含炔基有机硅杂化聚合物的合成及热稳定性

采用双乙炔基封端的硅氮烷单体(双(4-乙炔基苯胺基) 二苯基硅烷,M1) 与含不同二甲基硅基
结构单元[—Si( CH3 )2—,—Si( CH3 )2—O—Si( CH3 )2—和—Si( CH3 )2—O—Si( CH3 )2—O—Si( CH3 )2—] 的
双溴苯基封端单体进行Sonogashira 交叉偶联反应,制备出一系列含炔基有机硅杂化聚合物。通过红外( FTIR)
、核磁氢谱(1H-NMR) 和凝胶渗透色谱( GPC) 对聚合物的结构和分子量进行了表征,并采用热重分析
(TGA)对聚合物的热性能进行了研究。结果表明,二甲基硅基结构的引入显著提高聚合物的溶解性,各组聚
合物均展现出良好的热稳定性能,其中引入—Si(CH3)2—结构的聚合物具有相对最好的热稳定性。     

Prediction of shock-layer ultraviolet radiation for hypersonic vehicles in near space

A systemic and validated model was developed to predict ultraviolet spectra features from the shock layer of near-space hypersonic vehicles in the ‘‘solar blind" band region. Computational procedures were performed with 7-species thermal non-equilibrium fluid mechanics, finite rate chemistry, and radiation calculations. The thermal non-equilibrium flow field was calculated with a two-temperature model by the finite volume technique and verified against the bow-shock ultra-violet(BSUV) flight experiments. The absorption coefficient of the mixture gases was evaluated with a line-by-line method and validated through laboratory shock tube measurements. Using the line of sight(LOS) method, radiation was calculated from three BSUV flights at altitudes of 38,53.5 and 71 km. The investigation focused on the level and structure of ultraviolet spectra radiated from a NO band system in wavelengths of 200–400 nm. Results predicted by the current model show qualitative spatial agreement with the measured data. At a velocity of 3.5 km/s(about Mach11), the peak absolute intensity at an altitude of 38 km is two orders of magnitude higher than that at 53.5 km. Under the same flight conditions, the spectra structures have quite a similar distribution at different viewing angles. The present computational model performs well in the prediction of the ultraviolet spectra emitted from the shock layer and will contribute to the investigation and analysis of radiative features of hypersonic vehicles in near space.     

陶瓷隔热瓦的缺陷修补

分别采用了MgO、YSZ和Al₂O₃三种陶瓷粉体和一种含隔热瓦本体成分的粉料对陶瓷隔热瓦缺陷进行修补。研究了修补前后材料的微观形貌、力学及隔热性能。结果表明：采用含隔热瓦本体组成的粉料对陶瓷隔热瓦进行修补,修补部位与本体部位相容性好,且微观形貌相似,仍保持纤维搭接的多孔空间网络结构;修补后试样密度0.24 g/cm³、室温热导率0.044 W/（m·K）、压缩强度0.58 MPa;1 200℃、30 min热处理后,修补部位与本体部位结合性好,未出现裂纹、凹陷等缺陷,是有效的缺陷修补方法。     

Investigation on the Thermal Conductivity of 3-Dimensional and 4-Directional Braided Composites

It is vital to choose a factual and reasonable micro-structural model of braided composites for improving the calculating precision of thermal property of 3-D braided composites by finite element method (FEM). On the basis of new microstructure model of braided composites proposed recently, the model of FEM calculation for thermal conductivity of 3-dimennsional and 4-directional braided composites is set up in this paper. The curves of coefficient of effective thermal conductivity versus fiber volume ratio and interior braiding angle are obtained. Furthermore, comparing the results of FEM with the available experimental data,the reasonability and veracity of calculation are confirmed at the same time.     

高效空间应用燃料电池热能利用技术研究

首先介绍了空间应用燃料电池高效散热及温控技术。高精度控温主要是利用被动散热技术,将产生的热量快速传导至外部冷却介质,从而保证产热面的温度均匀性,实现电池稳定工作。通过嵌入式被动散热和双端散热的冷却方式,实现电堆内部最大温差小于5℃,换热系数达1000W/(m·K)。     

数值仿真技术在热真空试验中的应用

由于热真空试验中温度测点有限,且关键部位布置困难,不能反映试验过程部件整体和关键部位的温度结果,导致试验有效性和产品安全性难以判断。通过数值仿真技术对试验过程进行模拟,得到所有部件详细温度场,验证试验有效性与产品安全性;发现影响产品温度分布的因素,研究提高产品可靠性措施。通过对某天线热真空试验过程模拟,得到天线详细温度场,并发现产品散热板安装＂不紧密＂缺陷,是影响天线温度均匀性的＂关键点＂。     

航空发动机法兰接触热阻特性实验研究

通过搭建法兰接触热阻实验台,在法兰间隙0～0.75 mm、螺栓拧紧力矩20～40 N·m参数范围内,测量不同材料机匣多个轴向位置的壁温来获得通过法兰的热流,得到法兰的接触热阻、单位接触热导。分析了法兰间隙、螺栓拧紧力矩对法兰接触热阻特性的影响。研究结果表明随着法兰间隙的增加,接触热阻呈线性增加,最大增加0.03 K/W,单位接触热导先迅速减小,后趋于平缓,最大降低了10 744.2 W/(K·m2),约94.5%;随着拧紧力矩的增加,接触热阻减小,最大降低了22.1%。     

基于Ansys Icepak 的负载器热设计与热分析

基于热设计的基础理论与负载器的工作原理,应用Ansys Icepak仿真软件对供配电负载器工作过程中内部散热情况进行仿真,找出负载器内部温度最高部位,指导实际测试,避免实际测试的盲目性。另外,通过优化负载器散热孔设计,降低负载器温升值。     

碳纤维热导率与其微观结构参数的关系

碳纤维具有多晶多相特性,为了研究微晶结构特性对热导率的影响,本文通过XRD对碳纤维的微观特征结构参数的表征,对导热性能与微观特征结构的关联性进行了研究。研究结果表明,碳纤维热导率随着石墨微晶的基面宽度（L_a）、堆砌厚度（L_c）和平均堆垛层数（N）的增大而增大,随着孔隙率（V_p）的增大而降低。基于Raman图谱的分峰拟合信息,对碳纤维的石墨化度进行分析。结果显示,碳纤维的石墨化度越大,热导率越高。     

Remote upgrading of a space-borne instrument

The main purposes of experiment “Obstanovka” (“Environment” in Russian) consisting of several instruments are to measure a set of electromagnetic and plasma phenomena characterizing the space weather conditions, and to evaluate how such a big and highly energy consuming body as the International Space Station disturbs the surrounding plasma, and how the station itself is charged due to the operation of so many instruments, solar batteries, life supporting devices, etc. Two identical Langmuir electrostatic probes are included in the experiment “Obstanovka”. In this paper the Langmuir probes for “Obstanovka” experiment are described, including the choice of geometry (spherical or cylindrical), a more reliable method for the sweep voltage generation, an adaptive algorithm for the probe’s operation. Special attention is paid to the possibility for remote upgrading of the instrument from the ground using the standard communication channels.