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631.
基于Gaussian09W软件,采用密度泛函理论(Density Functional Theory,DFT)的B3LYP方法,在6-311G(d)基组水平上优化了一种香豆素3,4-并六元杂环衍生物分子的结构,得到其最稳定构型、分子能量及HOMO、LUMO轨道能量。在优化结构的基础上,用同样的方法计算了该分子的振动频率,频率分析证明了该优化结构为最稳定结构。利用分子的振动频率数据绘制了标题分子的红外光谱图,对其红外光谱峰位进行了归属。 相似文献
632.
某地球同步三轴卫星因故障导致推力器工作效率不稳定,使得采用原有方案进行向西轨道控制时姿态变化大,控制准确度降低.针对上述问题,通过分析卫星用于姿态控制的偏置动量轮的控制规律,利用星体角动量守恒条件,建立了偏置动量轮转速变化与轨道半长轴变化之间的相关性数学模型,提出了一种改进的基于偏置动量轮转速标定的轨道控制方法,同时结合姿态的稳定变化制定了轨道控制实施方案,并将其应用于实际卫星轨道控制中,取得了良好的控制效果.改进的控制方法提高了轨道控制的准确率,使得半长轴误差幅度由最大60%提高到0.2%左右,增加了姿态的稳定性,使得俯仰姿态变化幅度由最大0.7°减小到0.2°左右,降低了控制风险,减轻了地面控制人员的负担. 相似文献
633.
Steven A. Walker Lawrence W. Townsend John W. Norbury 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》2013
Estimates of organ dose equivalents for the skin, eye lens, blood forming organs, central nervous system, and heart of female astronauts from exposures to the 1977 solar minimum galactic cosmic radiation spectrum for various shielding geometries involving simple spheres and locations within the Space Transportation System (space shuttle) and the International Space Station (ISS) are made using the HZETRN 2010 space radiation transport code. The dose equivalent contributions are broken down by charge groups in order to better understand the sources of the exposures to these organs. For thin shields, contributions from ions heavier than alpha particles comprise at least half of the organ dose equivalent. For thick shields, such as the ISS locations, heavy ions contribute less than 30% and in some cases less than 10% of the organ dose equivalent. Secondary neutron production contributions in thick shields also tend to be as large, or larger, than the heavy ion contributions to the organ dose equivalents. 相似文献
634.
Émilie Hardy Agnès Levy Manuel Rodrigues Pierre Touboul Gilles Métris 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》2013
The MICROSCOPE space mission aims to test the Equivalence Principle with an accuracy of 10-15. The drag-free micro-satellite will orbit around the Earth and embark a differential electrostatic accelerometer including two cylindrical test masses submitted to the same gravitational field and made of different materials. The experience consists in testing the equality of the electrostatic acceleration applied to the masses to maintain them relatively motionless. The accuracy of the measurements exploited for the test of the Equivalence Principle is limited by our a priori knowledge of several physical parameters of the instrument. These parameters are partially estimated on-ground, but with an insufficient accuracy, and an in-orbit calibration is therefore required to correct the measurements. The calibration procedures have been defined and their analytical performances have been evaluated. In addition, a simulator software including the dynamics model of the instrument, the satellite drag-free system and the perturbing environment has been developed to numerically validate the analytical results. After an overall presentation of the MICROSCOPE mission, this paper will describe the calibration procedures and focus on the simulator. Such an in-flight calibration is mandatory for similar space missions taking advantage of a drag-free system. 相似文献
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637.
铷原子钟物理部分是铷原子钟的原子鉴频器,决定铷原子钟的短期和长期稳定度(1s以上),其中使用了金属铷、玻璃、镍铁合金等材料和一些双极性晶体管、运算放大器等器件,其核心部件铷泡是一个采用特殊真空工艺制造的器件,这些材料、器件和工艺的低剂量率辐射效应需要实验评价。本文提出并完成了铷原子钟物理部分的低剂量率辐射实验,采用Co60γ源,辐射剂量率0.01rad(Si)/s,总剂量50krad(Si),对铷原子钟物理部分和铷泡的辐射效应分别进行了实验评估。这项研究更加真实地逼近了空间的电离辐射,实验数据对于星载铷原子钟的在轨运行监测和下一代星载铷原子钟的抗辐射设计具有重要的作用。 相似文献
638.
J. Semkova R. Koleva St. Maltchev N. Bankov V. Benghin I. Chernykh V. Shurshakov V. Petrov S. Drobyshev I. Nikolaev 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》2012
The Liulin-5 experiment is a part of the international project MATROSHKA-R on the Russian segment of the ISS, which uses a tissue-equivalent spherical phantom equipped with a set of radiation detectors. The objective of the MATROSHKA-R project is to provide depth dose distribution of the radiation field inside the sphere in order to get more information on the distribution of dose in a human body. Liulin-5 is a charged particle telescope using three silicon detectors. It measures time resolved energy deposition spectra, linear energy transfer (LET) spectra, particle flux, and absorbed doses of electrons, protons and heavy ions, simultaneously at three depths along the radius of the phantom. Measurements during the minimum of the solar activity in cycle 23 show that the average absorbed daily doses at 40 mm depth in the phantom are between 180 μGy/day and 220 μGy/day. The absorbed doses at 165 mm depth in the phantom decrease by a factor of 1.6–1.8 compared to the doses at 40 mm depth due to the self-shielding of the phantom from trapped protons. The average dose equivalent at 40 mm depth is 590 ± 32 μSV/day and the galactic cosmic rays (GCR) contribute at least 70% of the total dose equivalent at that depth. Shown is that due to the South Atlantic Anomaly (SAA) trapped protons asymmetry and the direction of Liulin-5 lowest shielding zone the dose rates on ascending and descending nodes in SAA are different. The data obtained are compared to data from other radiation detectors on ISS. 相似文献
639.
G. Nath 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》2012,49(1):108-120
A self-similar solution is obtained for one dimensional adiabatic flow behind a cylindrical shock wave propagating in a rotating dusty gas in presence of heat conduction and radiation heat flux with increasing energy. The dusty gas is assumed to be a mixture of non-ideal (or perfect) gas and small solid particles, in which solid particles are continuously distributed. It is assumed that the equilibrium flow-condition is maintained and variable energy input is continuously supplied by the piston (or inner expanding surface). The heat conduction is expressed in terms of Fourier’s law and the radiation is considered to be of the diffusion type for an optically thick grey gas model. The thermal conductivity K and the absorption coefficient αR are assumed to vary with temperature only. In order to obtain the similarity solutions the initial density of the ambient medium is assumed to be constant and the angular velocity of the ambient medium is assumed to be decreasing as the distance from the axis increases. The effects of the variation of the heat transfer parameters and non-idealness of the gas in the mixture are investigated. The effects of an increase in (i) the mass concentration of solid particles in the mixture and (ii) the ratio of the density of solid particles to the initial density of the gas on the flow variables are also investigated. 相似文献
640.