增塑剂及燃烧催化剂对BAMO-THF复合推进剂性能的影响

采用混合硝酸酯(NG+DEGDN)和2,2-二硝基丙醇缩甲醛与2,2-二硝基丙醇缩乙醛混合物(A3)研究了增塑剂对3,3-二叠氮甲基氧丁环-四氮呋喃共聚醚(BAMO-THF)复合推进剂燃速、力学性能的影响。结果表明NG+DEGDN增塑的推进剂燃速和力学性能均优于A3。另外,研究了一种有机过渡金属燃速催化剂(代号OME)对BAMO-THF复合推进剂性能的影响。在显著提高BAMO-THF复合推进剂燃速同时,OME还可提高该体系力学性能。X射线光电子能谱(XPS)分析表明OME与粘结剂中叠氮基团存在作用力。     

硝胺无烟改性双基推进剂燃烧性能调节及控制规律的初探

根据多年研究工作的经验，对该类推进剂的催化剂品种选择，复合催化剂的协同作用，硝胺品种对燃烧性能影响，临界压力的下降，燃烧不稳定的抑制及烟雾特性等技术专题作了简要的总结。     

过氧化氢催化剂及其催化剂床技术综述

介绍了过氧化氢催化剂及其催化剂床技术的发展过程，包括从最初的液体喷注催化技术到发展较为成熟的银网催化剂床直到新型结构的整体式催化剂床。当前过氧化氢催化剂床的发展趋势是：高床载荷、床长短且装配简单、起动性能好、工作寿命长；催化剂床结构也不断从传统结构向新型结构发展。     

降低NEPE推进剂燃速压强指数研究

研究了两种新型含铅燃速催化剂（ｃｔ２０３－１，ｃｔ２０３－２）对ＮＥＰＥ推进剂燃速压强指数的影响，采用小配方实验和ＤＳＣ研究了两种催化剂与硝酸酯的相容性以及对推进剂固化反应的影响和对ＲＤＸ热分解的催化作用，并利用恒压静态燃速仪测量试了推进剂在４－１１ＭＰａ下的燃烧速度和燃速压强指数。结果表明峡谷种催化剂都表现出与硝酸酯良好的相容性，对推进剂的固化反应有明显的催化作用，对ＲＤＸ的热分解行为则基本没有     

改性双基推进剂燃烧催化规律的正交试验研究

用正交试验法研究了无烟改性双基推进剂的催化剂炭黑、铜盐和铅盐对燃速压强指数的影响，并用正交多项式求算了催化剂含量燃速及压强指数的定量关系式。     

负载型钌催化剂的制备及其催化性能

制备了负载型钌催化剂，研究了该催化剂对环十二碳三稀选择性催化加氢的催化活性和催化寿命，得到了环稀烃选择性催化加氢的最佳反应条件，结果表明，该催化剂的催化寿命能满足工业生产的要求。     

Comparing proton fluxes of central meridian SEP events with those predicted by SOLPENCO

We have developed an operational code, SOLPENCO, that can be used for space weather prediction schemes of solar energetic particle (SEP) events. SOLPENCO provides proton differential flux and cumulated fluence profiles from the onset of the event up to the arrival of the associated traveling interplanetary shock at the observer’s position (either 1.0 or 0.4 AU). SOLPENCO considers a variety of interplanetary scenarios where the SEP events develop. These scenarios include solar longitudes of the parent solar event ranging from E75 to W90, transit speeds of the associated shock ranging from 400 to 1700 km s⁻¹, proton energies ranging from 0.125 to 64 MeV, and interplanetary conditions for the energetic particle transport characterized by specific mean free paths. We compare the results of SOLPENCO with flux measurements of a set of SEP events observed at 1 AU that fulfill the following four conditions: (1) the association between the interplanetary shock observed at 1 AU and the parent solar event is well established; (2) the heliolongitude of the active region site is within 30° of the Sun–Earth line; (3) the event shows a significant proton flux increase at energies below 96 MeV; (4) the pre-event intensity background is low. The results are discussed in terms of the transit velocity of the shock and the proton energy. We draw conclusions about both the use of SOLPENCO as a prediction tool and the required improvements to make it useful for space weather purposes.     

To the problem on the reliability of solar energetic proton flux models

This work analyses basic issues of conformity of the most well-known models of solar energetic particles (SEP) fluxes to the experimental data. It is shown, that the postulates on neglecting SEP fluxes in quiet Sun years and on invariability SEP fluxes in active Sun years, underlying some models, contradict the experimental data.     

Energetic particle signatures of geoeffective coronal mass ejections

We have studied statistically associations of moderate and intense geomagnetic storms with coronal mass ejections (CMEs) and energetic particle events. The goal was to identify specific energetic particle signatures, which could be used to improve the predictions of the geoeffectiveness of full and partial halo CMEs. Protons in the range 1–110 MeV from the ERNE experiment onboard SOHO are used in the analysis. The study covers the time period from August 1996 to July 2000. We demonstrate the feasibility of energetic particle observations as an additional source of information in evaluating the geoeffectiveness of full and partial halo CMEs. Based on the observed onset times of solar energetic particle (SEP) events and energetic storm particle (ESP) events, we derive a proxy for the transit times of shocks driven by the interplanetary counterparts of coronal mass ejections from the Sun to the Earth. For a limited number of geomagnetic storms which can be associated to both SEP and ESP signatures, we found that this transit time correlates with the strength of geomagnetic storms.     

Solar proton enhancements in different energy channels and coronal mass ejections during the last solar cycle

The main properties of 11622 coronal mass ejections (CMEs) observed by the Solar and Heliospheric Observatory (SOHO) mission’s Large Angle and Spectrometric Coronagraph (LASCO-C2) from January 1996 through December 2006 are considered. Moreover, the extended database of solar proton enhancements (SPEs) with proton flux >0.1 pfu at energy >10 MeV measured at the Earth’s orbit is also studied. A comparison of these databases gives new results concerning the sources and acceleration mechanisms of solar energetic particles. Specifically, coronal mass ejections with width >180° (wide) and linear speed >800 km/s (fast) seem they have the best correlation with solar proton enhancements. The study of some specific solar parameters, such as soft X-ray flares, sunspot numbers, solar flare index etc. has showed that the soft X-ray flares with importance >M5 may provide a reasonable proxy index for the SPE production rate. From this work, it is outlined that the good relation of the fast and wide coronal mass ejections to proton enhancements seems to lead to a similar conclusion. In spite of the fact that in the case of CMEs the statistics cover only the last solar cycle, while the measurements of SXR flares are extended over three solar cycles, it is obvious for the studied period that the coronal mass ejections can also provide a good index for the solar proton production.