NC/GAP-TPE共混聚合物的制备和性能研究

采用扩链后共混再熟化的方法,制备了1组不同组成的硝化棉(NC)/含能热塑性弹性体(GAP-TPE)共混聚合物.采用红外光谱(FTIR)和X射线衍射(XRD)表征NC/GAP-TPE共混物的结构,扫描电镜(SEM)观察共混物的断面,动态热机械分析(DMA)测定共混物的玻璃化转变,运用拉伸实验研究不同配比NC/GAP-TP...     

纳米级金属粉对GAP热分解特性的影响

用ＤＳＣ和ＴＧ研究了纳米级Ｃｕ和Ｎｉ粉、超细Ａｌ粉和超细Ｎｉ粉以及普通Ｃｕ粉和Ａ粉对ＧＡＰ（聚叠氮缩水甘油醚）热分解特性的影响。ＤＳＣ实验结果表明：ＧＡＰ／金属粉样品有两个放热峰,高温区的放热峰是金属的氧化峰,峰温受气氛影响,低温区放热峰是ＧＡＰ的分解峰,不受气氛影响;金属Ｃｕ对ＧＡＰ的分解峰影响最大,其中纳米级Ｃｕ（ｎｍ－Ｃｕ）使ＧＡＰ分解放热峰的峰值温度提前了３３．２℃,普通Ｃｕ对ＧＡＰ的分解     

新型双基推进剂综合性能的研究

介绍一种新研制的无溶剂螺压双基推进剂，其比冲为２２５６Ｎ·ｓ／ｋｇ，燃速突破了４０ｍｍ／ｓ，压力指数小于０．５，采用Ｐｂ－Ｃｕ－Ｎｉ－Ｃ．Ｂ四元催化剂。     

含能粘合剂研究的新进展

新型含能粘合剂的研发对提高固体火箭推进剂的能量及性能有着重要的作用。本文根据国内外近年来在新型含能粘合剂研究方面取得的新进展,按照聚合物侧链所含取代基的不同,分别介绍了叠氮基聚醚粘合剂、硝酸酯粘合剂及其他几种含能粘合剂,对这些粘合剂的应用及性能进行了综合比较与讨论,最后展望了含能粘合剂技术的发展趋势,认为GAP、PGN等粘合剂将是21世纪初高能推进剂、低特征信号推进剂使用的主要品种。     

纳米鞣酸Pb(Ⅱ)配合物的合成及其燃烧催化性能研究

采用液相分散沉淀法制备了纳米鞣酸Pb(Ⅱ)配合物,用TG、TEM和FTIR对产物的形貌、粒径和组成进行了表征,考察了纳米鞣酸Pb(Ⅱ)配合物对RDX-CMDB推进剂燃烧的催化作用。结果表明,产物的平均粒径约为80 nm,能明显改善推进剂的燃烧性能,使推进剂的燃速提高了148%,压强指数(6~8 MPa)从0.861降低至0.129。     

December 2006 solar extreme events and their influence on the near-Earth space environment: “Universitetskiy-Tatiana” satellite observations

The Russian microsatellite “Universitetskiy-Tatiana” was launched on Jan. 20, 2005 and was both a scientific and educational mission. Its two main aims were declared as: (1) monitoring of the energetic particles dynamics in the near-Earth space environment after solar events and during quiet times, (2) educational activities based on experimental data obtained from the spacecraft. In this paper observations acquired during Dec. 5–16, 2006, known as “Solar Extreme Events 2006”, were analyzed. The “Universitetskiy-Tatiana” microsatellite orbit permits one to measure both solar energetic particle dynamics, variations of the boundary of solar particle penetration, as well as relativistic and sub-relativistic electrons of the Earth’s outer radiation belt during and after magnetic storms. Both relativistic electrons of the Earth’s outer radiation and solar energetic particles are an important source of radiation damage in near-Earth space. Therefore, the presented experimental results demonstrate the successful application of a small educational spacecraft both for scientific and educational programs.     

联合太阳和行星际物理参数预测行星际激波能否到达地球

选取第23太阳活动周（1997—2006年）期间542例由太阳爆发活动驱动的行星际激波事件,分析确定了太阳源头和行星际空间中影响行星际激波能否到达地球轨道的关键物理参数;在此基础上,建立了预测行星际激波能否到达地球的新预报模型（EdEaSPM）. 回溯预报结果表明,EdEaSPM模型的预报成功率约为66%,略高于国际一流预报模型的预报成功率;EdEaSPM模型的虚报率未超过50%,改善了当前国际主流模型虚报率较大的情况;对于偏度指标,虽然当前所有模型的偏度值均大于1,但EdEaSPM模型的偏度值最接近于1且明显小于其他模型的偏度值;EdEaSPM模型的其他评价指标也都高于国际主流模型的相应指标. 此外,选取2012年期间的激波事件对EdEaSPM模型进行了预报检验,预测结果与实际情况吻合. EdEaSPM模型不仅能够提前约1～3天进行预报,而且预报效果与国际一流模型具有可比性,尤其是在提高预报成功率及降低虚报率方面具有一定优势.     

A study on radio-loud interacting/non-interacting CMEs-associated SEPs and solar flares

We have established a data set of 58 major hybrid SEP events associated with meter-to-decahectometer wavelength (m-to-DH) type II bursts, solar flares, and radio-load CMEs during the period of 1997–2014. The main focus of our study is to address the following two questions: Does the interaction of CMEs play a role in the enhancement of SEP intensity? Is there any difference in the seed population, and parent eruptions in the SEP events with and without CME interactions? Hence, the sample of 58 events is classified into two sets: (i) 35 non-interacting-CME-associated SEP events; (ii) 23 interacting-CME-associated SEP events. All the characteristics of SEPs, their associated CMEs/flares and the relationships between them are statistically analyzed and compared. Some of the basic attributes and relative elemental abundances (Fe/O ratios) of the both the sets are also compared. The results indicate that the seed particles in non-interacting-CME-associated SEP events are mostly from solar wind/coronal materials. But in the case of interacting-CME-associated SEP events, it may be associated with both flare material from preceding flares and coronal materials from solar wind/preceding CMEs. The correlation studies reveal that there are clear correlations between logarithmic peak intensity of SEP events and properties of CMEs (space speed: cc?=?0.56) and solar flares (peak intensity: cc?=?0.40; integrated flux: cc?=?0.52) for non-interacting-CME-associated SEP events. But these correlations are absent for the interacting-CME-associated events. In addition, the results suggest that interaction of primary CMEs with their preceding CMEs plays an important role in the enhancement of peak intensity of SEPs at least for a set of m-to-DH type II bursts associated SEP events.     

硝胺无烟改性双基推进剂燃烧性能调节及控制规律的初探

根据多年研究工作的经验，对该类推进剂的催化剂品种选择，复合催化剂的协同作用，硝胺品种对燃烧性能影响，临界压力的下降，燃烧不稳定的抑制及烟雾特性等技术专题作了简要的总结。     

含2,4-二羟基苯甲酸铋催化剂的双基推进剂燃烧规律

1引言铅化合物是双基系推进剂中重要的燃烧催化剂,但其毒性引起了广泛关注。国外在研究对环境友善的绿色固体推进剂时,发现毒性极低的铋化合物对推进剂燃烧与常用的铅化合物具有相近催化效果,美国将2,4-二羟基苯甲酸铋用作双基推进剂燃烧催化剂来取代毒性较大的铅盐,以降低推进