含炔基有机硅杂化聚合物的合成及热稳定性

采用双乙炔基封端的硅氮烷单体(双(4-乙炔基苯胺基) 二苯基硅烷,M1) 与含不同二甲基硅基
结构单元[—Si( CH3 )2—,—Si( CH3 )2—O—Si( CH3 )2—和—Si( CH3 )2—O—Si( CH3 )2—O—Si( CH3 )2—] 的
双溴苯基封端单体进行Sonogashira 交叉偶联反应,制备出一系列含炔基有机硅杂化聚合物。通过红外( FTIR)
、核磁氢谱(1H-NMR) 和凝胶渗透色谱( GPC) 对聚合物的结构和分子量进行了表征,并采用热重分析
(TGA)对聚合物的热性能进行了研究。结果表明,二甲基硅基结构的引入显著提高聚合物的溶解性,各组聚
合物均展现出良好的热稳定性能,其中引入—Si(CH3)2—结构的聚合物具有相对最好的热稳定性。     

Prediction of shock-layer ultraviolet radiation for hypersonic vehicles in near space

A systemic and validated model was developed to predict ultraviolet spectra features from the shock layer of near-space hypersonic vehicles in the ‘‘solar blind" band region. Computational procedures were performed with 7-species thermal non-equilibrium fluid mechanics, finite rate chemistry, and radiation calculations. The thermal non-equilibrium flow field was calculated with a two-temperature model by the finite volume technique and verified against the bow-shock ultra-violet(BSUV) flight experiments. The absorption coefficient of the mixture gases was evaluated with a line-by-line method and validated through laboratory shock tube measurements. Using the line of sight(LOS) method, radiation was calculated from three BSUV flights at altitudes of 38,53.5 and 71 km. The investigation focused on the level and structure of ultraviolet spectra radiated from a NO band system in wavelengths of 200–400 nm. Results predicted by the current model show qualitative spatial agreement with the measured data. At a velocity of 3.5 km/s(about Mach11), the peak absolute intensity at an altitude of 38 km is two orders of magnitude higher than that at 53.5 km. Under the same flight conditions, the spectra structures have quite a similar distribution at different viewing angles. The present computational model performs well in the prediction of the ultraviolet spectra emitted from the shock layer and will contribute to the investigation and analysis of radiative features of hypersonic vehicles in near space.     

Nutation instability of spinning solid rocket motor spacecraft

The variation of mass,and moment of inertia of a spin-stabilized spacecraft leads to concern about the nutation instability.Here a careful analysis on the nutation instability is performed on a spacecraft propelled by solid rocket booster (SRB).The influences of specific solid propellant designs on transversal angular velocity are discussed.The results show that the typical SRB of End Burn suppresses the non-principal axial angular velocity.On the contrary,the frequently used SRB of Radial Burn could amplify the transversal angular velocity.The nutation instability caused by a design of Radial Burn could be remedied by the addition of End Burn at the same time based on the study of the combination design of both End Burn and Radial Burn.The analysis of the results proposes the design conception of how to control the nutation motion.The method is suitable to resolve the nutation instability of solid rocket motor with complex propellant patterns.     

陶瓷隔热瓦的缺陷修补

分别采用了MgO、YSZ和Al₂O₃三种陶瓷粉体和一种含隔热瓦本体成分的粉料对陶瓷隔热瓦缺陷进行修补。研究了修补前后材料的微观形貌、力学及隔热性能。结果表明：采用含隔热瓦本体组成的粉料对陶瓷隔热瓦进行修补,修补部位与本体部位相容性好,且微观形貌相似,仍保持纤维搭接的多孔空间网络结构;修补后试样密度0.24 g/cm³、室温热导率0.044 W/（m·K）、压缩强度0.58 MPa;1 200℃、30 min热处理后,修补部位与本体部位结合性好,未出现裂纹、凹陷等缺陷,是有效的缺陷修补方法。     

陀螺稳定平台视轴稳定系统自适应模糊PID控制

 在运动载体上的光电跟踪系统中,需要采用建立在陀螺稳定平台上的视轴稳定控制。分析了平台结构和惯性稳定隔离原理。针对系统机械谐振、力矩耦合及电气参数波动等非线性不确定因素的影响,设计了复合自适应模糊PID控制器。引入自适应调整因子进行控制规则和参数的在线修正,采用复合控制克服模糊控制固有的盲区,实现无差调节。在光电跟踪转台上的实验结果显示该方法能够有效地隔离载体扰动,减小扰动造成的误差,保证视轴对目标的准确瞄准,具有快速的动态响应和较强的抗干扰性。     

飞机综合航电系统总体设计综合评估方法

 航空电子系统的费用 效能是飞机总体系统效能的重要组成部分,也是降低飞机寿命周期费用的关键之一。在航空电子系统的总体设计阶段,传统的系统评估和优化方法主要针对的是独立子系统/设备的费用或效能指标。综合航电系统设计方案的费用 效能重要指标包括：可支付性、构型能力、任务能力、可靠性、维修性、测试性和技术风险,以组合的方式获得了相应的综合评估准则,给出了计算公式。以某新研航电系统作为实例演示了综合评估方法的实施情况,演示的重点集中于总体设计方案的可视化量化评估分析。该综合评估方法已显示出其在实际工程设计中的可行性和应用价值。     

Investigation on the Thermal Conductivity of 3-Dimensional and 4-Directional Braided Composites

It is vital to choose a factual and reasonable micro-structural model of braided composites for improving the calculating precision of thermal property of 3-D braided composites by finite element method (FEM). On the basis of new microstructure model of braided composites proposed recently, the model of FEM calculation for thermal conductivity of 3-dimennsional and 4-directional braided composites is set up in this paper. The curves of coefficient of effective thermal conductivity versus fiber volume ratio and interior braiding angle are obtained. Furthermore, comparing the results of FEM with the available experimental data,the reasonability and veracity of calculation are confirmed at the same time.     

高效空间应用燃料电池热能利用技术研究

首先介绍了空间应用燃料电池高效散热及温控技术。高精度控温主要是利用被动散热技术,将产生的热量快速传导至外部冷却介质,从而保证产热面的温度均匀性,实现电池稳定工作。通过嵌入式被动散热和双端散热的冷却方式,实现电堆内部最大温差小于5℃,换热系数达1000W/(m·K)。     

数值仿真技术在热真空试验中的应用

由于热真空试验中温度测点有限,且关键部位布置困难,不能反映试验过程部件整体和关键部位的温度结果,导致试验有效性和产品安全性难以判断。通过数值仿真技术对试验过程进行模拟,得到所有部件详细温度场,验证试验有效性与产品安全性;发现影响产品温度分布的因素,研究提高产品可靠性措施。通过对某天线热真空试验过程模拟,得到天线详细温度场,并发现产品散热板安装＂不紧密＂缺陷,是影响天线温度均匀性的＂关键点＂。     

正交各向异性单向复合材料裂纹尖端塑性区求解

基于复合材料力学基本理论,推导了Tsai-Hill准则、Hoffman准则和Tsai-Wu准则在平面问题下的一般表达式,在平面应力和应变状态下,得到复合材料中心裂纹板裂纹尖端塑性区的解析解.结果表明,基于Tsai-Wu准则得到的Ⅰ型、Ⅱ型和Ⅰ/Ⅱ复合型裂纹裂尖塑性区范围最小.平面应变状态下的裂尖塑性区范围小于平面应力状态下的裂尖塑性区范围.裂纹倾角β对复合材料裂尖塑性区范围和形状有明显影响,不同值得到的塑性区结果差别很大.不论是平面应力还是平面应变条件,裂纹尖端塑性区域都随着裂纹倾角的增大而增大.