疲劳关键件加速腐蚀因子可靠性分析

针对腐蚀条件下飞机结构疲劳寿命分析和评定问题,对疲劳关键件加速腐蚀因子进行了研究。以疲劳寿命作为疲劳关键件的腐蚀量,定义加速腐蚀因子为疲劳寿命相等时的服役时间与加速时间的比。假定疲劳寿命服从对数正态分布、疲劳寿命随腐蚀时间呈指数变化,推导得到了加速腐蚀因子的表达式以及加速腐蚀因子与腐蚀时间无关的结论;得到了加速腐蚀因子估计量的分布,对其进行了可靠性分析。并进行了典型结构模拟试件大气暴露和试验室加速腐蚀因子的可靠性分析。     

固体发动机钢制件在海洋环境下的防腐研究

对局部表面等离子喷涂氧化锆的固体火箭发动机钢质金属件在海洋环境（高热、高湿、含盐雾）的防腐方法进行了研究。筛选了喷管扩张段的防腐材料及工艺，进行了模拟海洋环境条件下的试验比较及热试车考核，推荐了一种实用、简便而有效的防腐方法，即在氧化锆喷涂层表面涂覆８２３涂料作为封闭剂，其余表面镀镉。     

00Cr17Ni14Mo2不锈钢的性能研究

本文研究了00C r17N i14Mo2不锈钢材料的的性能,证明其具有很好的机械性能、焊接性能和耐腐蚀性能,从用户和研究开发的角度探讨了其在压力容器、化工装置等领域的应用。     

Understanding stress corrosion cracking behavior of 7085-T7651 aluminum alloy in polluted atmosphere

The electrochemical and Stress Corrosion Cracking (SCC) behaviors of 7085-T7651 aluminum alloy in different environments are studied by electrochemical and mechanical testing. The research shows that the type, concentration of the corrosive medium and electrolyte state affect the electrochemical and SCC controlling processes of aluminum alloys. The Thin Electrolyte Layer (TEL) state and the addition of HSO₃^– increase the corrosion rate and SCC susceptibility. The presence of HSO₃^– in a corrosive environment can significantly accelerate the corrosion rate and mechanical property degradation, and this effect increases with the increase of HSO₃^– concentration. Compared with the solution environment, the TEL environment will further aggravate corrosion and mechanical property degradation. With the increase of HSO₃^– concentration, the pH of the corrosive environment exhibits little change, while the SCC degradation is significantly promoted. This is attributed to the HSO₃^– induced buffer effect and film-assisted stress effect, yielding the overshadowing effect against solution pH.     

Stress corrosion behavior of 2195-T8 Al-Li alloy with an artificial pit exposed to a 30vol% HNO3 solution

This paper experimentally studied the stress corrosion behavior of 2195-T8 Al-Li alloys with prefabricated pits in 30vol% HNO₃. The microstructure was observed and determined by the scanning electron microscopy and the transmission electron microscopy. The typical corrosion features, i.e., regular or irregular corrosion pits and sub/intergranular corrosion, were investigated, and the role of stress were analyzed. The statistical results of the number and area of corrosion pits in various sizes were studied using an improved image processing method. Experimental results demonstrate that stress affects the intergranular corrosion or sub-intergranular corrosion of the alloy most, and promotes them to evolve into cracks under stress corrosion. Stress also plays a role in accelerating corrosion severity of certain corrosion feature. The number of corrosion pits with an area of 0–50 μm² can be seen as an index to reflect the degree of corrosion. Besides, a corrosion phenomenon, i.e., the pit bottom in the site with the maximum stress locally suffering from no severe corrosion, was observed and discussed.