涡轮叶片蠕变损伤行为及固溶处理对叶片材料性能的影响

涡轮叶片是航空发动机及地面燃气轮机的重要热端部件,研究其损伤行为对涡轮叶片的制造及修复工作均有重要的意义。本文研究了长时与短时服役涡轮叶片的蠕变损伤行为,发现二者在蠕变空洞的形成机理上大致相同,而γ′相与碳化物的退化反应则有所差异,长时服役涡轮叶片的γ′相形貌更加粗大且不规则。对于碳化物,长时服役叶片的碳化物发生了由一次MC型向二次M23C6型的分解,而短时服役叶片的碳化物发生了由MC(1)型向MC(2)型的转化。此外,针对两种不同的叶片材料(K002和GTD-111高温合金),研究了不同的固溶处理制度对γ′相溶解行为的影响,发现提高固溶温度和增加固溶保温时间可以促进两种材料γ′相的溶解行为;而随着固溶时间的增加,两种材料的溶解激活能均逐渐增大,K002合金在不同固溶保温时间中的溶解激活能均大于GTD-111合金。     

热解碳界面层与国产T300 增韧SiC 复合材料拉伸性能关联性初探

在国产T300碳纤维上沉积不同厚度的热解碳形成界面层,通过前驱体浸渍裂解工艺制备“迷你”Cf/SiC复合材料,考察了T300碳纤维在相同工艺过程中其界面层厚度的最优工艺参数,并研究了热解碳界面层与“迷你”复合材料拉伸性能的关联性.采用SEM与Raman手段对Cf/SiC复合材料进行结构表征.结果表明:该复合材料有明显的裂纹偏转,经高温热处理后界面层状结构更加明显,其复合材料的拉伸强度随热解碳厚度的增加其值有先增加后减小的趋势(PyC的厚度在0～150 nm),当界面层厚度约为60 nm时达到最大值(1 385.7 MPa).     

新型碳化硅先驱体的制备及其性能研究

采用溶胶凝胶法，以正硅酸乙酯和酚醛树脂为原料，在草酸和六次甲基四胺的催化作用下，制备出了不含硫和氯等有害杂质的均相碳化硅先驱体，并在特定条件下，对所得先驱体进行烧结，使之转化为陶瓷。结果表明，溶胶凝胶法制得的先驱体呈黄色透明的玻璃态，其微观组成为几十纳米的微粒，树脂与SiO2可能通过氢键相互作用，有利于树脂在先驱体中均匀分布而形成均相先驱体，其陶瓷产率为78％；另外硝酸镍的加入对先驱体烧结过程中β-SiC的生成起到明显的促进作用。     

A hybrid chemical modification strategy for monocrystalline silicon micro-grinding: Experimental investigation and synergistic mechanism

For high performance manufacturing of micro parts and features, a hybrid chemical modification strategy is proposed to decrease critical energy barrier of mechanical removal of hard and brittle crystal material by refining localized machining condition. The strategy, namely UV-light and IR-laser hybrid chemical modification (UVIR-CM) strategy, includes two steps, an ultraviolet light (UV-light) catalytic advanced oxidation and an infrared laser (IR-laser) assisted selective modification based on Fenton liquid–solid reaction for monocrystalline silicon. The modification effects of UVIR-CM strategy were investigated by surface morphology micro-observation, cross-section transmission electron microscopy (TEM) observation, Raman spectroscopy analysis and nanoindentation test. Experimental results demonstrated that varied degrees of laser texturing appeared on different strategy samples’ IR-laser scanned area. And the IR-laser thermal damage has been successfully inhibited due to the refraction and reflection of energy by bubbles in liquid medium. But for the UVIR-CM strategy, a uniform and amorphous silicate layer is detected in a certain boundary. The UV-light promotes oxidation cycle ability of the chemical solution and ensures sufficient oxide modified layer for subsequent step. Attributing to synergism of photochemical, photothermal and kinetic effects induced by IR-laser, the modified layer displays layered structure with about 600 nm thickness, (2.7 ± 0.60) GPa nanohardness, and (93.7 ± 22.9) GPa indentation modulus. And the layered structure is amorphous layer, nanocrystal and micro-twins layer from the surface to the interior of sample. Consequently, it reveals that the subsequent mechanical removal will become easy due to decreasing energy barrier of monocrystalline silicon in selective area. Meanwhile, its original excellent mechanical properties also are maintained under a certain depth. The results contribute to develop a novel combined micro-machining technology to achieve collaborative manufacturing of structure shape and surface integrity for micro parts and feature.     

干式铣削Al-50wt%Si高硅铝合金刀具磨损与表面粗糙度评价

本文以Al-50wt%Si高硅铝合金为研究对象，采用单因素试验方法进行无涂层硬质合金刀具干式铣削试验，分析切削参数对刀具磨损和表面粗糙度的影响。结果表明：表面粗糙度受每齿进给量的影响最显著，随每齿进给量的增加而增加，当每齿进给量从0.07 mm/z增加到0.16 mm/z时，表面粗糙度增加2倍；刀具磨损受切削速度的影响最显著，随切削速度的增加而增加，当切削速度从140 m/min增加到260 m/min时，切削总长度降低3倍，而刀具后刀面磨损量仅是260 m/min速度下的0.8倍；表面粗糙度随刀具磨损的增加呈现先增加后降低的变化趋势，切削长度从350 mm增加到1 750 mm，刀具磨损量平均增加4.5倍，而表面粗糙度却下降2倍；硬质合金刀具主要的磨损形式为磨粒磨损、崩刃。