coefficients for rotational transitions between 23 levels of ortho and para H₂CC for kinetic temperatures 10, 20, 30, 40, and 50 K. The scattering problem is analyzed using the computer code MOLSCAT where the colliding partner is He atom. The interaction between H₂CC and He has been calculated with GAUSSIAN 2003. For the interaction potential obtained with GAUSSIAN 2003, MOLSCAT is used to derive the parameters q(L,M,M^′|E)$q(L\text{,}M\text{,}{M}^{\prime }|E)$ as a function of energy E   of the colliding partner. After averaging the parameters q(L,M,M^′|E)$q(L\text{,}M\text{,}{M}^{\prime }|E)$ over a Maxwellian distribution, the parameters Q(L,M,M^′|T)$Q(L\text{,}M\text{,}{M}^{\prime }|T)$ as a function of the kinetic temperature T in the cloud are obtained. Finally, the collisional rate coefficients have been calculated.     

Superbursts and long bursts as surface phenomenon of compact objects

We suggest that superbursts from some low mass X-ray binaries may be due to breaking and re-formation of diquark pairs, on the surface of realistic strange stars. Diquarks are expected to break up due to the explosion and shock of the thermonuclear process. After a prolonged accretion when almost all pairs get broken, the subsequent production of copious diquarks may produce sufficient energy to produce the superbursts.